地球科学进展 ›› 2017, Vol. 32 ›› Issue (8): 828 -838. doi: 10.11867/j.issn.1001-8166.2017.08.0828

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穿透性地球化学勘查技术综述与展望
韩志轩 1, 2, 3( ), 廖建国 3, 张聿隆 3, 张必敏 1, 2, 王学求 1, 2, *( )   
  1. 1.国土资源部地球化学探测技术重点实验室,中国地质科学院地球物理地球化学勘查研究所, 河北 廊坊 065000
    2.联合国教科文组织全球尺度地球化学国际研究中心,河北 廊坊 065000
    3.中国地质大学(北京),地球科学与资源学院,北京 100083
  • 收稿日期:2017-02-13 修回日期:2017-06-12 出版日期:2017-10-20
  • 通讯作者: 王学求 E-mail:hanzhixuan@igge.cn;wangxueqiu@igge.cn
  • 基金资助:
    国家重点研发计划项目“穿透性地球化学勘查技术”(编号:2016YFC0600608);中国地质科学院地球物理地球化学勘查研究所中央级公益性科研院所基本科研业务费专项资金资助项目(编号:AS2014J03)资助

Review of Deep-Penetrating Geochemical Exploration Methods

Zhixuan Han 1, 2, 3( ), Jianguo Liao 3, Yulong Zhang 3, Bimin Zhang 1, 2, Xueqiu Wang 1, 2, *( )   

  1. 1.Key Laboratory of Geochemical Exploration, MLR, Institute of Geophysical and Geochemical Exploration, CAGS,Langfang Hebei 065000, China
    2.UNESCO, International Center on Global-scale Geochemistry, Langfang Hebei 065000, China
    3.School of Earth Sciences and Resources, China University of Geosciences(Beijing), Beijing 100083, China
  • Received:2017-02-13 Revised:2017-06-12 Online:2017-10-20 Published:2017-08-20
  • Contact: Xueqiu Wang E-mail:hanzhixuan@igge.cn;wangxueqiu@igge.cn
  • About author:

    First author:Han Zhixuan(1987-), male, Hengshui City, Hebei Province, Engineer. Research areas include applied geochemistry.E-mail:hanzhixuan@igge.cn

  • Supported by:
    Project supported by the National Key Research and Development Program of China “Deep-penetrating geochemistry project”(No.2016YFC0600608);The National Nonprofit Institute Research Grant of IGGE(No.AS2014J03)

穿透性地球化学勘查技术通过获取覆盖层不同介质中的穿透性信息,以此达到指示隐伏矿体的目的。系统总结了活动态金属离子测量、酶提取测量、金属元素活动态测量、地电化学技术、植物地球化学技术、地气测量等几种穿透性地球化学勘查方法的理论基础和实际应用效果。指出今后应该加强元素迁移机理、元素卸载机制及元素卸载后在地表表现出的异常模式等异常形成机理研究,并进一步总结和研究穿透性地球化学勘查技术的矿种和景观适用性问题,从经济适用性角度出发,各种勘查技术要向着简化采样、分析流程和提高方法技术的稳定性努力,以便更加高效经济地开展覆盖区找矿工作。

It is a worldwide challenge to explore the deeply buried deposits. Deep-penetrating geochemical exploration methods were developed to solve the problems of how to get the information of the buried deposits in the covered layer. The methods were successfully used to indicate some buried deposits, but not all kinds of deposits. What is more, a method cannot be used in all kinds of landscapes. In this paper, theories and case studies of deep-penetrating geochemical exploration methods, including mobile metal ions, enzyme leach, leaching of mobile forms of metals in overburden, electro-geochemical extraction method, biogeochemical exploration, nano-metal in geogas were reviewed. Elements migration, unloading mechanism and anomaly models are the most important parts for deep-penetrating geochemistry and need to be further investigated. From the perspective of economic efficiency and applicability, sampling and analyzing procedures should be simplified to improve the stability of all methods.

中图分类号: 

[1] Wang Xueqiu.Conceptual model of deep-penetrating geochemical migration[J].Geological Bulletin of China, 2005,24(10/11):18-22.
[王学求. 深穿透地球化学迁移模型[J]. 地质通报, 2005, 24(10/11):18-22.]
[2] Wang Xueqiu.Deed penetration exploration geochemistry[J].Geophysical & Geochemical Exploration,1998, 22(3): 166-169.
[王学求. 深穿透勘查地球化学[J]. 物探与化探,1998, 22(3): 166-169.]
[3] Ryss Yu, Goldberg I.The partial extraction of metals (CHIM) method in mineral exploration[J].Method and Technique, ONTI, VITR, Leningrad, 1973, 84:5-19.
[4] Clark J.Enzyme-induced leaching of B-horizon soils for mineral exploration in areas of glacial overburden[J]. Transactions of the Institution of Mining and Metallurgy Section B—Applied Earth Science, 1993, 102: B19-B29.
[5] Mann A, Birrell R, Mann A, et al.Application of the mobile metal ion technique to routine geochemical exploration[J].Journal of Geochemical Exploration, 1998, 61(1): 87-102.
[6] Wang Xueqiu, Cheng Zhizhong, Lu Yinxiu, et al.Nanoscale metals in earthgas and mobile forms of metals in overburden in wide-spaced regional exploration for giant deposits in overburden terrains[J]. Journal of Geochemical Exploration, 1997, 58(1): 63-72.
[7] Wang Xueqiu.Leaching of mobile forms of metals in overburden: Development and application[J]. Journal of Geochemical Exploration, 1998, 61(1/3): 39-55.
[8] Cameron E, Hamilton S, Leybourne M, et al.Finding deeply-buried deposits using geochemistry[J].Geochemistry-Exploration, Environment, Analysis, 2004, 4(1): 7-32.
[9] Bajc A.A comparative analysis of enzyme leach and mobile metal ion selective extractions: Case studies from glaciated terrain, Northern Ontario[J].Journal of Geochemical Exploration, 1998, 61(1/3): 113-148.
[10] Clark J, Meier A, Riddle G.Enzyme leaching of surficial geochemical samples for detecting hydromorphic trace-element anomalies associated with precious-metal mineralized bedrock buried beneath glacial overburden in northern Minnesota[C]∥Proceedings of the Gold’90 Symposium-Gold’90. 1990: 189-207.
[11] Williams T, Gunn A.Application of enzyme leach soil analysis for epithermal gold exploration in the Andes of Ecuador[J].Applied Geochemistry, 2002, 17(4): 367-385.
[12] Yeager J, Clark J, Mitchell W, et al.Enzyme leach anomalies associated with deep Mississippi Valley-type zinc ore bodies at the Elmwood Mine, Tennessee[J].Journal of Geochemical Exploration, 1998, 61(1/3): 103-112.
[13] Wang Xueqiu.Delineation of geochemical blocks for undiscovered large ore deposits using deep-penetrating methods in alluvial terrains of eastern China[J].Journal of Geochemical Exploration, 2003, 77(1): 15-24.
[14] Wang Xueqiu, Xie Xuejin, Cheng Zhizhong, et al.Delineation of regional geochemical anomalies penetrating through thick cover in concealed terrains—A case history from the Olympic Dam deposit, Australia[J]. Journal of Geochemical Exploration, 1999, 66(1): 85-97.
[15] Xie Xuejin, Wang Xueqiu, Xu Li, et al.Orientation study of strategic deep penetration geochemical methods in the central Kyzylkum Desert Terrain, Uzbekistan[J]. Journal of Geochemical Exploration, 1999, 66(1/2): 135-143.
[16] Mann A, Reimann C, de Caritat P, et al. Mobile Metal Ion (R) analysis of European agricultural soils: Bioavailability, weathering, geogenic patterns and anthropogenic anomalies[J]. Geochemistry-Exploration Environment Analysis, 2015, 15(2/3): 99-112.
[17] Sadeghi M, Albanese S, Morris G, et al.REE concentrations in agricultural soil in Sweden and Italy: Comparison of weak MMI (R) extraction with near total extraction data[J]. Appled Geochemistry,2015, 63: 22-36.
[18] Wen Xueqin.Deep-penetrating Geochemistry: Theoretical Consideration,Methodology and Application in Desert Terrain[D]. Xi’an:Chang’an University,2008.
[文雪琴. 荒漠戈壁区深穿透地球化学的理论方法及应用研究[D].西安:长安大学,2008.]
[19] Wang Xueqiu.Leaching of mobile forms of metals in overburden: Development and application[J]. Journal of Geochemical Exploration, 1998, 61(1/3): 39-55.
[20] Tan Chenglong.Preliminary experiment on measuring technique for mobile forms of metals in overburdens in the exploration of interlayer oxidation zone sandstone-type Uranium deposits[J].World Nuclear Geoscience, 2005,22(4):231-235.
[谈成龙. 金属活动态测量方法在层间氧化带砂岩型铀矿勘查中的初步试验[J].世界核地质科学,2005,22(4):231-235. ]
[21] Liu Hongyan, Wang Xueqiu.Application of selective leaching of mobile metal forms on the exploration for sandstone-type Uranium deposit in Shihongtan, Xinjiang, China[J].Journal of Jilin University(Earth Science Edition),2006, 36(2): 183-186.
[刘红艳,王学求. 金属活动态提取技术在十红滩铀矿的应用[J]. 吉林大学学报:地球科学版,2006, 36(2): 183-186.]
[22] Ge Wei, Zhu Shu, Zhang Xin.Chromatography method to extract uranium in mobile forms from soil samples and its significance for uranium ore prospecting[J]. Uranium Geology, 2009, 25(1): 45-49,54.
[葛玮,朱姝,张鑫.层析法提取土壤样品中活动态铀及其找矿意义[J].铀矿地质, 2009, 25(1):45-49,54.]
[23] Xie Xuejin, Wang Xueqiu.Recent developments on deep-penetrating geochemistry[J]. Geoscience Frontiers, 2003,10(1): 225-238.
[谢学锦,王学求. 穿透性地球化学新进展[J]. 地学前缘, 2003, 10(1): 225-238.]
[24] Lin Chuan.Application of selective leaching of mobile metal forms on the exploration for Duo-long mineralize area, Ali, Tibet[J].China Science and Technology Information, 2014,(3/4):76-78.
[林川. 金属活动态提取技术在多龙铜矿区的应用[J].中国科技信息,2014,(3/4):76-78.]
[25] Liu Hanliang, Wang Xueqiu, Zhang Bimin, et al.Geochemical exploration for concealed Cu-Ni deposit, Shaquanzi, Xinjiang[J]. Computing Techniques for Geophysical and Geochemical Exploration, 2014, 36(6):763-770.
[刘汉粮,王学求,张必敏,等.沙泉子隐伏铜镍矿地球化学勘查方法试验[J].物探化探计算技术,2014, 36(6):763-770.]
[26] Nie Lanshi, Cheng Zhizhong, Wang Xueqiu, et al.Comparative study of deep-penetrating geochemical methods: A case study of the Hua'obote lead-zinc deposits, Inner Mongolia, China[J]. Geological Bulletin of China, 2007, 26(12):1 574-1 578.
[聂兰仕,程志中,王学求,等.穿透性地球化学方法对比研究——以内蒙古花敖包特铅锌矿为例[J].地质通报,2007, 26(12):1 574-1 578.]
[27] Song Leiying.Analysis on the test results of MOMEO of Haruleaobao Mining area, Xinbaerhu Right Banner, Inner Mongolia[J]. Sci-tech Information Development & Economy, 2010, 20(7):174-176.
[宋雷鹰. 内蒙古哈如勒敖包矿区金属活动态测量的试验效果[J].科技情报开发与经济,2010, 20(7):174-176.]
[28] Wen Xueqin.Application of selective leaching of mobile metal forms in forestry terrain, Daxing’anling, Heilongjiang[J].Journal of Earth Sciences and Environment, 2006, 28(4):43-48.
[文雪琴. 金属活动态提取法及其在黑龙江大兴安岭森林覆盖区的应用[J].地球科学与环境学报, 2006, 28(4):43-48.]
[29] Cheng Zhizhong, Wang Xueqiu, Yu Jinsong.Application of deep-penetration geochemistry in Loess Terrain: A case of Zhangquanzhuang Gold Deposit[J].Mineral Deposits, 2002, 21(Suppl.1):1 124-1 127.
[程志中,王学求,喻劲松.深穿透性地球化学方法在黄土覆盖区的应用——张全庄金矿试验实例[J].矿床地质,2002,21(增刊1):1 124-1 127.]
[30] Wen Xueqin.Application of selective leaching of mobile metals in red earth and loess terrain[J].Journal of Earth Sciences and Environment, 2007, 29(4):369-373.
[文雪琴. 金活动态测量法在红壤区与干旱黄土区找矿中的应用[J].地球科学与环境学报,2007, 29(4):369-373.]
[31] Hu Zhongxian, Yu Yuanbang.The combination of effective geochemical methods in search for concealed ore deposits from region to ore district in the forest-swamp area[J].Geophysical & Geochemical Exploration, 2009,33(1):35-37,42.
[胡忠贤,于援帮.森林沼泽区从区域到矿区有效寻找隐伏矿的地球化学方法组合[J].物探与化探,2009, 33(1):35-37,42.]
[32] Zhao Bo, Gong Min, Xiong Ran, et al.Soil metallic active state prospecting test under the condition of humid low-mountain landscape[J].Geophysical & Geochemical Exploration, 2012,36(6):902-906.
[赵波,龚敏,熊燃,等.湿润中低山景观条件下土壤金属活动态找矿试验[J].物探与化探,2012,36(6):902-906.]
[33] Huang Guizhen.Overview of new prospecting methods of Gobi-overburden area[J].Resources Environment & Engineering, 2014, 28(1):69-73.
[黄桂珍. 荒漠戈壁覆盖区的矿产勘查技术探讨[J]. 资源环境与工程, 2014, 28(1):69-73.]
[34] Zhang Bimin, Wang Xueqiu, He Ling,et al.Geochemical exploration for concealed deposits on semi-arid grasslands of Inner Mongolia[J]. Geophysical & Geochemical Exploration, 2013, 37(5): 804-810.
[张必敏,王学求,贺灵,等. 内蒙古半干旱草原区隐伏矿地球化学勘查方法试验[J]. 物探与化探,2013, 37(5): 804-810.]
[35] Tong Chunhan, Li Juchu, Ge Liangquan, et al.Experimental observation of the nano-scale particles in geogas matters and its geological significance[J]. Science in China (Series D), 1998, 28(2):153-156.
[童纯菡,李巨初,葛良全,等.地气物质纳米微粒的实验观测及意义[J].中国科学:D辑,1998, 28(2):153-156.
[36] Wang Xueqiu. Concepts, Theories,Methods of Nano-metals in Earth Gas[M]. Beijing: Geological Publishing House, 1999:105-124.
[王学求. 地球气纳微金属测量的概念、理论与方法[M]. 北京:地质出版社, 1999:105-124.]
[37] Zhou Ziyong, Tao Shu, Xu Fuliu, et al.A physical-mathematical model for the transport of heavy metals and toxic matter from point sources by geogas microbubbles[J]. Ecological Modeling, 2003, 161(1): 139-149.
[38] Wang Mingqi, Gao Yuyan.Tracing source of geogas with lead isotopes: A case study in Jiaolongzhang Pb-Zn deposit, Gansu Province[J].Geoochemistry,2007,36(4): 391-399.
[汪明启, 高玉岩. 利用铅同位素研究金属矿床地气物质来源:甘肃蛟龙掌铅锌矿床研究实例[J]. 地球化学, 2007, 36(4):391-399.]
[39] Zhou Sichun,Liu Xiaohui, Tong Chunhan, et al.Application research of geogas survey in prospecting concealed ore[J].Acta Geologica Sinica,2014,88(4):736-754.
[周四春,刘晓辉,童纯菡,等.地气测量技术及在隐伏矿找矿中的应用研究[J].地质学报,2014,88(4):736-754.]
[40] Liu Bin, Zhou Sichun, Ge Liangquan, et al.Geogas anomaly characteristics of the Huangshaping Lead-Zinc Deposit in the Qianlishan-Qitianling Ore concentration area and their prospecting significance in South Hunan[J].Acta Geoscientica Sinica, 2011,32(4):413-418.
[刘斌,周四春,葛良全,等.湘南千里山—骑田岭矿集区黄沙坪型铅锌矿地气异常特征及找矿意义[J].地球学报,2011,32(4):413-418.]
[41] Tong Chunhan, Li Juchu, Ge Liangquan, et al.Transportation of the ore-forming matters by ascending gas flows in the crust and the mechanism of geogas prospecting[J].Journal of Mineralogy and Petrology, 1997,17(3):84-89.
[童纯菡,李巨初,葛良全,等.地壳内上升气流对物质的迁移及地气测量原理[J].矿物岩石,1997,17(3):84-89.]
[42] Liu Xiaohui, Zhou Sichun, Tong Chunhan, et al.A study of element migration regularity in geogas model[J]. Geophysical & Geochemical Expolration, 2012,36(6):1 050-1 054.
[刘晓辉,周四春,童纯菡,等.地气模型中元素迁移规律[J].物探与化探,2012,36(6):1 050-1 054.]
[43] Hu Bo, Zhou Sichun, Liu Xiaohui, et al.Geogas survey experiment for exploration of concealed polymetallic deposit at great depth[J].Geophysical & Geochemical Expolration, 2012,36(6):1 068-1 072.
[胡波,周四春,刘晓辉,等.大深度隐伏多金属矿地气探测试验[J].物探与化探,2012,36(6):1 068-1 072.]
[44] Yang Fenggen, Tong Chunhan.Geogas anomaly and mechanism in Xuanhan Gas Field[J]. Earth Science—Journal of China University of Geosciences, 2000,25(1):103-106.
[杨凤根,童纯菡.宣汉气田的地气测量及其机理研究[J].地球科学,2000,25(1):103-106.]
[45] Ding Xitong, Zhou Sichun.Geochemical characteristics of earth-gas of lead-zinc deposits in Dongshan package exploration of Western Yunnan[J]. Advances in Earth Science,2012,27(Suppl.1):9-10.
[丁西同,周四春. 滇西东山整装勘查区铅锌矿地气与地球化学特征[J]. 地球科学进展,2012,27(增刊1):9-10.]
[46] Cao Jianjin, Hu Ruizhong, Xie Guiqing.Migration of geogas-carrying gold nanoparticles in Quaternary sediments[J]. Geochimica et Cosmochimica Acta (Special Supplement), 2005, 69(10): A519.
[47] Cao Jianjin, Hu Ruizhong, Liang Zhirong, et al.TEM observation of geogas-carried particles from the Changkeng concealed gold deposit, Guangdong Province, South China[J]. Journal of Geochemical Exploration, 2009, 101(3):247-253.
[48] Cao Jianjin, Hu Xianyong, Jiang Zhongtao, et al.Experimental simulation of adsorption of geogas-carried gold nanoparticles in alluvial cover of the middle-lower reaches of the Yangtze River[J]. Geofluids, 2010, 10(3): 438-446.
[49] Cao Jianjin.Characteristics, formation and migration of the particles carried by ascending gas flow from the concealed metal deposits[J]. Geoscience Frontiers, 2012, 19(3):113-119.
[曹建劲. 隐伏金属矿床上升气流微粒特征、形成及迁移[J].地学前缘, 2012, 19(3):113-119.]
[50] Wei Xiaojun, Cao Jianjin, Holub R, et al.TEM study of geogas-carried nanoparticles from the Fankou lead-zinc deposit, Guangdong Province, South China[J]. Journal of Geochemical Exploration, 2013, 128:124-135.
[51] Luo Songying, Cao Jianjin, Yan Hongbin, et al.TEM observations of particles based on sampling in gas and soil at the Dongshengmiao polymetallic pyrite deposit, Inner Mongolia, Northern China[J]. Journal of Geochemical Exploration, 2015, 158: 95-111
[52] Wang Xueqiu, Zhang Bimin, Liu Xuemin.Nanogeochemistry: Deep-penetrating geochemical exploration through cover[J]. Geoscience Frontiers, 2012, 19(3): 101-112.
[王学求,张必敏,刘雪敏. 纳米地球化学:穿透覆盖层的地球化学勘查[J]. 地学前缘,2012, 19(3): 101-112.]
[53] Ye Rong, Zhang Bimin, Yao Wensheng, et al.Occurrences and formation of copper nanoparticles over the concealed ore deposits[J]. Geoscience Frontiers, 2012, 19(3): 120-129.
[叶荣, 张必敏, 姚文生, 等. 隐伏矿上方纳米铜颗粒存在形式与成因[J]. 地学前缘, 2012, 19(3): 120-129.]
[54] Liu Xuemin, Chen Yuelong, Wang Xueqiu.Research on isotope identification for anomalous sources of deep-penetration geochemistry: Two cases of Jinwozi Au deposit,Xinjiang and Bairendaba-Weilasituo polymetallic deposit,Inner Mongolia[J]. Geoscience, 2012, 26(5): 1 104-1 116.
[刘雪敏, 陈岳龙, 王学求. 穿透性地球化学异常源同位素识别研究: 以新疆金窝子金矿床、内蒙古拜仁达坝—维拉斯托多金属矿床为例[J]. 现代地质, 2012, 26(5): 1 104-1 116.]
[55] Zhu Jian, Zhou Sichun, Liu Jun, et al.Discussion on factors influencing the effects of geogas methods[J]. Modern Mining,2014,(1):62-64,96.
[朱剑,周四春,刘俊,等. 影响地气测量结果有关因素的讨论[J]. 现代矿业, 2014,(1):62-64,96.]
[56] Wang Yunqi.To improve the efficiency of catching review geogas method set[J].World Nonferrous Metal,2016, 13:179-180.
[王昀颀. 提高地气测量捕集效率方法综述[J].世界有色金属,2016, 13:179-180.]
[57] Zhao Hongtao, Zhang Qinghua.The present application status of deep geochemical penetration method for mineral prospecting[J].Contributions to Geology and Mineral Resources Research,2010,25(3):196-200,211.
[赵洪涛,张庆华.深穿透化探方法及在矿产勘查中的应用[J].地质找矿论丛,2010,25(3):196-200,211.]
[58] Li Jinming, Lu Jun, Yan Liangjun.Theoretical and experimental study for geoelectrochemical extraction method[J].Geoscience Frontiers,1998, 5(2):39-47.
[李金铭,卢军,严良俊. 地电化学提取法的理论与实验研究[J]. 地学前缘, 1998, 5(2):39-47.]
[59] Kang Ming, Luo Xianrong.The present and future of electrogeochemical method for metallicore deposit prospecting[J].Geological Review, 2005, 51(4):452-457.
[康明,罗先熔.金属矿床地电化学勘查方法研究现状及前景展望[J].地质论评,2005, 51(4):452-457.]
[60] Luo Xianrong.The Mechanism of Electrogeochemical Halo-formation and the Application of Electrogeochemical Method to Exploration of Metallic Ore Deposits[D].Hefei: Hefei University of Technology,2005.
[罗先熔. 地电化学成晕机制、方法技术及找矿研究[D]. 合肥:合肥工业大学,2005.]
[61] Sun Binbin, Liu Zhanyuan, Zhou Guohua.Research status and development trends for geoelectrochemical methods[J].Geophysical & Geochemical Exploration, 2015,39(1):16-21.
[孙彬彬,刘占元,周国华.地电化学方法技术研究现状及发展趋势[J].物探与化探,2015,39(1):16-21.]
[62] Sun Binbin, Zhang Xuejun, Liu Zhanyuan, et al.A preliminary study of the formation mechanism of the geoelectric chemistry anomaly[J].Geophysical & Geochemical Exploration, 2015, 39(6):1 183-1 187.
[孙彬彬,张学君,刘占元,等.地电化学异常形成机理初探[J].物探与化探, 2015, 39(6):1 183-1 187.]
[63] Sun Binbin, Liu Zhanyuan, Zhou Guohua.The development of the solid carrier elements extractor[J].Geophysical & Geochemical Exploration, 2011,35(3): 375-378.
[孙彬彬,刘占元,周国华.固体载体型元素提取器研制[J].物探与化探,2011, 35(3):375-378.]
[64] Gao Yunlong.Using geoelectrochemical technical to extract uranium and other metal[J].China Nuclear Science and Technology Report, 1990,(Suppl.4):38-39.
[高云龙. 地电化学提取铀及其它金属的研究[J].中国核科技报告,1990, (增刊4):38-39.]
[65] Luo Xianrong,Zhang Xuehong,Zhang Li.The application of the various new methods in search for hidden stibium ore deposits: An example from Muli stibium mining area, Yunan[J]. Journal of Guilin Institute of Technology, 1997, 17(1):42-48.
[罗先熔,张学洪,张力.应用多种化探新方法寻找隐伏锑矿——以云南木利锑矿为例[J].桂林工学院学报,1997, 17(1):42-48.]
[66] Zhang Lingchen.Application of geoelectrical chemical extraction in gold and silver deposits[J].Journal of Precious Metallic Geology, 2000, 9(2):105-110.
[张令臣. 地电化学提取法在金银矿上的应用效果[J].贵金属地质,2000, 9(2):105-110.]
[67] Xia Yongjian, Chen Youdong, Wang Siliang, et al.Tentative investigation of absorption electricity extraction for exploring gold in Hetai gold deposit[J].Gold,2008,29(9):7-10.
[夏永健,陈友东,王斯亮,等.地电化学测量在河台金矿找矿中的试验研究[J].黄金,2008,29(9):7-10.]
[68] Cao Zhonghuang, Luo Xianrong,Wang Peipei, et al.Comparative study of copper nickel-deposit exploration by the geoelectro-chemical extraction method in different overburden areas[J].Geology and Exploration, 2010, 46(3): 476-482.
[曹中煌,罗先熔,王培培,等.不同覆盖区地电化学提取法寻找铜镍矿对比研究[J].地质与勘探,2010, 46(3):476-482.]
[69] Liu Xiujuan, Luo Xianrong, Zheng Xiaoming, et al.Electro-geochemical method in search of concealed gold deposit: A case study in Barunsurideritu gold deposit in Abaga county of Inner Mongolia[J]. Da Zhong Ke Ji,2011,(5):97-99.
[刘秀娟,罗先熔,郑小明,等. 地电化学新方法寻找隐伏金矿研究——以内蒙古阿巴嘎旗巴润苏德日图金矿区为例[J]. 大众科技, 2011,(5):97-99.]
[70] Wen Meilan, Luo Xianrong, Xiong Jian.Electro-geochemical method in search of concealed uranium deposits in an area of Jiangxi Province[J].Mineral Exploration, 2011, 2(4):404-408.
[文美兰,罗先熔,熊健.江西某地区地电化学法寻找隐伏铀矿研究[J].矿产勘查, 2011, 2(4):404-408.]
[71] Wang Zhendong, Luo Xianrong, Wang Jian, et al.Electro-geochemical method in search of concealed gold deposit in Qinghai-Tibet Plateau: A case study in Zhajiatongna region of Qinghai[J]. Modern Mining,2012,(2):50-52,55.
[王振东,罗先熔,王坚,等. 地电化学技术在青藏高原冻土覆盖区寻找隐伏金矿的研究——以青海扎家同哪地区为例[J]. 现代矿业, 2012,(2):50-52,55.]
[72] Wang Chunsheng, Wang Faming, Wang Qin, et al.Abnormal features, halo-formation mechanism and exploration forecast of copper-nickel ore electrogeochemical of Xingsheng mining area, Inner Mongolia Oroqen[J]. Jilin Geology, 2013, 32(1):106-109.
[王春生,王发明,王芹,等.内蒙古鄂伦春兴盛矿区铜镍矿地电化学异常特征、成晕机制及找矿预测[J].吉林地质, 2013, 32(1):106-109.]
[73] Zhang Zhenbing, Zhang Hai, Yuan Yueqin, et al.The application of terrestrial electrochemical structure superimposition halo method to prognosis of blind deposit[J].Yunan Geology, 2014, 33(2):245-249.
[张振兵,张海,袁月琴,等.地电化学、构造叠加晕法在盲矿预测中的运用[J].云南地质, 2014, 33(2):245-249.]
[74] Yu Sang, Zheng Qinyuan, Xiang Wu, et al.Preliminary experiment on deep orebody prospecting by geoelectrochemical extraction method in Wushan Copper Deposit, Jiangxi[J].Global Geology, 2015, 34(3):800-806.
[于桑,郑钦元,向武,等.地电化学提取法在武山铜矿深部找矿的试验研究[J].世界地质, 2015, 34(3):800-806.]
[75] Huang Lin, Chen Qiong, Zhao Zhijun, et al.Characteristics of geo-electrochemical anomalies of Wuzhishan lead-zinc deposit in Guizhou Province[J].Modern Mining, 2016, (2):116-118.
[黄林,陈琼,赵志军,等.贵州五指山铅锌矿地电化学异常特征[J].现代矿业,2016, (2):116-118.]
[76] Kang Ming, Cen Kuang, Luo Xianrong.Application of “Dipole CHIM” electrified by low voltage dipole[J]. Geology and Prospecting, 2006, 42(4):81-85.
[康明,岑况,罗先熔.低电压偶极子供电方式下的“偶极CHIM”应用效果[J].地质与勘探,2006, 42(4):81-85.]
[77] Yan Wei, Luo Xianrong, Zhang Youjun, et al.Application of geo-electrochemical integrated technique in prospecting prediction in Lunshan gold deposit,Jiangsu[J].Global Geology, 2014, 33(3):615-622.
[闫伟,罗先熔,张友军,等.地电化学集成技术在江苏仑山金矿找矿预测的应用[J].世界地质, 2014, 33(3):615-622.]
[78] Chen Xiquan, Luo Xianrong, Liu Liwen, et al.Study of exploring concealed gold deposits in different landscape areas by geo-electrochemical exploration methods[J].Mineral Resources and Geology, 2007, 21(1):70-74.
[陈希泉,罗先熔,刘莉文,等.地球电化学勘查法寻找不同景观区隐伏金矿的研究[J].矿产与地质, 2007, 21(1):70-74.]
[79] Song Ci’an, Lei Liangqi.Research and orientation of exploration vegetation geochemistry in China[J].Journal of Guilin University of Technology, 2009, 29(1):1-11.
[宋慈安,雷良奇.我国勘查植物地球化学的研究现状及发展方向[J].桂林工学院学报, 2009, 29(1):1-11.]
[80] Tang Jinrong, Cui Xilin, Shi Junfa.New progress in research on non-traditional geochemical prospecting methods[J].Geological Bulletin of China, 2009, 28(C1):232-244.
[唐金荣,崔熙琳,施俊法.非传统化探方法研究的新进展[J].地质通报, 2009, 28(C1):232-244.]
[81] Xie Xuejin, Xu Bangliang.Indicative plant for copper deposit:Elsholtzia splendens[J]. Acta Geologica Sinica,1954, 32(4):360-368.
[谢学锦, 徐邦梁. 铜矿指示植物海州香薷[J]. 地质学报, 1954, 32(4):360-368.]
[82] Quan Heng, Zhang Hong, Zhang Jiongfei, et al.Biogeochemical exploration in Daxinganling forest covered area[J].Journal of Precious Metallic Geology, 1998, 7(4):241-249.
[权恒, 张宏, 张炯飞, 等.大兴安岭森林覆盖区植物化探找矿方法研究[J].贵金属地质, 1998, 7(4):241-249.]
[83] Hu Xishun, Liu Jincheng, Wang Zhenyang, et al.Primary study of biogeochemical exploration for gold deposits in Xiaoqinling of Shannxi Province[J]. Gold Scienceand Technology, 1992, 1(8):31-32.
[胡西顺, 刘金成, 汪振洋, 等. 陕西小秦岭地区金矿植物地球化学勘查初步研究[J]. 黄金科学技术, 1992, 1(8):31-32.]
[84] Chen Daiyan, Zou Zhenxi, Ren Dayin.A preliminary application of the geobiotanical method to the Lanmuchang thallium (mercury) ore deposits in southwest Guizhou[J]. Journal of Guilin University of Technology (Natural Science Edition), 2000, 29(5):32-38.
[陈代演, 邹振西, 任大银.地质植物法在黔西南滥木厂铊(汞)矿床的初步应用[J].贵州工业大学学报:地球科学版, 2000, 29(5):32-38.]
[85] Kong Lingshao, Sun Shizhou, Luo Jinling, et al.The phytocommunity and phyto-geochemistry characteristics of Pb and Zn in the mining area of Xitieshan mountain in Qinghai Province and their relationship with the Pb and Zn deposits[J].Acta Phytoecologica et Geobotanic Sinica, 1988, 12(1):40-49.
[孔令韶, 孙世洲, 罗金铃, 等.青海锡铁山矿区铅、锌的植物地球化学特征及其与成矿的关系[J].植物生态学与地植物学学报, 1988, 12(1):40-49.]
[86] Song Ci’an, Lei Liangqi, Yang Qijun, et al.Botanical geochemical of redwood of the Au-Cu deposits in Beishan, Gansu[J].Geology and Prospecting, 2001, 37(3):45-49.
[宋慈安, 雷良奇, 杨启军, 等.甘肃北山金、铜矿床红沙的植物地球化学特征及其找矿意义[J].地质与勘探, 2001, 37(3):45-49.]
[87] Song Ci’an, Lei Liangqi, Yang Qijun, et al.Characteristics of biogeochemical anomalies and prognostic model in Gongpoquan copper ore field, Gansu, China[J].Geology-Geochemistry, 2002, 30(2):40-45.
[宋慈安,雷良奇,杨启军,等.甘肃公婆泉铜矿区生物地球化学异常特征及找矿预测模式[J].地质地球化学, 2002, 30(2):40-45.]
[88] Cen Kuang,Ye Rong,Shen Yongli, et al.The effect of 1∶50000 geochemical vegetation survey in the Beishan Gobi desert region[J].Geology and Prospecting, 2003, 39(6):86-89.
[岑况, 叶荣, 沈镛立,等.北山戈壁荒漠地区1∶5万植物地球化学测量效果[J].地质与勘探, 2003, 39(6):86-89].
[89] Dai Xinggen.Biogeochemical exploration: A case study of uranium deposit exploration using Jimu[J].Geophysical & Geochemical Exploration, 1981, 5(1):17-25.
[戴兴根. 生物地球化学法——檵木找铀矿的试验研究[J]. 物探与化探, 1981, 5(1):17-25.]
[90] Kong Lingshao, Gao Ping.Characteristics of phytogeochemistry in Naomu-hong copper mine area at Alashan of Neimonggol[J]. Acta Batanica Sinica, 1992, 34(10):781-789.
[孔令韶, 高平.内蒙阿拉善脑木洪铜矿区的植物地球化学特征[J].植物学报, 1992, 34(10):781-789.]
[91] Hou Jiali, Yang Miyun.Thallium-used as a path finding element for prospecting of gold deposits[J].Geological Exploration for Non-ferrous Meta, 1995, 4(4):223-227.
[侯嘉丽, 杨密云.用铊作探途元素寻找金矿[J]有色金属矿产与勘查, 1995, 4(4):223-227.]
[92] Song Ci’an, Lei Liangqi, Yang Zhongping, et al.Influence of shielding effect on formation of biogeochemical anomaly and selection of prospecting effective indicator plant[J]. Geological Science and Technology Information, 2012, 31(1):1-8.
[宋慈安,雷良奇,杨仲平,等.屏障效应对生物地球化学异常形成的影响及找矿有效指示植物的选择[J].地质科技情报, 2012, 31(1):1-8.]
[93] Govett G.Detection of deeply buried and blind sulphide deposits by measurement of H+ and conductivity of closely spaced surface soil samples[J]. Journal of Geochemical Exploration, 1976, 6(1/2):359-382.
[94] Kristiansson K, Malmqvist L.Evidence for non-diffusive transport of Rn in the ground and a new physical model for the transport[J]. Geophysics, 1982, 47(10):1 444-1 452.
[95] Hamilton S.Electrochemical mass-transport in overburden: A new model to account for the formation of selective leach geochemical anomalies in glacial terrain[J]. Journal of Geochemical Exploration, 1998, 63(3):155-172.
[96] Hamilton S, Cameron E M, McClenaghan M B, et al. Redox, pH and SP variation over mineralization in thick glacial overburden, Part I:Methodologies and field investigation at the Marsh Zone gold property[J]. Geochemistry: Exploration, Environment, Analysis, 2004, 4(1): 33-34.
[97] Garnett D.Element mobility in transported overburden-are we looking in the wrong direction?[J]. The Association of Applied Geochemists: Explore, 2004, 127:3-5.
[98] Wang Xueqiu, Zhang Bimin, Yao Wensheng, et al.Geochemical exploration: From nanoscale to global-scale patterns[J]. Geoscience Frontiers, 2014,21(1): 65-74.
[王学求, 张必敏, 姚文生, 等. 地球化学探测:从纳米到全球[J]. 地学前缘, 2014,21(1): 65-74.
[99] Wang Xueqiu, Xu Shanfa, Chi Qinghua, et al.Gold geochemical provinces in China:A Micro-and Nano-scale formation mechanism[J].Acta Geologica Sinica, 2013, 87(1): 1-8.
[王学求,徐善法,迟清华,等. 中国金的地球化学省及其成因的微观解释[J]. 地质学报, 2013, 87(1): 1-8.
[100] Coker W B.Future research directions in exploration geochemistry:Is there a future?[C]∥Milkereit B.Proceedings of Exploration 07:Fifth Decennial International Conference on Mineral Exploration. 2007: 331-337.
[101] Tan Chenglong.Two widely different geochemical methods: Partial extraction technique and leaching of mobile forms of metals in overburden[J].World Nuclear Geoscience, 2004, 21(3):171.
[谈成龙. 偏提取技术和金属活动态测量是两种迥异的地球化学方法[J]. 世界核地质科学,2004,21(3):171.]
[102] Liu Bin, Zhou Sichun, Ge Liangquan, et al.Geogas anomaly characteristics of the Huangshaping Lead-Zinc deposit in the Qianlishan-Qitianling ore concentration area and their prospecting significance in south Hunan[J]. Acta Geoscientica Sinica, 2011, 32(4):413-418.
[刘斌, 周四春, 葛良全, 等.湘南千里山—骑田岭矿集区黄沙坪型铅锌矿地气异常特征及找矿意义[J].地球学报, 2011, 32(4):413-418.]
[103] Yao Wensheng, Wang Xueqiu, Zhang Bimin, et al.Pilot study of deep penetrating geochemical exploration for sandstone type uranium deposit, Ordos Basin[J].Geoscience Frontiers,2012, 19(3):167-176.
[姚文生, 王学求, 张必敏, 等.鄂尔多斯盆地砂岩型铀矿穿透性地球化学勘查方法实验[J].地学前缘,2012, 19(3):167-176.]
[104] Liu Chang, Cao Jianjin, Xiong Zhihua.Geogas exploration of Bingba copper deposit in Guanling County of Guizhou Province[J]. Mineral Deposits,2010, 29(Suppl.1):641-642.
[刘昶,曹建劲,熊志华. 地气测量在贵州关岭丙坝铜矿应用研究[J].矿床地质, 2010, 29(增刊1):641-642.]
[105] Wang Xiaojia, Lu Mei, Wang Zhenkai, et al.Characteristics of geogas anomalies measured in the Shengjiayao gold deposit of Shan County, Henan Province[J].Geology and Exploration, 2016, 52(4):667-677.
[王晓佳,鲁美,王振凯,等.申家窑金矿床地气测量异常特征[J].地质与勘探, 2016, 52(4):667-677.]
[106] Sun Jian, Chen Yuelong, Li Dapeng.New advances in geochemical exploration of concealed deposits[J]. Advances in Earth Science, 2011, 26(8): 822-836.
[孙剑,陈岳龙,李大鹏. 隐伏矿床勘查地球化学新进展[J]. 地球科学进展,2011,26(8):822-836.]
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