地球科学进展 ›› 2004, Vol. 19 ›› Issue (2): 211 -217. doi: 10.11867/j.issn.1001-8166.2004.02.0211

综述与评述 上一篇    下一篇

陆地水热系统气体地球化学研究进展
高博 1,2;陈践发 4;王先彬 3   
  1. 中国科学院地球化学研究所,贵州 贵阳 550002;云南大学地球科学系,云南 昆明 650091; 中国科学院兰州地质研究所,甘肃 兰州 730000;石油大学,北京
  • 收稿日期:2003-04-16 修回日期:2003-07-23 出版日期:2004-12-20
  • 通讯作者: 高博(1961-),男,甘肃兰州市人,博士后,主要从事地热流体地球化学方面的研究. E-mail:E-mail:gaobo1961@163.com

A REVIEW OF GAS GEOCHEMISTRY OF CONTINENTAL GEOTHERMAL SYSTEM

GAO Bo 1,2, CHEN Jianfa 4, WANG Xianbin 3   

  1. 1. Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550000,China;2.Yunnan University, Kunming,650091,China;3.Lanzhou Institute of Geology,Chinese Academy of Sciences, Lanzhou,730000,China;4.Petroleam University, Beijing 102249,China
  • Received:2003-04-16 Revised:2003-07-23 Online:2004-12-20 Published:2004-04-01

地表水热活动常伴有通量不等的气体释放,作为水-岩反应和地球深部脱气的产物,泉气的化学和同位素组成因其热储所处的大地构造单元、岩性和应力状态的差异而有所不同。对泉气化学和同位素组成时空变化的观测和研究是了解地壳-岩石圈动力学的重要方面,有助于地震、火山活动等地质灾害的监测和地热资源的开发利用。

Hot spring water and gases are always concomitant and the fluxes of gases released from different geothermal systems are various. As a  results of  water-rock reaction and degassing from the deep,the chemical and isotopic composition of geothermal spring gases are diverse because of different settings of the geothermal reservoir in the aspect of tectonic position, lithology and stress status. It is of significance to study the spatiotemporal changes of chemical and isotopic component of hot sprig gases and that may help us realize crust-lithosphere kinetic status. Furthermore, there will be application foreground in the monitoring or predicting earthquake and volcano activity as well as geothermal exploitation and utilization.

中图分类号: 

[1]Craig H. The isotopic geochemistry of water and carbon in geothermal areas[A]. In: Conference on Nuclear Geology in Geothermal Areas[C]. Italy: Spoleto,1963.17-53.
[2]Hearn E H, Kennedy B M, Truesdell A H. Coupled variations in helium isotopes and fluid chemistry: Shoshone geyser Basin, Yellowstone National Park[J].Geochimica et  Cosmochimica Acta, 1990,54: 3 103-3 113.
[3]Poreda R J, Craig H, Arnorsson S, et al. Heluim isotopes in Icelandic geothermal systems:I.3He, gas chemistry and 13C relations[J].Geochimica et Cosmochimica Acta,1992, 56: 4 221-4 228.
[4]Matthews A, Fouillac C, Hill R, et al. Mantledrived volatiles in continental crust: The Massif Central of France[J].Earth and  Planetary Science Letters,1987,85:117-128.
[5]Griesshaber E, O'Nions R K, Oxburgh E R. Helium and carbon isotope systematics in crustal fluids from the Eifel, the Rhine Graben and Black Forest, F.R.G[J]. Chemical Geology,1992,99: 213-235.
[6]Conides I. Magmatic cabon dioxide at the crust's surface in the Carpathian Basin[J].Geochemistry  Journal,1993,27(22): 241-249.
[7]Daling W G, Griesshaber E, Andrews J N, et al. The origin of hydrothermal and other gases in the Kenya Rift Valley[J].Geochimca et Cosmochimica Acta, 1995,59(12): 2 501-2 512
[8]Weinlich F H, Braeauer K, Kampf, et al. An active subcontinental mantle volatile system in the western Eger rift, Central Europe: Gas flux, isotopic (He, C, and N) and compositional fingerprints[J].Geochimca et Cosmochimica Acta,1999,63(21): 3 653-3 671.
[9]Polyak B G, Prasolov E M, Tolstikhin I N, et al. Helum isotopes in fluids of the Baykal Rift zone[J].International Geology review, 1993,2:186-202.
[10]Nagao K, Takaoka N, Matsubayashi O. Rare gas isotopic compositions in natural gasses of Japan[J].Earth and  Planetary Science Letters, 1981,53: 175-188.
[11]Kiyosu Y, Yoshida Y. Origin of gases from the Takinoue geothermal area in Japan[J].Geochemistry Journal, 1988, 22: 183-193.
[12]Giggenbarch W F, Sano Y, Wakita H. Isotopic composition of Helium, and CO2 and CH2 contents in gases produced along the New Zealand part of a convergent place boundary[J].Geochimica et Cosmochimica Acta, 1993,57: 3 427-3 455.
[13]Ono A, sano Y, Wakita H, et al. Carbon isotopes of menthane and carbon dioxide in hydrothermal gases of Japan[J].Geochemistry Journal,1993, 27: 287-295.
[14]Piperov N B, Kamensky I L, Tolstikhin I N. Isotopes of the light noble gases in mineral waters in the eastern part of the Balkan peninsula, Bulgaria[J].Geochimica et Cosmochimica Acta,1994,58:1 889-1 898.
[15]Gherardi F, Panichi C, Caliro S, et al. Water and gas geochenistry of the Euganean and Berician thermal district(Italy)[J].Applied Geochemistry, 2000,15:455-474.
[16]Minissale A, Vaselli O, Chandrasekharam D,et al. Origin and evolution of 'intracratonic' thermal fluids from central-western peninsular India[J]. Earth and Planetary  Science Letters,2000,181: 377-394.
[17]Sano Y, Urabe A, Wakita H, et al. Origin of hydrogennitrogen gas seeps, Oman[J].Applied Geochemistry, 1993, 8: 1-8.
[18]Torgersen T. Terrestrial helium degassing fluxes and the atmospheric helium budget: Implications with respect to the degassing processes of continental crust[J].Chemical Geology,1989,79:1-14.
[19]Mamyrin B A, Tolstikhin I N. Helium Isotopes in Nature[M]. Amsterdam: Elsvier,  1984. 273.
[20]Drubetskoy Y R, Matukov D I, Lokhov K I.Noble gases and volatiles in the minerals of some metamorphic rocks: The search for a mantle component[J].International Geology Review,1991:142-149.
[21]Tolstikhin I N, Dokuchayeva V S, Kamenskiya I L. Juvenile He in ancient rocks: He, Ar, U,and K in the Monchegora Pluton, Kola Peninsula[J].Geochimiky(in Russian), 1991,8:1 146-1 158.
[22]Minissale A,Eans W C, Magro G, et al. Mutiple source components in gas manifestations from north-central Italy,1992[J].Chemical Geology, 1997,142:175-192.
[23]Allard P, Jean_Baptiste P, D'Alessandro W, et al. Mantle-derived helium and carbon in ground waters and gases of Mount Etna, Italy[J].Earth and Planetary Science Letters,1997, 148:501-516.
[24]Zhao Ping(赵平), Dujirang(多吉), Liang Tingli(梁廷立),et al. Gas geochemistry of Yangbajing geothermal field, Tibet[J].Chinese Science Bulletin(科学通报), 1998,43(7):691-696(in Chinese)
[25]Yokoyama T, Nakai  S, Wakita H. He, C isotopic compositions of  hot springs in Tibetan plateau[J]. Journal of Vocanology and Geothermal Research,1999,88(1~2):99-107.
[26]Spiro B, Hoke L, Chenery C. Carbon-isotope characteristics of CO2 and CH2 in geothermal springs from the Central Andes[J].International Geology Review,1997,39:938-947.
[27]Marty B, O'Nions R K, Oxburgh E R, et al. Helium isotopes in Alpine regions[J].Tectonophysics,1992, 206:71-78.
[28]Andrews J N, Goldbrunner J E, Darling W G,et al. A radiochemical, hydrochemical and dissolved gas study of groundwater in the Molasse basin of Upper Austria[J]. Earth and Planetary Science Letters,1985, 73:317-332.
[29]Andrews J N, Hussain N, Youngman M J. Atmospheric and radiogenic gases in  groudwaters from the Stripa granite[J]. Geochimica et Cosmochimica Acta,1989, 53:1 831-1 841.
[30]Solomon D K, Hunt A, Poreda J. Source of radiogenic helium 4 in shallow aquifers: Implications for dating young groundwater[J].Water Resource Research,1996,32(6):1 805-1 803.
[31]SharifZade V B, Verkhovskiy A B, Loktev V A, et al. Inert-gas isotopes in south Pamir nitrogen-thermal and CO2 waters[J].Geokhimiya(in Russian), 1988, 8:1 187-1 198.
[32]Martel D J, O'Nions R K, Hillton D R, et al. The role of element distribution in production and release of radiogenic helium: The Carnmenellis Grantite, southwest England[J]. Chemical Geology, 1990, 88:207-221.
[33]Torgersen T, Habermehl M A, Clarke W B. Crustal helium fluxes and heat flow in the Great Artesian Basin, Australia[J].Chemical Geology, 1992,102:139-152.
[34]Xu Yongchang(徐永昌), Wang Xianbin(王先彬), Wu Renming(吴仁铭), et al. Noble gas isotopes of in natural gases[J].Geochimica(地球化学), 1979, 4:271-282(in Chinese)
[35]Sun Mingliang(孙明良). Measurement technology of noble gas isotopes in natural gases[J].Acta Sedimentologica Sinica(沉积学报), 2001,19(2):270-275(in Chinese)
[36]Ballentine C J, O'Nions R K, Oxburgh E R, et al. Rare gas constraints on hydrocarbon accumulation, crustal degassing and groundwater flow in the Pannonian Basin[J].Earth and  Planetary Science Letters,1991,105: 229-246.
[37]Drescher J, Kirsten T, Schafer K. The rare gas inventory of the continental crust, recovered by the KTB Continental Deep Drilling Project[J].Earth and  Planetary Science Letters,1998, 154:247-263.
[38]Marty B, Gunnlaugsson E, Jambon A, et al. Gas geochemistry of geothermal fluids, the Hengill area, southwest rift zone of Iceland[J].Chemical Geology, 1991,91:207-225.
[39]Tolstikhin I N, Ddokuchaeva V S, Kamensky I L. Juvenile helium in ancient rocks: Ⅱ. U-He, K-Ar,Sm-Nd, and Rb-Sr systematics in the Monche Pluton.3He/4He rations frozen in uraniumfree ultramafic rocks[J]. Geochimica et Cosmochimica Acta, 1992,56:987-999.
[40]Wang Xianbin(王先彬), Xu Sheng(徐胜), Cheng Jianfa(陈践发), et al. The characters of hot spring gass and helium isotopic component[J].Chinese Science Bulletin(科学通报), 1993,38(9):814-817(in Chinese)
[41 ]Dai Jinxin(戴金星), Dai Chunsen(戴春森), Song Yan(宋岩), et al.Natural gas Geochemistry of warm springs and the isotopic components of C, He in some areas of China[J].Science in  China(B)(中国科学,B辑),1994,24(4):426-433(in Chinese)
[42]Shangguan Zhiguan(上官志冠),Bai Chunhua(白春华), Sun Mingliang(孙明良). Character of magma gas release derived from mantle , Rehai, Tengchong geothermal area[J].Science in  China(D)(中国科学,D辑)),2000,30(4): 407-414(in Chinese)
[43]Shangguan Zhiguan(上官志冠), Zheng Yaqin(郑雅琴), Dong Jichuan(董继川). The source of gases released  from Tianchi volcanic geothermal area Changbaishan Mountains[J].Science in  China(D)(中国科学,D辑),1997,27(4):318-324(in Chinese)
[44]Du Jianguo(杜建国), Li Shengqiang(李圣强), Liu Lianzhu(刘连柱), et al.Geochemistry of gases from Wudalianchi volcanic district, northeastern China[J].Geochimica(地球化学), 1999,28(2):171-176(in Chinese)
[45]Xu Yongchang(徐永昌), Shen Ping(沈平),Sun Mingliang(孙明良). Nonhydrocarbon and noble gas geochemistry of natural gases from eastern China[J].Science in  China(B)(中国科学,B辑), 1990,6:645-651(in Chinese)
[46]Shangguan Zhiguan(上官志冠), Dujirang(都吉), Zang Wei(臧伟). Geothermal fluid geochemistry of Tan-lu fault belts and Jiaoliao fault block[J].Science in  China(D)(中国科学,D辑), 1998,28(1):23-29(in Chinese)
[47]Liu Deliang(刘德良),Tao Shizhen(陶士振),Zhang Chaoming(张朝明). Gas geochemistry of thermal springs in Tanlu fault belts[J].  Geological Journal of China Universities(高校地质学报), 2001,7:81-86(in Chinese)
[48]Jiang Shan(蒋珊). The isotopic components of warm springs and natural gases in Tanlu fault belts and its structure activity[J].Geology and Geochemistry(地质地球化学), 1992,5:87-89(in Chinese)
[49]Wang Jihua(王基华), Lin Yuanwu(林元武), Liu Chenglong(刘成龙),et al.Evidence of H, O stable isotope and gas components for the formation of warm springs in south of Zhangjiakou district[J].Hydrogeology and Engineering Geology(水文地质工程地质), 2000,4:30-33(in Chinese)
[50]Zhang Weimin(张卫民). The application of hydrogeochemistry  methods in geothermal water source analysis, Hengjin district, south of Jiangxi Province[J].Hydrogeology and Engineering Geology(水文地质工程地质), 2001,4:45-48(in Chinese)
[51]Wang Xianbin(王先彬), Xu Sheng(徐胜), Cheng Jianfa(陈践发), et al. Gas geochemistry of warm springs in earthquake areas[J].Science in  China(B)(中国科学,B辑), 1992,8:849854(in Chinese)
[52]Wang Wei(王蔚),Zhang Jingrong(张景荣),Hu Guixing(胡桂兴),et al. Geochemistry of warm springs in northweat of Hunan Province[J]. Science in  China(B)(中国科学,B辑), 1995,24(4):427-433.(in Chinese)
[53]Du Jianguo,  Cheng W, et al. Isotope geochemical characteristics  of thermal springs in earthquake zone of Sichuan, China[J].Journal of Asia Earth Science,2004 (in press).
[54]Liu Zaihua(刘再华), Yuan Daoxian(袁道先), He Shiyi(何师意), et al. The geochemistry of CO2  -water-carbonate rock in geothermal systems and the orign of CO2[J]. Science in  China(D)(中国科学,D辑), 2000,30(2):208-214(in Chinese)
[55]Honda M, Kurita K, Hamano Y, et al. Experimetal studies of He and degassing during rock fracturing[J].Earth and Planetary Science Letters, 1982, 59:429-436.
[56]Torgersen T, O'Donnel J. The degassing flux from the solid Earth: Release by fracture[J].Geophysical Research Letters, 1991, 18(5):951-954.
[57]Sugisaki R, et al. Gas geochemical changes at mineral springs associated with 1995 southern Hyogo earthquake(M=7.2), Japan[J].Earth and Planetary Science Letters, 1996, 139:239-249.
[58]Tedesco D, Scarsi P. Chemical (He, H2, CH2, Ne, Ar, N2) and isotopic (He,Ne,Ar,C) variations at the Solfatara crater(south Italy): Mixing of Different source in relation to seismic activity[J].Earth and Planetary Science Letters,1999, 171:465-480.
[59]Sorey M L, Kennedy B M, Evans W C, et al. Helium isotope and gas discharge variations associated with crustal unrest in Long Valley Caldera, California, 1989-1992[J]. Journal of Geophysical Research, 1993,98(B9): 15 871-15 889.
[60]Minissale A, Vaselli O, Tassi F,et al. Fluid mixing in the carbonate aquifers near Rapolano(central Italy): Chemical and isotopic constraints[J].Applied Geochemistry, 2002, 17: 1 329-1 342.
[JP3][61]Darling W G. Hydrthermal hydrocarbon gases: I, Genesis and geothermometry[J]. Applied Geochemistry, 1998, 13(7):815-824.
[62]Wang Yang(汪洋). Estimations of the ratio of crust/mantle heat flowusing helium isotope ratio of underground fluid[J].Chinese Journal of Geophysics(地球物理学报), 2000,43(6):762-770(in Chinese)
[63]Hirner A V, Feldmann J, Krupp E, et al. Metal(loid)organic compounds in geothermal gases and waters[J].Organic Geochemistry,1998,29(5-7):1 765-1 778.
[64]Grgory K D, Philip E R. Nonmagmatic fracturecontrolled hydrothermal systems in the Idaho Batholith, South Fork Payette geothermal system[J].Chemical Geology, 2001,173:271-291.
[65]Chen Moxiang(陈墨香), Wang Jiyang(汪集旸).Review and prospect on geothermal studies in China[J].Acta Geophysica Sinica(地球物理学报),1994,37(supp.1):320338(in Chinese).

[1] 陈璐,孙若愚,刘羿,徐海. 海洋铜锌同位素地球化学研究进展[J]. 地球科学进展, 2021, 36(6): 592-603.
[2] 储著银, 许继峰. 铼—锇同位素和铂族元素分析方法及地学应用进展[J]. 地球科学进展, 2021, 36(3): 245-264.
[3] 闫雅妮, 张伟, 张俊文, 任亚雄, 赵志琦. 大陆硅酸盐岩石风化过程中镁同位素地球化学研究进展[J]. 地球科学进展, 2021, 36(3): 325-334.
[4] 张子洋, 闫明, MULVANEY Robert, 季峻峰, 效存德, 刘雷保, 安春雷. 东南极 LGB69冰芯 17122001年气温变化记录的初步研究[J]. 地球科学进展, 2021, 36(2): 172-184.
[5] 梁承弘, 鹿化煜. 风成沉积物叶蜡氢同位素在揭示东亚季风区干湿变化中的原理及应用[J]. 地球科学进展, 2021, 36(1): 45-57.
[6] 单森,齐远志,罗春乐,付文静,薛跃君,王旭晨. 中国主要河流输送陆源碳的同位素特征及影响因素[J]. 地球科学进展, 2020, 35(9): 948-961.
[7] 李旭明,李来峰,王浩贤,王野,陈旸. 土壤中次生与碎屑组分的差异性剥蚀[J]. 地球科学进展, 2020, 35(8): 826-838.
[8] 赖正,苏妮,吴舟扬,连尔刚,杨承帆,李芳亮,杨守业. 流域风化过程稳定锶同位素的分馏与示踪[J]. 地球科学进展, 2020, 35(7): 691-703.
[9] 余小灿,刘成林,王春连. 锂同位素地球化学在大陆地热体系研究中的应用[J]. 地球科学进展, 2020, 35(3): 246-258.
[10] 朱艳宸,李丽,王鹏,贺娟,贾国东. 海洋氮循环中稳定氮同位素变化与地质记录研究进展[J]. 地球科学进展, 2020, 35(2): 167-179.
[11] 常鑫,张明宇,谷玉,王厚杰,刘喜停. 黄、东海陆架泥质区自生黄铁矿成因及其控制因素[J]. 地球科学进展, 2020, 35(12): 1306-1320.
[12] 周涛, 蒋壮, 耿雷. 大气氧化态活性氮循环与稳定同位素过程:问题与展望[J]. 地球科学进展, 2019, 34(9): 922-935.
[13] 温学发,张心昱,魏杰,吕斯丹,王静,陈昌华,宋贤威,王晶苑,戴晓琴. 地球关键带视角理解生态系统碳生物地球化学过程与机制[J]. 地球科学进展, 2019, 34(5): 471-479.
[14] 马晓旭,刘传联,金晓波,张洪瑞,马瑞罡. 长链烯酮在古大气二氧化碳分压重建的应用[J]. 地球科学进展, 2019, 34(3): 265-274.
[15] 秦瑞,史贵涛,陈振楼. 大气硝酸盐中氮氧稳定同位素研究进展[J]. 地球科学进展, 2019, 34(2): 124-139.
阅读次数
全文


摘要