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地球科学进展  2016, Vol. 31 Issue (11): 1125-1136    DOI: 10.11867/j.issn.1001-8166.2016.11.1125
综述与评述     
氧化石墨烯对环境污染物的吸附行为及吸附机理
杜佳媛1, 魏永鹏1, 刘菲菲2, 代燕辉1, 赵建1, 王震宇1*, *
1.中国海洋大学,近海环境污染控制研究所,海洋环境与生态教育部重点实验室,山东 青岛 266100;
2.山东大学,环境科学与工程学院,山东 济南 250100
Adsorption Behavior and Mechanism of Environmental Pollutants on Graphene Oxide
Du Jiayuan1, Wei Yongpeng1, Liu Feifei2, Dai Yanhui1, Zhao Jian1, Wang Zhenyu1, *
1.Institute of Costal Environmental Pollution Control, and Ministry of Education Key Laboratory of Marine Environment and Ecology, Ocean University of China, Qingdao 266100, China;
2.School of Environmental Science and Engineering, Shandong University, Jinan 250100, China
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摘要: 氧化石墨烯具有相对较大的表面积,其表面存在的丰富的含氧官能团使其具有良好的亲水性,能稳定地分散在水溶液中,是一种潜在的优质吸附剂。现有研究表明,氧化石墨烯对重金属及阳离子染料废水的处理效果明显优于广泛应用的传统吸附剂,然而由于其自身结构缺陷的原因,其应用还受到很多局限。介绍了氧化石墨烯的制备和结构,并重点针对氧化石墨烯及其复合材料对重金属离子和有机污染物的吸附行为、吸附机理、吸附模型及吸附影响条件等进行了综述,最后对氧化石墨烯及其复合材料在吸附方向的研究和应用前景进行了展望。
关键词: 氧化石墨烯重金属复合材料有机污染物吸附    
Abstract: Graphene oxide, as an emerging material for contaminants removal,possesses relatively large specific surface area, and it shows good dispersion in water phase due to the hydrophilicessence resulted from abundant oxygen-containing functional groups on the edge, thus leading to a potential excellent adsorbent. Current studies revealthat, because graphene oxide is negatively-charged in a wide range of pHs, the removal efficiency of heavy metals and cationic dyes by graphene oxide is significantly higher than by traditional adsorbents, like activated carbon. However, its applications are still limited due to its structural defects. For example, its π domain is destructed during fabrication process. Therefore, certain structural modifications need to be conducted on the purpose of improving its performance, achieving a better result in water purification. This paper presented the preparation and structure of graphene oxide, and reviewed the adsorption behaviors, adsorption mechanisms, adsorption models and influence factors of heavy metals and organic pollutants on graphene oxide and its composites, respectively. In view of unresolved issues, further research should focus on comprehensive adsorption mechanisms, more facile and effectivemethods for structural modifications and the treatment of graphene oxide after adsorption process.
Key words: Graphene oxide    Heavy metals    Organic pollutant.    Composite    Adsorption
收稿日期: 2016-06-30 出版日期: 2016-11-20
:  P951  
基金资助: 国家自然科学基金重点项目“典型人工纳米颗粒在不同生态系统中的环境行为及食物链中的关键过程”(编号:41530642)资助
通讯作者: 王震宇(1969-),男,宁夏银川人,教授,主要从事污染环境的生物修复研究.E-mail:wang0628@ouc.edu.cn   
作者简介: 杜佳媛(1993-),女,黑龙江哈尔滨人,硕士研究生,主要从事水资源利用与水污染控制研究.E-mail:dujiayuan@tju.edu.cn
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杜佳媛, 魏永鹏, 刘菲菲, 代燕辉, 赵建, 王震宇. 氧化石墨烯对环境污染物的吸附行为及吸附机理[J]. 地球科学进展, 2016, 31(11): 1125-1136.

Du Jiayuan, Wei Yongpeng, Liu Feifei, Dai Yanhui, Zhao Jian, Wang Zhenyu. Adsorption Behavior and Mechanism of Environmental Pollutants on Graphene Oxide. Advances in Earth Science, 2016, 31(11): 1125-1136.

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http://www.adearth.ac.cn/CN/10.11867/j.issn.1001-8166.2016.11.1125        http://www.adearth.ac.cn/CN/Y2016/V31/I11/1125

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