[1] Golden D C, Chen C C, Dixon J B. Transformation of birnessite to buserite, todorokite, and manganite under mild hydrothermal treatment[J].Clays and Clay Minerals,1987, 35: 271-280. [2] Mellin T A, Lei G. Stabilization of 10Å-manganates by interlayer cations and hydrothermal treatment: Implications for the mineralogy of marine manganese concretions[J].Marine Geology,1993, 115: 67-83. [3] Post J E. Manganese oxide minerals: Crystal structures and economic and environmental significance[J].Proceedings of the National Academy of Sciences of the United States of America,1999, 96: 3 447-3 454. [4] Tan Wenfeng, Liu Fan, Li Yonghua, et al. Mineralogy of manganese in ironmanganese nodules of several soils in China[J]. Acta Pedologica Sinica,2000, 37(2): 192-201.[谭文峰, 刘凡, 李永华,等. 我国几种土壤铁锰结核中的锰矿物类型[J]. 土壤学报, 2000, 37(2): 192-201.] [5] McKeown D A, Post J E. Characterization of manganese oxide mineralogy in rock varnish and dendrites using X-ray absorption spectroscopy[J].American Mineralogist,2001, 86: 701-713. [6] Buatier M D, Guillaume D, Wheat C G, et al. Mineralogical characterization and genesis of hydrothermal Mn oxides from the flank of the Juan the Fuca Ridge[J].American Mineralogist,2004, 89: 1 807-1 815. [7] Takahashi Y, Manceau A, Geoffroy N, et al. Chemical and structural control of the partitioning of Co, Ce, and Pb in marine ferromanganese oxides[J].Geochimica et Cosmochimica Acta,2007, 71(4): 984-1 008. [8] Frondel C, Marvis U B, Ito J. New occurrence of todorokite[J].American Mineralogist,1960,45:1 167-1 173. [9] Turner S, Buseck P. Todorokies: A new family of naturally occurring manganese oxides[J].Science,1981, 212: 1 024-1 027. [10] Siegel M D, Turner S. Crystalline todorokite associated with biogenic debris in manganese nodules[J].Science,1983, 219: 172-174. [11] Golden D C, Chen C C, Dixon J B. Synthesis of Todorokite[J].Science,1986, 231: 717-719. [12] Shen Y F, Zerger R P, Suib S L, et al. Manganese oxide octahedral molecular sieves: Preparation, characterization and application[J].Science,1993, 260: 511-515. [13] Feng Q, Kanoh H, Miyai Y, et al. Metal ion extraction/insertion reactions with todorokite-type manganese oxide in the aqueous phase[J].Chemistry of Materials,1995, 7: 1 722-1 727. [14] Luo J, Zhang Q, Huang A, et al. Double-aging method for preparation of stabilized Na-buserite and Transformations to todorkites incorporated with various metals[J].Inorganic Chemistry,1999, 38: 6 106-6 113. [15] Liu J, Cai J, Son Y C, et al. Magnesium manganese oxide nanoribbons: Synthesis, characterization, and catalytic application[J].The Journal of Physical Chemistry B,2002, 106: 9 761-9 768. [16] Post J E, Heaney P J, Hanson J. Synchrotron X-ray diffraction study of the structure and dehydration behavior of todorokite [J].American Mineralogist,2003, 88: 142-150. [17] Feng X H, Tan W F, Liu F, et al. Synthesis of todorokite at atmospheric pressure[J].Chemistry of Materials,2004, 16: 4 330-4 336. [18] Al-Sagheer F A, Zaki M L. Synthesis and surface characterization of todorokite-type microporous manganese oxides: Implications for shapeselective oxidation catalysts[J].Microporous and Mesoporous Materials,2004, 67: 43-52. [19] Liu Z H, Kang L, Ooi K, et al. Studies on the formation of todorokite-type manganese oxide with different crystalline birnessitres by Mg2+-templating reaction[J].Journal of Colloid and Interface Science,2005, 285: 239-246. [20] Onda A, Hara S, Kakiyoshi K, et al. Synthesis of manganese oxide octahedral molecular sieves containing cobalt, nickel, or magnesium, and the catalytic properties for hydration of acrylonitrile[J].Applied Catalysis A: General,2007, 321: 71-78. [21] Abakumov A M, Hadermann J, Tendeloo G V, et al.[SrF0.8(OH)0.2]2.526[Mn6O12]:Columnar rocksalt fragments inside the todorokite-type tunnel structure[J].Chemistry of Materials,2007, 19: 1 181-1 189. [22] McKenzie R M. The synthesis of birnessite, cryptomelane, and some other oxides and hydroxides of manganese[J]. Mineralogical Magazine,1971, 38: 493-503. [23] McKenzie R M. Manganese oxides and hydroxides[M]//Dixon J B, Weed S B, eds. Minerals in Soil Environments (2nd edition). Madison: Soil Science Society of America,1989: 439-465. [24] Burns R G, Burns V M, Stockman H W. A review of the todorokite-buserite problem: Implications to the mineralogy of marine manganese nodules[J].American Mineralogist,1983, 68: 972-980. [25] Giovanoli R. A review of the todorokite-buserite problem: Implications to the mineralogy of marine manganese nodules: Discussion[J].American Mineralogist,1985, 70: 202-204. [26] Turner S, Siegel M D, Buseck P R. Structure features of tordorkite intergrowths in manganese nodules[J].Nature,1982, 296: 841-842. [27] BodeïS, Manceau A, Geoffroy N, et al. Formation of todorokite from vernadite in Ni-rich hemipelagic sediments[J].Geochimica et Cosmochimica Acta, 2007, 71: 5 698-5 716. [28] Chukhrov F V, Gorshkov A I, Sivtsov A V. New data on natural todorkites[J].Nature,1979, 278: 631-632. [29] Chukhrov F V, Gorschkov A I, Rudnitskaya E S, et al. Manganese minerals in clays—A reviews[J].Clays and Clay Minerals, 1980, 28: 346-354. [30] Post J E, Bish D L. Rietveld refinement of the todorokite structure[J].American Mineralogist,1988, 73: 861-869. [31] Gutzmer J, Beukes N J. Asbestiform manjiroite and todorokite from the Kalahari manganese field, South Africa[J].Journal of Geology,2000, 103(3/4):163-174. [32] Zhou H, Wang J Y, Chen X, et al. Studies of oxidative dehydrogenation of ethanol over manganese oxide octahedral molecular sieve catalysts[J].Microporous and Mesoporous Materials,1998, 21: 315-324. [33] Ching S, Krukowska K S, Suib S L. A new synthetic route to todorokite-type manganese oxides[J].Inorganica Chimica Acta, 1999, 294: 123-132. [34] Kumagai N, Komaba S, Abe K, et al. Synthesis of metal-doped todoroktie-type MnO2 and its cathode characteristics for rechargeable lithium batteries[J].Journal of Power Sources,2005, 146: 310-314. [35] Shen Y F, Suib S L, O'Yang C L. Effects of inorganic cation templates on octahedral molecular sieves of manganese oxide[J].Journal of American Chemistry Society,1994, 116: 11 020-11 029. [36] Malinger K A, Laubernds K, Son Y C, et al. Effects of microwave processing on chemical, physical and catalytic properties of todorokite-type manganese oxide[J].Chemistry of Materials,2004, 16: 4 296-4 303. [37] Tan Wenfeng. The Composition and Surface Chemistry Characteristics of Fe-Mn Nodules of Several Soils in China[D].Wuhan: Huazhong Agricultural University, 2000.[谭文峰. 我国几种土壤中铁锰结核的物质组成与表面化学性质[D].武汉: 华中农业大学,2000.][38] Tan W F, Liu F, Li Y H, et al. Mineralogy of manganese oxides in ironmanganese nodules of several main types of soils in China[J].Pedosphere,2000, 10: 365-274. [39] Burns R G, Burns V M, Sung w, et al. Ferromanganese mineralogy suggested terminology of the principal manganese oxide phases[J].Geological Society of America,1974, 6:1 029-1 030. [40] Tebo B M, Bargar J R, Clement B, et al. Manganese biooxides: Properties and mechanisms of formation[J].Annual Review of Earth and Planetary Science,2004, 32: 287-328. [41] Villalobos M, Lanson B, Manceau A, et al. Structural model for the biogenic Mn oxide produced by Pseudomonas putida[J]. American Mineralogist,2006, 91: 489-502. [42] Miyata N, Tani Y, Sakata M,et al. Microbial manganese oxide formation and interaction with toxic metal ions[J].Journal of Bioscience and Bioengineering,2007, 104(1): 1-8. [43] Webb S M, Dick G J, Bargar J R, et al. Evidence for the presence of Mn(III) intermediates in the bacterial oxidation of Mn(II)[J].Proceedings of the National Academy of Sciences of the United States of America,2005, 102: 5 558-5 563. [44] Saratovsky I, Wightman P G, Pasten P A, et al. Manganese oxides: Parallels between abiotic and biotic structures[J].Journal of American Chemistry Society,2006, 128: 11 188-11 198. [45] Miyata N, Maruo K, Tani Y, et al. Produce of biogenic manganese oxides by Anamorphic Ascomycete Fungi isolated from streambed pebbles[J].Geomicrobiology Journal,2006, 23: 63-73. [46] Burns V M, Burns R G. Post-depositional metal enrichment processes inside manganese nodules from the north equatorial Pacific[J].Earth and Planetary Science Letters,1978, 39:341-348. [47] Chen Jianlin, Zhang Fusheng, Lin Chengyi, et al.Biogenesis study of manganese nodules from the Chinese pioneer area in the Pacific ocean[J].Acta Geologica Sinica,2001, 75(2): 228-232.[陈建林, 张富生, 林承毅, 等. 太平洋中国开辟区锰结核生物成因研究[J].地质学报,2001, 75(2): 228-232.] [48] Kim H S, Pasten P A, Gaillard J F, et al. Nanocrystalline todorokite-like manganese oxide produce by bacterial catalysis[J]. Journal of American Chemistry Society, 2003, 125: 14 284-14 285. [49] Kim H S, Stair P C. Bacterially produced manganese oxide and todorokite: UV raman spectroscopic comparison[J].The Journal of Physical Chemistry B,2004, 108: 17 019-17 026. [50] Webb S M, Fuller C C, Tebb B M, et al. Determination of Uranly incorporation into biogenic manganese oxides X-ray absorption spectroscopy and scattering[J].Environmental Science & Technology,2006, 40: 771-777. [51] Ostwald J.Some observations on the chemical composition of todorokite[J].Mineralogical Magazine,1986, 50: 336-340. [52] Chukhrov F V, Gorshkov A I, Sivtsov A V. New data on natural todorkites[J].Nature,1979, 278: 631-632. [53] Turner S, Buseck P R. Manganese oxide tunnel structures and their intergrowths[J].Science,1979, 203: 456-458. [54] Liu Bin, Xia Xi. Doped Ca-,doped Ba-,doped Ni-todorokites and their electrochemical behavior in aqueous electrolytes[J]. Journal of Applied Sciences,2001, 19(2): 636-640.[刘斌, 夏熙. 含钙、含钡和含镍镁锰矿的合成及在水溶液中的电化学性能[J]. 应用科学学报, 2001, 19(2): 636-640.] [55] Ali A A, Al-Sagheer F A, Zaki M I. Surface texture morphology and chemical composition of hydrothermally synthesized tunnel-structure manganese(IV) oxide[J].International Journal of Inorganic Materials,2001, 3: 427-435. [56] Vileno E, Zhou H, Zhang Q, et al. Synthetic todorkite produce by microwave heating: An active oxidation catalyst[J].Journal of Catalysis,1999, 187: 285-297. [57] Feng Xionghan, Liu Fan, Tan Wenfeng, et al. Synthesis of todorokite by refluxing process and its primary characterization[J].Science in China (Series D),2003, 33(11): 1 084-1 093.[冯雄汉, 刘凡, 谭文峰,等.回流条件下钙锰矿的合成及其初步表征[J]. 中国科学:D辑,2003, 33(11): 1 084-1 093.] [58] Feng Xionghan, Tan Wenfeng, Liu Fan, et al. Hydrothermal synthesis of todorokite and its influencing factors[J].Earth Science—Journal of China University of Geosciences,2005, 30(3): 347-352.[冯雄汉,谭文峰,刘凡,等.热液条件下钙锰矿的合成及其影响因素[J]. 地球科学——中国地质大学学报, 2005, 30(3): 347-352.] [59] Cui H J, Feng X H, Liu F, et al. Factors governing formation of todorokite at atmospheric pressure[J].Science in China(Series D),2005, 48:1 678-1 689. [60] Cui H, Feng X, Tan W, et al. Synthesis of todorokite-type manganese oxide from Cu-buserite by controlling the pH at atmospheric Pressure[J].Microporous and Mesoporous Materials,2009, 117: 41-47. [61] Cui Haojie. Factors Governing the Chemical Formation of Todorokite at Atmospheric Pressure[D]. Wuhan: Huazhong Agricultural University, 2007.[崔浩杰. 常压下钙锰矿化学形成的影响因素研究[D]. 武汉:华中农业大学, 2007.] [62] Drits V A, Silvester E, Gorshkov A I, et al. Structure of synthetic monoclinic Na-rich birnessiteand hexagonal birnessite: I. Results from X-ray diffraction and selected-area electron diffraction[J].American Mineralogist,1997, 82: 946-961. [63] Lanson B, Drits V A, Silvester E, et al. Structure of H-exchanged hexagonal birnessite and its mechanism of formation from Na-rich monoclinic buserite at low pH[J].American Mineralogist,2000, 85: 826-838. [64] Silvester E J, Manceau A, Drits V A. The structure of monoclinic Na-rich birnessite and hexagonal birnessite. Part 2 Results from chemical studies and EXAFS spectroscopy[J].American Mineralogist,1997, 82: 962-978. [65] Lanson B, Drits V A, Feng Q, et al. Structure of synthetic birnessite: Evidence for a triclinic one-layer unit cell[J].American Mineralogist,2002, 87:1 662-1 671. [66] Cui H J, Liu X W, Tan W F, et al. Influence of Mn(III) availability on the phase transformation from layered buserite to tunnelstructured todorokite[J].Clays and Clay Minerals,2008, 56: 397-403. [67] Cui H J, Feng X H, He J Z, et al. Effects of reaction conditions on the formation of todorokite at atmospheric pressure[J].Clays and Clay Minerals, 2006, 54: 605-615. [68] Tian Z R, Tong W, Wang J Y, et al. Manganese oxide mesoporous structures: mixed valent semiconducting catalysts[J]. Science,1997, 276: 926-930. [69] Suib S L. Sorption, catalysis, and separation by design[J].Chemical Innovation,2000,(30): 27-33. [70] Liu Fan, Tan Wenfeng, Liu Guiqiu, et al. Adsorption of heavy metal ions on Fe-Mn nodules in several soils and types of Mn oxide minerals[J].Acta Pedologica Sinica, 2002, 39(5): 699-706.[刘凡,谭文峰, 刘桂秋,等.几种土壤铁锰结核中锰氧化物的重金属离子吸附与锰矿物类型[J] .土壤学报,2002, 39(5): 699-706.] [71] Balakhonov S V, Churagulov B R, Gudilin E A. Selective cleaning of ions of heavy metals from water solutions using the H-form of todorokite synthesized by the hydrothermal method[J].Journal of Surface Investigation X-ray, Synchrotron and Neutron Techniques,2008,2(1):152-155. [72] Vileno E, Ma Y, Zhou H, et al. Facile synthesis of synthetic tordorkite(OMS-1), co-precipitation reactions in the presence of a microwave field[J].Microporous and Mesporous Materials,1998, 20: 3-15. [73] Vileno E, Zhou H, Zhang Q, et al. Synthetic todorkite produce by microwave heating: An active oxidation catalyst[J].Journal of Catalysis,1999, 187: 285-297. [74] De Guzman R N, Shen Y F, Shaw B R, et al. Role of cyclic voltammetry in characterizing solids: Natural and synthetic manganese oxide octahedral molecular sieves[J].Chemistry of Materials,1993,5:1 395-1 400. [75] Duncan M J, Leroux F, Corbeit J M, et al. Todorokite as a Li insertion cathode: Comparison of a large tunnel framework “MnO2” structure with its related layered structure[J].Journal of The Electrochemical Society,1998, 145: 3 746-3 757. [76] Kumagai N, Komaba S, Sakai H, et al. Preparation of todorokite-type manganese-based oxide and its application as lithium and magnesium rechargeable battery cathode[J].Journal of Power Sources,2001, 97/98: 515-517. [77] Suib S L. Porous manganese oxide octahedral molecular sieves and octahedral layered materials[J].Accounts of Chemical research,2008, 41(4): 479-487. |