极地冰芯电学性质及导电测量技术研究进展

doi:10.11867/j.issn.1001-8166.2016.02.0161.

地球科学进展 ›› 2016, Vol. 31 ›› Issue (2): 161 -170. doi: 10.11867/j.issn.1001-8166.2016.02.0161.

极地冰芯电学性质及导电测量技术研究进展

马天鸣 ^1, ²(

), 谢周清 ¹, 李院生 ^2,,A; ^*(

)

1.中国科学技术大学地球和空间科学学院,安徽合肥 230026
2.中国极地研究中心冰川室,上海 200136

收稿日期:2015-12-21 修回日期:2016-01-29 出版日期:2016-02-20
通讯作者: 李院生 E-mail:matianming@pric.org.cn;liyuansheng@pric.org.cn
基金资助:
国家高技术研究发展计划“冰架热水钻机关键技术与系统开发”(编号:2011AA090401);南北极环境综合与考察专项(2015年度)“2015年度冰盖断面及格罗夫山综合考察与冰穹A深冰芯钻探”(编号:CHINARE2015-02-02)资助

Research Progress on Electrical Properties and Conductivity Measurement Technology of Ice Core

Tianming Ma ^1, ²( ), Zhouqing Xie ¹, Yuansheng Li ^2, ^*( )

1.The School of Earth and Space Science, University of Science and Technology of China, Hefei 230026,China
2.Polar Research Institute of China, Shanghai 200136, China

Received:2015-12-21 Revised:2016-01-29 Online:2016-02-20 Published:2016-02-10
Contact: Yuansheng Li E-mail:matianming@pric.org.cn;liyuansheng@pric.org.cn
About author:
First author:Ma Tianming(1990-), male, Jinzhou City, Liaoning Province, Master Student. Research areas include geochemistry on ice and snow in Antarctic.E-mail:matianming@pric.org.cn

Corresponding author:Li Yuansheng(1956-), male, Baotou City, Inner Mongolia Province, Professor. Research area include glaciology in Antarctic.E-mail:liyuansheng@pric.org.cn.
Supported by:
Project supported by the National High Technology Research and Development Program of China “Hot water ice drilling project at the Amery Ice Shelf”(No.2011AA090401);The Chinese Polar Environment Comprehensive Investigation & Assessment Programmes “Comprehensive surveys along Zhongshan Station to Dome A and in the Grove Mountains and deep ice core drilling at the Dome A”(No.CHINARE2015-02-02)

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冰芯是全球气候变化研究的重要对象,通过物理和化学手段可提取其中的古气候信息。作为物理分析技术之一,冰芯导电测量技术可分为ECM和DEP 2类,已运用到多个冰芯项目中。其主要反映了冰芯电学性质受温度、压力、杂质等因素影响而产生的变化,而导致这些变化的原因可从宏观和微观方面进行解释和探究。冰芯导电测量获得的结果可应用于定年、火山事件、积累率、生物质燃烧、离子浓度恢复等多领域研究,对帮助系统认识第四纪晚更新世以来的南极气候演变过程具有重要意义。通过详细总结极地冰芯导电性质及测量技术的主要研究成果,探讨了该技术在中国Dome A深冰芯项目中的应用前景。

关键词: 冰芯, 导电测量技术, ECM, DEP, 古气候

Ice core is an important object of the global climate change research, and can extract paleoclimate information by physical and chemical methods. As one of the major physical analysis technology, conductivity measurement technology mainly contains two methods and has been applied to many drilling project. The technology reflects the ice core electrical properties influenced by factors such as temperature, pressure, impurities and changes, and the cause of these changes can be explained from the aspects of macroscopic and microscopic. What obtained from measurement can be used to the research of dating, volcanic events, accumulation rate, biomass burning, ion concentration recovery, which systematically help us to understand the quaternary evolution of Antarctic climate since late pleistocene. This paper summarized in detail the main research achievements on electrical properties and dielectric measurement technology of ice core, and also discussed the prospect of the technology in China deep ice core project further.

Key words: Ice core, Conductivity measurement technology, ECM, DEP, Paleoclimate.

中图分类号:

P343.6

图1 ECM设备实物图

Fig.1 ECM equipment physical figure

表1 历年南北两极深冰芯ECM设备及相关参数

Table 1 ECM equipment and related parameters of polar deep ice cores

冰芯地点	电极材料	电压 /V	电极间距 /cm	测试温度 /℃	冰芯长度 /m	端部形状及分辨率	其他及备注
GRIP和GISP2^{[ 11 , 12 ]}	黄铜	1 250(GRIP) 2 100(GISP2)	1	-14(或更低)	2.5	方形, 1~2 mm	移动速度 25 mm/s
NEEM和NGIRP^{[ 13 ]}	黄铜	1 250	1	-14(0.23 eV)	1.65~2.2 (来源于DEP)	1~2 cm (NGRIP1, NEEM),1 mm (NGIRP2)	/
Bryd站^{[ 14 , 15 ]}	黄铜	1 200	1	-23	/	1 mm	/
DOME C^{[ 16 , 17 ]}	碳掺杂硅橡胶	350 (小电极间)	电极内部8 mm空间,共有7个小电极	-20+/-2	2.2	1 mm	冰面宽度: 10 cm
VOSTOK^{[ 17 ]}	黄铜	1 500	0.2	-15,通风和绝缘预先加热一晚,-50 ℃重复测量	1	圆形、1 mm	移动速度: 2 m/min, 冰面宽度: 10 cm
DOME F^{[ 18 , 19 ]}	黄铜	1 250	0.15	-20+/-1	/	2 mm	/
WAIS divide^{[ 20 ]}	/	1 250	1	-14~-15	1	1 mm	/
South pole站^{[ 21 ]}	黄铜	1 000	1	约为-15	0.5	尖端锋利,估计为1~2 mm	去除上端的10 mm进行测量
Siple DOME^{[ 22 ]}	/	1 000	1	/	1	3 mm	/

表1 历年南北两极深冰芯ECM设备及相关参数

Table 1 ECM equipment and related parameters of polar deep ice cores

冰芯地点	电极材料	电压 /V	电极间距 /cm	测试温度 /℃	冰芯长度 /m	端部形状及分辨率	其他及备注
GRIP和GISP2^{[ 11 , 12 ]}	黄铜	1 250(GRIP) 2 100(GISP2)	1	-14(或更低)	2.5	方形, 1~2 mm	移动速度 25 mm/s
NEEM和NGIRP^{[ 13 ]}	黄铜	1 250	1	-14(0.23 eV)	1.65~2.2 (来源于DEP)	1~2 cm (NGRIP1, NEEM),1 mm (NGIRP2)	/
Bryd站^{[ 14 , 15 ]}	黄铜	1 200	1	-23	/	1 mm	/
DOME C^{[ 16 , 17 ]}	碳掺杂硅橡胶	350 (小电极间)	电极内部8 mm空间,共有7个小电极	-20+/-2	2.2	1 mm	冰面宽度: 10 cm
VOSTOK^{[ 17 ]}	黄铜	1 500	0.2	-15,通风和绝缘预先加热一晚,-50 ℃重复测量	1	圆形、1 mm	移动速度: 2 m/min, 冰面宽度: 10 cm
DOME F^{[ 18 , 19 ]}	黄铜	1 250	0.15	-20+/-1	/	2 mm	/
WAIS divide^{[ 20 ]}	/	1 250	1	-14~-15	1	1 mm	/
South pole站^{[ 21 ]}	黄铜	1 000	1	约为-15	0.5	尖端锋利,估计为1~2 mm	去除上端的10 mm进行测量
Siple DOME^{[ 22 ]}	/	1 000	1	/	1	3 mm	/

图2 DEP设备基本结构图 ^{[

26
]}

Fig.2 DEP equipment basic structure ^{[

26
]}

表2 南北两极深冰芯中DEP使用情况及相关参数

Table 2 DEP equipment and related parameters of polar ice cores

冰芯地点	频率	分辨率
Dolleman冰芯^{[ 7 ]}	在20 Hz~300 KHz,静频 60 Hz,主弥散频率75 Hz, 弛豫频率12 Hz	5 cm
GRIP^{[ 11 , 12 ]}	20个,120~300 kHz	2 cm
GRIP(HRDEP)^{[ 28 ]}	50 kHz	5~6 mm
NEEM和 NGIRP^{[ 13 , 26 ]}	250 kHz	2~5 mm
DOME C(EDC 96/99)^{[ 29 ]}	100 kHz	2 cm
DML系列^{[ 17 ]}	250 kHz	5 mm
Dome F^{[ 30 ]}	20 Hz~1 MHz	/
WAIS divide^{[ 20 ]}	使用HRDEP方法,同HRDEP	/

表2 南北两极深冰芯中DEP使用情况及相关参数

Table 2 DEP equipment and related parameters of polar ice cores

冰芯地点	频率	分辨率
Dolleman冰芯^{[ 7 ]}	在20 Hz~300 KHz,静频 60 Hz,主弥散频率75 Hz, 弛豫频率12 Hz	5 cm
GRIP^{[ 11 , 12 ]}	20个,120~300 kHz	2 cm
GRIP(HRDEP)^{[ 28 ]}	50 kHz	5~6 mm
NEEM和 NGIRP^{[ 13 , 26 ]}	250 kHz	2~5 mm
DOME C(EDC 96/99)^{[ 29 ]}	100 kHz	2 cm
DML系列^{[ 17 ]}	250 kHz	5 mm
Dome F^{[ 30 ]}	20 Hz~1 MHz	/
WAIS divide^{[ 20 ]}	使用HRDEP方法,同HRDEP	/

表3 不同条件下冰的电学性质 ^{[

31
]}

Table 3 The electrical properties of ice on different conditions ^{[

31
]}

变量	参数	高频实部介电常数	高频电导
温度/℃	-15	3.15	9.0
温度/℃	-50	3.13	0.2
压力/MPa	0.1	3.15	9.0
压力/MPa	28	/	8.7
密度/(kg/m)	350	1.67	2.2
密度/(kg/m)	917	3.15	9.0
组构	∥c-axis	3.18	9.0
组构	⊥c-axis	3.14	9.0
杂质H⁺/μmol	0	3.15	9.0
杂质H⁺/μmol	4	3.15	25.0

表3 不同条件下冰的电学性质 ^{[

31
]}

Table 3 The electrical properties of ice on different conditions ^{[

31
]}

变量	参数	高频实部介电常数	高频电导
温度/℃	-15	3.15	9.0
温度/℃	-50	3.13	0.2
压力/MPa	0.1	3.15	9.0
压力/MPa	28	/	8.7
密度/(kg/m)	350	1.67	2.2
密度/(kg/m)	917	3.15	9.0
组构	∥c-axis	3.18	9.0
组构	⊥c-axis	3.14	9.0
杂质H⁺/μmol	0	3.15	9.0
杂质H⁺/μmol	4	3.15	25.0

图3 ECM实测结果随温度变化曲线 ^{[

35
]}

Fig.3 ECM change curve with temperature ^{[

35
]}

图4 电镜下的晶间水脉 ^{[

59
]}

Fig.4 Intercrystalline water pulse under the electron microscope ^{[

59
]}

[1]	Wei Lijia, Li Yuansheng, Tan Dejun, et al.Reveiw of research on insoluble microparticles in the polar cores[J].Advances in Earth Science,2005, 20(2):216-222.
	[韦丽佳, 李院生, 谭德军, 等. 极地冰芯不溶性微粒研究进展[J]. 地球科学进展, 2005, 20(2): 216-222.]
[2]	Sun Bo, Yao Tandong, Kang Jiancheng, et al.Solid electrical conductivity measurement of polar ice cores and its environmental significance[J].Chinese Journal of Polar Research,1998, 10(3): 235-240.
	[孙波, 姚檀栋, 康建成, 等. 极地冰芯固体直流导电特性检测 (ECM) 及环境意义[J]. 极地研究, 1998, 10(3): 235-240.]
[3]	Eigen M, Maeyer L D.Self-dissociation and protonic charge transport in water and ice[J].Proceedings of the Royal Society A,1958, 247(1 251): 505-533.
[4]	Chai S Y, Vogelhut P O.Activation energy of direct-current electrical conductivity of ice with HF and NH3 added[J]. Science,1965, 148(3 677): 1 595-1 598.
[5]	Takei I, Maeno N. Electric characteristics of point defects in HCl-doped ice[J].Le Journal de Physique Colloques,1987, 48(C1): C1-121-C1-126.
[6]	Hammer C U.Acidity of polar ice cores in relation to absolute dating, past volcanism, and radio-echoes[J].Journal of Glaciology,1980, 25(93): 359-372.
[7]	Moore J C, Paren J G. A new technique for dielectric logging of Antarctic ice cores[J]. Le Journal de Physique Colloques,1987, 48(C1): C1-155-C1-160.
[8]	Yang Jianping, Ding Yongjian, Fang Yiping, et al.Research frame of vulnerability and adaptation for the cryosphere and its changes[J]. Advances in Earth Science,2015, 30(5): 517-529.
	[杨建平, 丁永建, 方一平, 等. 冰冻圈及其变化的脆弱性与适应研究体系[J]. 地球科学进展, 2015, 30(5): 517-529.]
[9]	Wu Guoxiong, Lin Hai, Zou Xiaolei, et al.Research on global climate change and scientific data[J].Advances in Earth Science,2014, 29(1): 15-22.
	[吴国雄, 林海, 邹晓蕾, 等. 全球气候变化研究与科学数据[J]. 地球科学进展, 2014, 29(1): 15-22.]
[10]	Brook E J, Wolff E, Dahl-Jensen D, et al.The future of ice coring: International Partnerships in Ice Core Sciences (IPICS)[J]. PAGES News,2006, 14(1): 6-10.
[11]	Taylor K C, Alley R B, Lamorey G W, et al. Electrical measurements on the Greenland Ice Sheet Project 2 core[J]. Journal of Geophysical Research:Oceans,1997, 102(C12): 26,511.
[12]	Taylor K C, Hammer C U, Alley R B, et al.Electrical conductivity measurements from the GISP 2 and GRIP Greenland ice cores[J].Nature, 1993, 366(6 455): 549-552.
[13]	Rasmussen S O, Abbott P M, Blunier T, et al.A first chronology for the North Greenland Eemian Ice Drilling (NEEM) ice core[J]. Climate of the Past, 2013, 9(6): 2 713-2 730.
[14]	Hammer C U, Clausen H B, Langway Jr C C. The Byrd ice core: Continuous acidity measurements and solid electrical conductivity measurements[J].Annals of Glaciology,1985, 7: 214.
[15]	Hamer C U, Clausen H B, Langway C C. Electrical Conductivity Method (ECM) stratigraphic dating of the Byrd Station ice core, Antarctica[J]. Annals of Glaciology,1994, 20(1): 115-120.
[16]	King M R.Fractal analysis of eight glacial cycles from an Antarctic ice core[J].Chaos, Solitons & Fractals,2005, 25(1): 5-10.
[17]	Wolff E, Basile I, Petit J R, et al.Comparison of Holocene electrical records from Dome C and Vostok, Antarctica[J]. Annals of Glaciology,1999, 29(1): 89-93.
[18]	Hondoh T, Narita H, Hori A, et al.Basic analyses of Dome Fuji deep ice core Part 2: Physical properties[J].Polar Meteorology & Glaciology,1999, 13: 90-98.
[19]	Hondoh T, Narita H, Hori A, et al.Physical properties of the Dome Fuji deep ice core[J].Memoirs of National Institute of Polar Research Special Issue,2003, 57: 63-71.
[20]	Fitzpatrick J J, Voigt D E, Fegyveresi J M, et al.Physical properties of the WAIS Divide ice core[J].Journal of Glaciology,2014, 60(224): 1 181.
[21]	Ramirez E, Hoffmann G, Taupin J D, et al.A new Andean deep ice core from Nevado Illimani (6 350 m), Bolivia[J].Earth and Planetary Science Letters,2003, 212(3): 337-350.
[22]	Taylor K C, Alley R B, Meese D A, et al.Dating the Siple Dome (Antarctica) ice core by manual and computer interpretation of annual layering[J].Journal of Glaciology, 2004, 50(170): 453-461.
[23]	Sugiyama K, Fujita S, Sueoka S, et al.Preliminary measurement of high-frequency electrical conductivity of Antarctic ice with AC-ECM technique[J].Proceedings of the NIPR Symposium on Polar Meteorology and Glaciology,1995, 9: 12-22.
[24]	Sugiyama K, Fujita S, Narita H, et al.Measurement of electrical conductance in ice cores by AC-ECM method[C]∥International Symposium on Physics of Ice Core Records. Shikotsukohan, Hokkaido, Japan:Hokkaido University Press, 2000.
[25]	Wolff E W, Paren J G.A two-phase model of electrical conduction in polar ice sheets[J].Journal of Geophysical Research: Solid Earth (1978-2012),1984, 89(B11): 9 433-9 438.
[26]	Wilhelms F, Kipfstuhl J, Miller H, et al.Precise dielectric profiling of ice cores: A new device with improved guarding and its theory[J].Journal of Glaciology,1998, 44(146): 171-174.
[27]	Mulvaney R.Ice core methods, conductivity studies[M]∥Scott Elias A, ed. Encyclopedia of Quaternary Science.Netherlands:Elsevier,2013.
[28]	Moore J C.High-resolution dielectric profiling of ice cores[J].Journal of Glaciology,1993, 39(132): 245-248.
[29]	Bohleber P, Hackel M, Eisen O, et al.A multi-method approach to the dielectric properties of natural firn and ice at kHZ-and radio frequencies[C]∥13th International Conference on the Physics and Chemistry of Ice (PCI-2014). Hanover, NH: ACS Publications, 2014.
[30]	Fujita S, Azuma N, Motoyama H, et al.Electrical measurements on the 2503 m Dome F Antarctic ice core[J]. Annals of Glaciology,2002, 35(1): 313-320.
[31]	Wolff E.Electrical stratigraphy of polar ice cores: Principles, methods[M]∥Hondoh T, ed.Physics of Ice Core Records. Sapporo: Hokkaido University Press,2000:155-171.
[32]	Grimm R E, Stillman D E, MacGregor J A. Dielectric signatures and evolution of glacier ice[J].Journal of Glaciology,2015, 61(230): 1 159-1 170.
[33]	Hochstein M.Electrical resistivity measurements on ice sheets[J].Journal of Glaciology,1967, 6(47):623-633.
[34]	Kulessa B.A critical review of the low-frequency electrical properties of ice sheets and glaciers[J]. Journal of Environmental & Engineering Geophysics,2007, 12(1): 23-36.
[35]	Taylor K, Alley R, Fiacco J, et al.Ice-core dating and chemistry by direct-current electrical conductivity[J]. Journal of Glaciology,1992, 38(130): 325.
[36]	Chan R K, Davidson D W, Whalley E.Effect of pressure on the dielectric properties of ice I[J]. The Journal of Chemical Physics,1965, 43(7): 2 376-2 383.
[37]	Barnes P R F, Wolff E W, Mulvaney R, et al. Effect of density on electrical conductivity of chemically laden polar ice[J]. Journal of Geophysical Research: Solid Earth (1978-2012),2002, 107(B2): ESE 1-1-ESE 1-14.
[38]	Eisen O, Bohleber P, Heilig A, et al.Dielectric Properties of Snow and Ice in the MHz-range, ISEMA International Conference on electromagnetic Wave interaction With water and Moist Substances, Bauhaus University, 2013[C].Weimar: Bauhaus University Press, 2013.
[39]	Shabtaie S, Bentley C R.Electrical resistivity sounding of the East Antarctic ice sheet[J].Journal of Geophysical Research: Solid Earth (1978-2012),1995, 100(B2): 1 933-1 954.
[40]	Wolff E W.Comment [on “Electrical resistivity sounding of the East Antarctic ice sheet” by Sion Shabtaie and Charles R. Bentley][J]. Journal of Geophysical Research: Solid Earth,1996, 101(B12): 27 735-27 737.
[41]	Gränicher H, Jaccard C, Scherrer P, et al.Dielectric relaxation and the electrical conductivity of ice crystals[J]. Discussions of the Faraday Society,1957, 23: 50-62,doi:10.1039/DF9572300050.
[42]	Schwander J, Neftel A, Oeschger H, et al.Measurement of direct current conductivity on ice samples for climatological applications[J].The Journal of Physical Chemistry,1983, 87(21): 4 157-4 160.
[43]	West L J, Rippin D M, Murray T, et al.Dielectric permittivity measurements on ice cores: Implications for interpretation of radar to yield glacial unfrozen water content[J]. Journal of Environmental & Engineering Geophysics,2007, 12(1): 37-45.
[44]	Moore J C, Mulvaney R, Paren J G.Dielectric stratigraphy of ice: A new technique for determining total ionic concentrations in polar ice cores[J].Geophysical Research Letters,1989, 16(10): 1 177-1 180.
[45]	Moore J C, Wolff E W, Clausen H B, et al.Electrical response of the Summit-Greenland ice core to ammonium, sulphuric acid, and hydrochloric acid[J].Geophysical Research Letters,1994, 21(7): 565-568.
[46]	Wolff E W, Miners W D, Moore J C, et al.Factors controlling the electrical conductivity of ice from the polar regions a summary[J].The Journal of Physical Chemistry B,1997, 101(32): 6 090-6 094.
[47]	Hammer C U.Initial direct current in the buildup of space charges and the acidity of ice cores[J].The Journal of Physical Chemistry,1983, 87(21): 4 099-4 103.
[48]	Tison J L, Souchez R, Wolff E W, et al.Is a periglacial biota responsible for enhanced dielectric response in basal ice from the Greenland Ice Core Project ice core?[J].Journal of Geophysical Research: Atmospheres (1984-2012),1998, 103(D15): 18 885-18 894.
[49]	Stillman D E, MacGREGOR J A, Grimm R E. Electrical response of ammonium-rich water ice[J]. Annals of Glaciology,2013, 54(64): 21-26.
[50]	Moore J C, Reid A P, Kipfstuhl J.Microstructure and electrical properties of marine ice and its relationship to meteoric ice and sea ice[J].Journal of Geophysical Research: Oceans (1978-2012),1994, 99(C3): 5 171-5 180.
[51]	Moore J, Paren J, Oerter H.Sea salt dependent electrical conduction in polar ice[J].Journal of Geophysical Research: Solid Earth (1978-2012),1992, 97(B13): 19 803-19 812.
[52]	Legrand M, Petit J R, Korotkevich Y S. DC conductivity of Antarctic ice in relation to its chemistry[J]. Le Journal de Physique Colloques,1987, 48(C1): C1-605-C1-611.
[53]	Wolff E W, Moore J C, Clausen H B, et al.Long-term changes in the acid and salt concentrations of the Greenland ice core project ice core from electrical stratigraphy[J].Journal of Geophysical Research: Atmospheres (1984-2012),1995, 100(D8): 16 249-16 263.
[54]	Arvaniti M, Vallelonga P.Application of Contactless Conductivity Detection to Ice Core Analysis[D].Denmark:University of Copenhagen,2014.
[55]	Jaccard J, Jacoby J.Theory Construction and Model-building Skills: A Practical Guide for Social Scientists[M].New York:Guilford Press, 2010.
[56]	Ryzhkin I A, Whitworth R W.The configurational entropy in the Jaccard theory of the electrical properties of ice[J].Journal of Physics: Condensed Matter, 1997, 9(2): 395.
[57]	Maurice D A, Alex A, Silva A J R D, et al. Orientational defects in ice Ih: An interpretation of electrical conductivity measurements[J]. Physical Review Letters, 2006, 96(7):1-5.
[58]	Stillman D E, MacGregor J A, Grimm R E. The role of acids in electrical conduction through ice[J]. Journal of Geophysical Research: Earth Surface,2013, 118(1): 1-16.
[59]	Mader H M.Observations of the water-vein system in polycrystalline ice[J].Journal of Glaciology,1992, 38(130): 333-347.
[60]	Gow A J, Williamson T.Rheological implications of the internal structure and crystal fabrics of the West Antarctic ice sheet as revealed by deep core drilling at Byrd Station[J]. Geological Society of America Bulletin,1976, 87(12): 1 665-1 677.
[61]	Naveau P, Ammann C M.Statistical distributions of ice core sulfate from climatically relevant volcanic eruptions[J]. Geophysical Research Letters,2005, 32(5):215-236.
[62]	Zheng J, Kudo A, Fisher D A, et al.Solid electrical conductivity (ECM) from four Agassiz ice cores, Ellesmere Island NWT, Canada: High-resolution signal and noise over the last millennium and low resolution over the Holocene[J]. The Holocene,1998, 8(4): 413-421.
[63]	Liu L, Kang J, Petit J R, et al.The 4700 aB. P. volcanic signal detected in Vostok BH8 ice core, Antarctica[J]. Chinese Science Bulletin,2005, 50(22): 2 636-2 639.
[64]	Parrenin F, Petit J R, Masson-Delmotte V, et al.Volcanic synchronisation between the EPICA Dome C and Vostok ice cores (Antarctica) 0-145 kyr BP[J]. Climate of the Past,2012, 8(3): 1 031-1 045.
[65]	Wolff E W.Chemical signals of past climate and environment from polar ice cores and firn air[J]. Chemical Society Reviews,2012, 41(19): 6 247-6 258.
[66]	Looyenga H.Dielectric constants of heterogeneous mixtures[J].Physica,1965, 31(3): 401-406.
[67]	Glen J W, Paren J G.The electrical properties of snow and ice[J].Journal of Glaciology,1975, 15: 15-38.
[68]	Karlöf L, Winther J G, Isaksson E, et al.A 1500 year record of accumulation at Amundsenisen western Dronning Maud Land, Antarctica, derived from electrical and radioactive measurements on a 120 m ice core[J]. Journal of Geophysical Research: Atmospheres (1984-2012),2000, 105(D10): 12 471-12 483.
[69]	Oerter H, Wilhelms F, Jung-Rothenhäusler F, et al.Accumulation rates in Dronning Maud Land, Antarctica, as revealed by dielectric-profiling measurements of shallow firn cores[J]. Annals of Glaciology,2000, 30(1): 27-34.
[70]	Oerter H, Graf W, Wilhelms F, et al.Accumulation studies on Amundsenisen, Dronning Maud Land, Antarctica, by means of tritium, dielectric profiling and stable-isotope measurements: First results from the 1995-1996 and 1996-1997 field seasons[J].Annals of Glaciology,1999, 29(1): 1-9.
[71]	Hofstede C M, Van De Wal R S W, Kaspers K A, et al. Firn accumulation records for the past 1000 years on the basis of dielectric profiling of six cores from Dronning Maud Land, Antarctica[J]. Journal of Glaciology,2004, 50(169): 279-291.
[72]	Wilhelms F.Explaining the dielectric properties of firn as a Density-and-Conductivity Mixed Permittivity (DECOMP)[J]. Geophysical Research Letters,2002,44(1):150-153.
[73]	You Chao, Yao Tandong, Wu Guangjian.Research progress on biomass burning records in snow and ice[J]. Advances in Earth Science,2014, 29(6): 662-673.
	[游超, 姚檀栋, 邬光剑. 雪冰中生物质燃烧记录研究进展[J]. 地球科学进展, 2014, 29(6): 662-673.]
[74]	Chylek P, Johnson B, Damiano P A, et al.Biomass burning record and black carbon in the GISP2 ice core[J]. Geophysical Research Letters,1995, 22(2): 89-92.
[75]	Taylor K C, Mayewski P A, Twickler M S, et al.Biomass burning recorded in the GISP2 ice core: A record from eastern Canada?[J]. The Holocene,1996, 6(1): 1-6.
[76]	Moore J C, Paren J G, Mulvaney R.Chemical evidence in polar ice cores from dielectric profiling[J]. Annals of Glaciology,1990, 14: 195-198.
[77]	Barker S.The ‘flickering switch’of late Pleistocene climate change revisited[J].Geophysical research letters,2005, 32(24):1-4.
[78]	Moore J C, Wolff E W, Clausen H B, et al.The chemical basis for the electrical stratigraphy of ice[J]. Journal of Geophysical Research,1992, 97(B2): 1 887-1 896.
[79]	Wolff E W, Moore J C, Clausen H B, et al.Climatic implications of background acidity and other chemistry derived from electrical studies of the Greenland Ice Core Project ice core[J]. Journal of Geophysical Research-All Series, 1997, 102: 26 325-26 332.
[80]	Tang Xueyuan, Sun Bo, Li Yuansheng,et al.Review of the glaciological research progress and future development of deep ice core plan[J]. Chinese Journal of Polar Research,2012,24(1):77-86.
	[唐学远, 孙波, 李院生, 等. 冰穹A 冰川学研究进展及深冰芯计划展望[J]. 极地研究, 2012, 24(1): 77-86.]

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