地球科学进展 ›› 2011, Vol. 26 ›› Issue (10): 1050 -1056. doi: 10.11867/j.issn.1001-8166.2011.10.1050

研究论文 上一篇    下一篇

实验模拟碳酸盐岩储层包裹体对油气充注的响应
葛云锦 1,2,陈勇 2*,周瑶琪 2,周振柱 2   
  1. 1.延长石油(集团)有限责任公司研究院,陕西西安710075;
    2.中国石油大学(华东)地球科学与技术学院,山东青岛266555
  • 收稿日期:2011-04-18 修回日期:2011-08-11 出版日期:2011-10-10
  • 通讯作者: 陈勇(1976-),男,四川安岳人,副教授,主要从事流体包裹体和油气地球化学研究. E-mail:yongchenzy@upc.edu.cn
  • 基金资助:

    国家自然科学基金项目“碳酸盐岩烃类包裹体捕获机制及其成岩成藏响应:来自实际储层温压条件的人工合成包裹体证据”(编号:40902040);中央高校基本科研业务费专项资金项目“储层流体包裹体形成机制与分析方法研究”(编号:10CX05004A);中国石油科技创新基金研究项目“准南霍—玛—吐构造带油气成藏过程流体示踪研究”(编号:2010D-5006-0106)资助.

Experimental Simulation of Fluid Inclusion Response to Hydrocarbon Charge in Carbonate Reservoir

Ge Yunjin 1,2,Chen Yong 2,Zhou Yaoqi 2,Zhou Zhenzhu 2   

  1. 1.Research Institute of Yanchang Petroleum(GROUP)Co., Ltd, Xi′an710075,China;
    2.School of Geosciences, China University of Petroleum, Qingdao266555, China
  • Received:2011-04-18 Revised:2011-08-11 Online:2011-10-10 Published:2011-10-10

设计了一系列不同油水比(3/7,5/5,7/3,9/1)的实验,以冰洲石为主矿物合成了烃类包裹体,为探讨碳酸盐岩烃类流体包裹体的形成机制提供了一条有效途径。镜下观察及显微荧光分析发现:样品中合成的包裹体沿裂隙分布,表明微裂隙愈合过程中捕获包裹体,烃类和盐水包裹体既同时出现在同一裂隙中,又有分带出现的情况。样品中合成的烃类包裹体数量随油水升高而增多。烃类包裹体所发荧光与实验原油荧光特征一致。显微测温研究显示:不同油水比条件下形成的包裹体均一温度并无明显差异,油气饱和度不是包裹体均一温度的主要影响因素,均一温度受压力及气液相成分影响。实验结果显示,油气对晶体生长和包裹体的形成有抑制作用,但不会终止其形成。油气包裹体的大量形成对应着油气充注的关键时期。油水不混溶造成烃类包裹体和盐水包裹体分带出现。

Synthetic oil(hydrocarbon)-bearing inclusion were synthesized in Iceland crystal with different Oil/water ratios (3/7,5/5,7/3,9/1), which provided better means for researching the mechanism of trapping oil(hydrocarbon)-bearing inclusion in carbonate. Through microscopic observation and micro-fluorometry, it could be seen that the inclusions distributed along the microcrack, which demonstrated that inclusions were trapped during the process of crack healing. Oil and brine inclusions not only distributed in the same crack, but also in different zone. The quantity of synthetic oil(hydrocarbon)-bearing inclusions increased company with the O/W ratios rising.The fluorescence characteristic of oil inclusions and oil adopted in experiment was coincident. There were no apparent differences among the homogenization temperature of inclusions from different sample. Therefore   the hydrocarbon saturation was not the main influential factor of homogenization temperature. Homogenization temperature was affected by pressure and gaseous and liquid phase composition. It could be concluded that crystal growth and inclusions trapping were inhibited by oil and gas, but not terminated. The critic time of hydrocarbon accumulation coincided with trapping much oil inclusions. Zonation of oil and brine inclusions distribution was caused by immiscibility effect between oil and water. 

中图分类号: 

[1] Dixon S A,Summers D M, Surdam R C.Diagenesis and prservation of porosity in Norphlet Formation(Upper Jurassic),southern Alabama[J].American Association of Petroleum Geologists Bulletin,1989,73(6):707-728.
[2] Gluyas J G,Robinson A G,Emery D,et al.Link between Petroleum Emplacement and Sandstone Cementation[R].Petroleum Geology of Northwest Europe:Proceedings of the Fourth Conference,1993.
[3] Neilson J E,Oxtoby N H,Simmons M D,et al.The relationship between petroleum emplacement and carbonate reservoir quality: Examples from Abu Dhabi and the Amu Darya Basin[J].Marine and Petroleum Geology,1998,15(1):57-72.
[4] Marchand A M E,Haszeldine R S,Smalley P C,et al.Evidence for reduced quartz-cementation rates in oil-filled sandstones[J].Geology,2001,29(10):915-918.
[5] Marchand A M E,Smalley P C,Haszeldine R S,et al.Note on the importance of hydrocarbon fill for reservoir quality prediction in sandstones[J].American Association of Petroeum Geologists Bulletin,2002,86(9):1 561-1 571.
[6] Walderhaug O.A fluid inclusion study of quartz-cemented sandstones from offshore mid-Norway-possible evidence for continued quartz cementation during oil emplacement[J].Journal of Sed Petroleum,1990,60(2):203-210.
[7] Ramm M. Porosity-depth trends in reservoir sandstones: Theoretical models related to Jurassic sandstones,offshore Norway[J].Marine and Petroleum Geology,1992,9(5):553-567.
[8] Saigal G,Bjorlykke K,Larter S.The effects of oil emplacement on diagenetic processes—Examples from the Fulmar reservoir sandstones,Central North Sea.Am.Assoc[J].Petroleum Geologists Bulletin,1992,76(7):1 024-1 033.
[9] Midtb R E A,Rykkje J M,Ramm M.Deep burial diagenesis and reservoir quality along the eastern flank of the Viking Graben.Evidence for illitization and quartz cementation after hydrocarbon emplacement[J].Clay Minerals,2000,35(1):227-237.
[10] Yuan Dongshan,Zhang Zhihuan,Zhu Lei,et al.Effects of oil charge on quartz cement[J].Acta Petrologica Sinica,2007,23(9):2 315-2 320.[袁东山,张枝焕,朱雷,等.油气聚集对石英矿物成岩演化的影响[J].岩石学报,2007,23(9):2 315-2 320.]
[11] Ni Pei,Wang Yigang.Experimental study on synthetic oil(hydrocarbon)-bearing inclusions[J].Acta Petrologica Sinica,2007,23(9):2 033-2 038.[倪培,王一刚.人工合成烃类包裹体的实验研究[J].岩石学报,2007,23(9):2 033-2 038.]
[12] Ni Pei,Meng Fanwei.Experimental study on synthetic oil (hydrocarbon)-bearing inclusions in carbonate[J].Acta Petrologica sinica,2008,24(1):161-165.[倪培,孟凡巍.碳酸盐岩中烃类包裹体的人工合成实验研究[J].岩石学报,2008,24(1):161-165.]
[13] Balitsky V S, Yu V,Prokof′ev,et al. Experimental study of the interaction of mineral-forming hydrothermal solutions with oil and their joint migration[J].Petrology,2007,15(3):211-223.
[14] Julien Bourdet,Jacques Pironon.Strain response and re-equilibration of CH4-rich synthetic aqueous fluid inclusions in calcite during pressure drops[J].Geochimica et Cosmochimica Acta,2008,72(12/15):2 946-2 959.
[15] Liu Dehan,Lu Huanzhang,Xiao Xianming.Oil-gas Inclusion and Its Application in Exploration and Development[M].Guangdong:Guangdong  Science and Technology Publish House,2007.[刘德汉,卢焕章,肖贤明.油气包裹体及其在石油勘探和开发中的应用[M].广东:广东科技出版社,2007.]
[16] Ge Yunjin,Chen Yong,Zhou Yaoqi.Effects of hydrocarbon emplacement on diagenesis of carbonatite in different conditions[J].Journal of China University of Petroleum(Edition of Natural Science),2009,33(1):18-22.[葛云锦,陈勇,周瑶琪.不同成岩条件下油气充注对碳酸盐岩成岩作用的影响[J].中国石油大学学报:自然科学版,2009,33(1):18-22.]
[17] Ge Yunjin,Chen Yong,Zhou Yaoqi,et al.Characteristics of synthetic hydrocarbon-bearing inclusions in carbonatic rocks under various oil-water ratios[J].Acta Geologica Sinica,2009,83(4):542-549.[葛云锦,陈勇,周瑶琪,等.不同油水比条件下人工合成碳酸盐岩烃类包裹体特征实验研究[J].地质学报,2009,83(4):542-549.]
[18] Chen Yong,Ge Yunjin,Zhou Yaoqi,et al.Hydrocarbon-bearing inclusions synthesized in carbonate at the temperature and pressure of natural reservoir:Some important implications for the study of petroleum geology[J].Earth Science Frontiers,2009,16(1):11-16.[陈勇,葛云锦,周瑶琪,等.实际储层温压条件下成功合成碳酸盐岩烃类包裹体及其启示意义[J].地学前缘,2009,16(1):11-16.]
[19] Ni Pei,Rao Bing,Ding Junying,et al.Studies on the synthetic fluid inclusions and their application to laser raman spectrum analysis field[J].Acta Petrologica Sinica,2003,19(2):319-326.[倪培,饶冰,丁俊英,等.人工合成包裹体的实验研究及其在激光拉曼探针测定方面的应用[J].岩石学报,2003,19(2):319-326.]
[20] Zhang Wenhuai,Chen Ziying.The Geology of Fluid Inclusions[M].Wuhan:China University of Geosciences Press,1993.[张文淮,陈紫英.流体包裹体地质学[M].武汉:中国地质大学出版社,1993.]
[21] Goldstein R H,Reynolds T J.Systematics of Fluid Inclusions in Diagenetic Minerals[M].Tulsa:SEPM, Short Course,1994.
[22] Ge Yunjin.Trapping Mechanism of Hydrocabon Inclusion in Carbonate and Its Response to Hydrocarbon Accumulation[D].Qingdao:China University of Petroleum(East China),2010.[葛云锦.碳酸盐岩烃类包裹体形成机制及其对油气成藏的响应[D].青岛:中国石油大学(华东),2010.]
[23] Pan Changchun,Zhou Zhongyi,Xie Qilai.Hydrocarbon inclusions:Implications to petroleum geology and geochemistry[J].Acta Sedimentologica Sinica,1996,14(4):15-23.[潘长春,周中毅,解启来.油气和含油气包裹体及其在油气地质地球化学研究中的意义[J].沉积学报,1996,14(4):15-23.]
[24] Cao Jian,Yao Suping,Hu Wenxuan,et al.Detection of water in petroleum inclusions and its implications[J].Chinese Science Bulletin,2006,51(12):1 501-1 507.[曹剑,姚素平,胡文瑄,等.油气包裹体中水的检出及其意义[J].科学通报,2006,51(13):1 583-1 588.]
[25] Teinturier S,Pironon J.Experimental growth of quartz in petroleum environment.Part Ⅰ:Procedures and fluid trapping[J].Geochimica et Cosmochimica Acta,2004,68(11):2 495-2 507.
[26] Sun He,Xiao Yilin.Fluid inclusions:Latest development,geological applications and prospect[J].Advances in Earth Science,2009,24(10):1 105-1 121.[孙贺,肖益林.流体包裹体研究:进展、地质应用及展望[J].地球科学进展,2009,24(10):1 105-1 121.]
[27] Song Mingshui.Limitation of restoring the paleohydrocarbon-water contact by GOI[J].Petroleum Geology and Recovery Efficiency,2007,14(3):5-8.[宋明水.含烃流体包裹体丰度法追溯古油水界面的局限性[J].油气地质与采收率,2007,14(3):5-8.]
[28] Zhao Yanjun,Chen Honghan.The relationship between fluorescence colors of oil inclusions and their maturities[J].Earth Science(Journal of China University of Geosciences),2008,33(1):91-96.[赵艳军,陈红汉.油包裹体荧光颜色及其成熟度关系[J].地球科学:中国地质大学学报,2008,33(1):91-96.]

[1] 蔡长娥,陈鸿,尚文亮,倪凤玲. 牙形石( U-Th/He热定年技术的研究进展[J]. 地球科学进展, 2020, 35(9): 924-932.
[2] 杜江民,龙鹏宇,杨鹏,丁强,胡秀银,李伟,柏杨,盛军. 中国陆相湖盆碳酸盐岩储集层特征及其成藏条件[J]. 地球科学进展, 2020, 35(1): 52-69.
[3] 王宇航, 朱园园, 黄建东, 宋虎跃, 杜勇, 李哲. 海相碳酸盐岩稀土元素在古环境研究中的应用[J]. 地球科学进展, 2018, 33(9): 922-932.
[4] 王小垚, 曾联波, 魏荷花, 孙建芳, 史今雄, 徐翔, 曹东升, 陆诗磊. 碳酸盐岩储层缝洞储集体研究进展[J]. 地球科学进展, 2018, 33(8): 818-832.
[5] 陈科贵, 刘思序, 王兆峰, 张翼飞. 基于曲线重构的缝洞型碳酸盐岩储层测井识别研究——以南图尔盖盆地Karabulak油田Pz层为例 *[J]. 地球科学进展, 2018, 33(11): 1154-1160.
[6] 王龙, KhalidLatif, MuhammadRiaz, 刘晓晔. 微生物碳酸盐岩的成因、分类以及问题与展望——来自华北地台寒武系微生物碳酸盐岩研究的启示[J]. 地球科学进展, 2018, 33(10): 1005-1023.
[7] 黄奇波, 覃小群, 刘朋雨, 张连凯, 苏春田. 非岩溶水和硫酸参与溶蚀对湘南地区地下河流域岩溶碳汇通量的影响[J]. 地球科学进展, 2017, 32(3): 307-318.
[8] 董爱国, 朱祥坤. 表生环境中镁同位素的地球化学循环[J]. 地球科学进展, 2016, 31(1): 43-58.
[9] 罗维均, 王世杰, 刘秀明. 喀斯特洞穴系统碳循环的烟囱效应研究现状及展望 *[J]. 地球科学进展, 2014, 29(12): 1333-1340.
[10] 张兴波,蒋勇军,邱述兰,曹敏,胡毅军. 农业活动对岩溶作用碳汇的影响:以重庆青木关地下河流域为例[J]. 地球科学进展, 2012, 27(4): 466-476.
[11] 黄思静,Hairuo QING,胡作维,王春梅,郜晓勇,邹明亮,王庆东. 四川盆地东北部三叠系飞仙关组碳酸盐岩成岩作用和白云岩成因的研究现状和存在问题[J]. 地球科学进展, 2007, 22(5): 495-503.
[12] 王勇. “白云岩问题”与“前寒武纪之谜”研究进展[J]. 地球科学进展, 2006, 21(8): 857-862.
[13] 刘燕学;柳永清;旷红伟. 一种严格受控于环境和时间的特殊碳酸盐岩——臼齿构造碳酸盐岩[J]. 地球科学进展, 2005, 20(7): 710-716.
[14] 韩贵琳;刘丛强. 贵州喀斯特地区河流的研究——碳酸盐岩溶解控制的水文地球化学特征[J]. 地球科学进展, 2005, 20(4): 394-406.
[15] 于晓果;李家彪. 天然气水合物分解及其生态环境效应研究进展[J]. 地球科学进展, 2004, 19(6): 947-954.
阅读次数
全文


摘要