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地球科学进展  2009, Vol. 24 Issue (1): 25-32    DOI: 10.11867/j.issn.1001-8166.2009.01.0025
李 俊,谢 丽*,盛 杰,栾富波,周 琪
同济大学污染控制与资源化研究国家重点实验室,上海 200092
Reductive Transformation of Organic Pollutants by Surface-Bound Fe(Ⅱ) Systems:A Review
Li Jun,Xie Li,Sheng Jie,Luan Fubo,Zhou Qi
State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China
 全文: PDF(1041 KB)  


关键词: 表面结合铁Fe(Ⅱ)铁氧化物非生物还原有机污染物      

Soil and sediments are anoxic and anaerobic environment, often containing high levels of Fe(Ⅱ) due to the interaction of iron reducing bacteria with iron oxide minerals which are widely present in subsurface. The Fe(Ⅱ) associated with iron oxides is highly reactive, and could play an effective role in reducing organic pollutants. This paper reviews the involved interfacial mechanisms, and the abiotic reductive transformation process of halogenated and nitroaromatic compounds occurring on the surface-bound Fe(Ⅱ) system. Impact factors such as active surface sites, pH, types of iron oxide mineral, contact time of Fe(Ⅱ) with iron oxide, metals and humic acid are discussed and evaluated. The natural surface bound Fe(Ⅱ) system is, therefore, likely to play a potential role in reductive in-situ transformation of organic pollutants in subsurface remediation, and this reaction should be enhanced and taken into account in further studies.

Key words: Surface-bound iron    Fe(Ⅱ)    Iron oxide    Abiotic reduction    Organic pollutants.
收稿日期: 2008-09-20 出版日期: 2009-01-10
:  X171  


通讯作者: 谢丽(1976-),女,湖南常德人,副教授,主要从事污水处理理论与技术方面的研究.     E-mail:
作者简介: 李俊(1985-),女,浙江嘉兴人,硕士研究生,主要从事水污染控制工程研究.
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李俊,谢丽,盛杰,栾富波,周琪. Fe(Ⅱ)/铁氧化物表面结合铁系统还原有机污染物的研究进展[J]. 地球科学进展, 2009, 24(1): 25-32.

Li Jun,Xie Li,Sheng Jie,Luan Fubo,Zhou Qi. Reductive Transformation of Organic Pollutants by Surface-Bound Fe(Ⅱ) Systems:A Review. Advances in Earth Science, 2009, 24(1): 25-32.


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