长链烯酮在古大气二氧化碳分压重建的应用

doi:10.11867/j.issn.1001-8166.2019.03.0265

地球科学进展 ›› 2019, Vol. 34 ›› Issue (3): 265 -274. doi: 10.11867/j.issn.1001-8166.2019.03.0265

长链烯酮在古大气二氧化碳分压重建的应用

马晓旭(

),刘传联(

),金晓波,张洪瑞,马瑞罡

同济大学海洋地质国家重点实验室，上海 200092

收稿日期:2018-12-21 修回日期:2019-02-16 出版日期:2019-03-10
通讯作者: 刘传联 E-mail:jiselle@163.com;liucl@tongji.edu.cn
基金资助:
国家重大科技专项子课题“南海深水区古海洋学与优质烃源岩关系研究(编号：2016ZX05026007-03);国家自然科学基金项目“利用颗石藻生理作用来校正烯酮古CO2气压计中的b值”(编号：41806050)

The Application of Alkenone-Based pCO ₂ Reconstructions

Xiaoxu Ma( ),Chuanlian Liu( ),Xiaobo Jin,Hongrui Zhang,Ruigang Ma

State Key Laboratory of Marine Geology, Tongji University, Shanghai 200092, China

Received:2018-12-21 Revised:2019-02-16 Online:2019-03-10 Published:2019-04-28
Contact: Chuanlian Liu E-mail:jiselle@163.com;liucl@tongji.edu.cn
About author: Ma Xiaoxu （1994-）， female， Zibo City, Shandong Province， Master student. Research areas include paleoceanography. E-mail： jiselle@163.com | Ma Xiaoxu （1994-）， female， Zibo City, Shandong Province， Master student. Research areas include paleoceanography. E-mail： jiselle@163.com |Liu Chuanlian（1963-）， male， Jining City, Shandong Province, Professor. Research areas include marine micropaleontology and paleoceanography. E-mail： liucl@tongji.edu.cn
Supported by:
Project supported by the National Science and Technology Major Project of the Ministry of Science and Technology of China “Study on the relationship between the palaeoceanography and the hydrocarbon source rocks in the deep water of the South China Sea” （No. 2016ZX05026007-03)Fundation: and the National Nature Science Foundation of China “Calibrating the b value in alkenone-based CO2 paleo-barometer by using coccolithophore physiology”(No. 41806050)

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大气二氧化碳浓度的变化与全球冰盖变化、温度、海平面变化密切相关，了解过去大气二氧化碳浓度的变化及对二氧化碳与气候之间关系的研究，是预测未来气候变化的重要手段。长链烯酮碳同位素是重建古大气二氧化碳分压(pCO₂)的重要指标之一，广泛应用于新生代以来大气二氧化碳的重建。对长链烯酮重建大气二氧化碳的方法进行了综述，介绍了颗石藻长链烯酮的地球化学性质，回顾了二氧化碳被动扩散模型的发展、长链烯酮重建二氧化碳的指标的发展及其不确定性，颗石藻的碳浓缩机制以及新生代以来长链烯酮重建大气二氧化碳的地质记录。

关键词: 长链烯酮, 大气二氧化碳分压, 碳同位素, 颗石藻, 被动扩散模型

The changing of atmospheric carbon dioxide concentration is closely related with the changing of global ice sheet，temperature and sea level. Knowledge of the past atmospheric carbon dioxide concentration and its relationship with climate is an important method of predicting the future climate change. Coccolith derived long-chain alkenone carbon isotope is one of the important proxies to reconstruct past carbon dioxide, which is wildly applied in the reconstruction of the Cenozoic atmospheric carbon dioxide. In this paper, we focused on the method of alkenone-based atmospheric carbon dioxide concentration, including the geochemical properties of long-chain alkenone, carbon diffusive model and the carbon isotope fraction. Then, we introduced the development of alkenone-based carbon dioxide proxy and its uncertainty. Coccolith cell geometry and growth rate have great influence on carbon dioxide fraction. Besides, there are some uncertainties about carbon concentration mechanisms in coccolithes, which may have some influence on alkenone-based carbon dioxide method to reconstruct ancient carbon dioxide more accurately. At the end, we summarized the Cenozoic carbon dioxide record with various proxies including alkenone carbon dioxide, boron isotope, palaeosol carbonate nodules and stomatal indices of fossil leaves.

Key words: Long-chain alkenone, Atmospheric carbon dioxide, Carbon isotope, Coccolith, Diffusive models.

中图分类号:

P532

图1 ε_f为25 $‰$ 时，自然环境中浮游植物类群b值与[PO $4 3 -$ ]的比值（数据来自参考文献[24,67~69]）

Fig. 1 b values of natural haptophyte populations versus soluble phosphate when ε_f is 25 $‰$ (Data from references[24,67~69])

图1 ε_f为25 $‰$ 时，自然环境中浮游植物类群b值与[PO $4 3 -$ ]的比值（数据来自参考文献[24,67~69]）

Fig. 1 b values of natural haptophyte populations versus soluble phosphate when ε_f is 25 $‰$ (Data from references[24,67~69])

图2 生长速率与光合作用的影响因素

Fig. 2 The influence factors of growth rate and photosynthesis

图3 不同指标下的50 Ma以来pCO₂记录^{[

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Fig. 3 Cenozoic pCO₂ record from different proxies^{[

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The Application of Alkenone-Based pCO 2 Reconstructions

The Application of Alkenone-Based pCO ₂ Reconstructions