铁碳共沉作用对土壤重金属的吸附性能研究进展

doi:10.11867/j.issn.1001-8166.2017.08.0867

地球科学进展 ›› 2017, Vol. 32 ›› Issue (8): 867 -874. doi: 10.11867/j.issn.1001-8166.2017.08.0867

赵转军(

), 杨艳艳 ^*(

), 庞瑜, 赵立芳, 管宇立, 张兆虎

兰州大学资源环境学院,甘肃兰州 730000

收稿日期:2017-05-30 修回日期:2017-07-06 出版日期:2017-10-20
通讯作者: 杨艳艳 E-mail:zhj_zhao@lzu.edu.cn;yangyy2015@lzu.edu.cn
基金资助:
国家自然科学基金项目“纳米级铁碳共沉物对西北农田土壤重金属Cd/Pb的固定吸附作用研究”(编号:41771341);甘肃省尾矿库企业环境风险预控及应急管理工作要点调查研究项目 (编号:20170117000896)资助

A Review of Study on Fe-C Interaction and Their Adsorption Properties to Soil Heavy Metal

Zhuanjun Zhao( ), Yanyan Yang ^*( ), Yu Pang, Lifang Zhao, Yuli Guan, Zhaohu Zhang

College of Earth and Environmental Sciences,Lanzhou University, Lanzhou 730000, China

Received:2017-05-30 Revised:2017-07-06 Online:2017-10-20 Published:2017-08-20
Contact: Yanyan Yang E-mail:zhj_zhao@lzu.edu.cn;yangyy2015@lzu.edu.cn
About author:
First author:Zhao Zhuanjun(1977-), female, Tianshui City,Gansu Province, Associate professor. Research areas include treatment and remediation of heavy metal pollution in water and soil.E-mail:zhj_zhao@lzu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China “Adsorption and Immobilization of Cd and Pb by Nano-sized Fe-C coprecipitates in the agricultural soils, arid region of Northwest China”(No.41771341);Investigation and Research Project of Environmental Risk Pre-control and Emergency Management of Tailings Bank in Gansu Province(No.20170117000896)

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随着铁碳(Fe-C)共沉机理被越来越多的学者认可,Fe-C共沉物成为近年环境科学领域内的研究热点之一。在探讨铁氧化物和有机质的相互作用及Fe-C共沉物对重金属的吸附研究进展基础上,阐述了共沉物在固定土壤重金属离子方面的潜力:在有机质参与作用下,铁氧化物的表面性质、吸附性能等均发生了规律性变化,这些变化是决定土壤环境中重金属离子迁移转化的前提。在影响因素方面,pH值、有机质含量、铁氧化物种类及表面性质对共沉物的吸附效果影响较为显著。通过研究可以看出,一定条件下Fe-C共沉物所拥有的优良吸附性能将为土壤重金属污染场地修复治理工作提供重要理论基础。

关键词: 铁氧化物, 有机质, Fe-C共沉物, 吸附作用, 重金属

Nowadays, the Fe-C coprecipitate mechanism is recognized by more and more scholars and becomes the hot topic in the environmental science. On the basis of discussing the interaction between iron oxide and organic matter, and the adsorption research progress of Fe-C complexes on heavy metals, the immobilization potential of Fe-C complexes on heavy metals in polluted soil were illustrated. The surface properties and physical characterizations of iron oxide are changed regularly with the interaction of organic matter, which lead to the higher adsorption capacity of Fe-C complexes in contrast to single iron oxide. Besides, the influences of pH values, organic matter types and surface properties of iron oxides on the adsorption capacity of Fe-C complexes on heavy metals were discussed. The excellent adsorption performance of Fe-C complexes in certain conditions will provide important theoretical basis for contaminated soil remediation.

Key words: Iron oxide, Organic matter, Fe-C complexes, Adsorption, Heavy metal.

中图分类号:

P934

图1 不同C/Fe比例下水铁矿及其碳的共沉物的XRD图谱 ^{[

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Fig.1 X-Ray Diffractograms of pure ferrihydrite, some coprecipitates with different C/Fe ratios ^{[

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]}

图2 针铁矿及针铁矿—腐殖酸复合物的XRD图 ^{[

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Fig.2 X-Ray Diffraction patterns of the goethite and goethite-humic acid complex ^{[

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图3 水铁矿及不同C/Fe下水铁矿—胡敏酸复合物的SEM图像 ^{[

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Fig.3 Scanning Electron Microscopy of ferrihydrite and ferrihydrite-humic acid complex with different C/Fe ratios ^{[

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图4 胡敏酸(a)、针铁矿(b)及针铁矿—胡敏酸复合物(c)的TEM图像 ^{[

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Fig.4 Transmission Electron Micrographs of humic acid(a), goethite(b) and goethite-humic acid complex(c) ^{[

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图5 pH值对3种复合物吸附Hg ²⁺的影响 ^{[

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Fig.5 Effect of pH on adsorption of three complex on Hg ^{2+[

53
]}

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