地球科学进展 ›› 2003, Vol. 18 ›› Issue (3): 476 -482. doi: 10.11867/j.issn.1001-8166.2003.03.0476

研究论文 上一篇    下一篇

  1. 国家地质实验测试中心,北京 100037
  • 收稿日期:2002-08-13 修回日期:2003-01-07 出版日期:2003-06-01
  • 通讯作者: 王毅民 E-mail:wirma@ht.rol.cn.net
  • 基金资助:



Wang Yimin,Wang Xiaohong,Gao Yushu   

  1. National Research Center of Geoanalysis, Beijing 100037,China
  • Received:2002-08-13 Revised:2003-01-07 Online:2003-06-01 Published:2003-06-01

简述了现代地质分析的观念,在此基础上,从整体分析、微区原位分析和元素微区分布分析、显微观察和结构与形态分析、有机分析、地质年代学和稳定同位素分析及现场分析技术 6个方面评介了当今地质分析的现代技术与方法。地学需求是地质分析技术发展的原动力,现代分析科学是其发展的技术基础。最后指出了未来地质分析发展的主要趋向。

    The idea of modern geoanalysis is briefly described. Modern technologies and methods of geoanalysis are introduced and reviewed from six aspects: bulk analysis; micro-(in situ)analysis and element distribution analysis; structure, image and valence state analysis; organic and speciation analysis; age-dating and stable-isotope methods; and field(in situ) analysis techniques. The main content of each part is as follows:
    The idea of modern geoanalysis is shown by describing its history,development,formation of the idea and development trends in the future.
    Currently,the most important Bulk Analysis techniques are X-Ray Fluorescence Spectrometry(XRF), Inductively Coupled Plasma Atomic Emission Spectrometry(ICP-AES), ICP Mass Spectrometry(ICP-MS), Instrument Neutron Activation Analysis (INAA)and Total Reflection XRF(TRXRF).
    Microanalysis(in situ)and Element Distribution Analysis(element map) techniques include:①Electron microbeam techniques: Electron Microprobe Analysis(EMPA), Scanning Electron Microscopy(SEM), Analytical Electron Microscopy (AEM)and Transmitted Electron Microscopy (TEM);②X-ray and high-energy ion-beam techniques: Synchrotron Radiation X-ray Microprobe(SRXRM)and Scanning Nuclear Microprobe(SNM);③Laser and low energy ion-beam techniques: Laser Ablation ICP-MS(LA-ICP-MS) and Secondary Ion Mass Spectrometry(SIMS).
    Structure,image, and valence state analysis techniques involve: X-Ray Diffraction (XRD),various Electron Microscopy(EMPA, SEM, AEM and TEM)and some surface analysis techniques: Electron Spectroscopy for Chemical Analysis(ESCA),Auger Electron Spectroscopy(AES), Extended X-ray Absorption Fine Structure(EXAFS), X-ray Absorption Near Edge Structure(XANES) and Scanning Tunneling Microscope(STM)or Atomic Force Microscope(AFM).
    As a result of demands of energy-minerals and environment-geoscience research,the organic component and speciation analysis has been other important field in modern geoanalysis. Main techniques are Gas Chromatography(GC),Mass Spectrometry(MS),High Performance Liquid Chromatography(HPLC),Capillary Electrophoresis(CE), Laser Laman Spectroscopy(LLS),Fourier Infrared Spectrometry(FIRS), chemical sensor and their combined techniques.
    Dating and stable isotope analysis techniques include: the conventional TIMS,NIMS and new micro-dating techniques: SIMS,SHRIMP,LA-ICP-MS,AMS and Laser probe Ar/Ar dating.
    The field and in situ analysis techniques include: the geochemical detect of extraterrestrial materials, the analysis techniques on board and under water for marine mineral resources, the field analysis for general survey, mining, drill core and well logging.


[1] Potts P J. Geoanalysis: Past, present and future[J].Analyst,1997,122(11):1 179-1 186.

[2] Wang Yimin, Gao Yushu, Wang Xiaohong. The review and prospect on geoanalysis[J]. Chinese Journal of Analytical Chemistry, 2001, 29(7):845-851.[王毅民,高玉淑,王晓红.地质分析的历史发展及当今热点[J].分析化学, 2001,29(7):845-851.]

[3] Kane R J. Foreword. Geoanalysis '97[J]. The Analysts,1997, 122(11): 1 177.

[4] Carignan J,Telouk P, Valladon M. Guest editorial[J]. Geostandards Newsletter,2001,25(2/3):185.

[5] Wang Yimin, Gao Yushu, Wang Xiaohong. The prospects of geoanalysis in China viewed from the “Geoanalysis 2000”[J]. Acta Geoscientia Sinica,2001,22 (2):103-106.[王毅民,高玉淑,王晓红. “Geoanalysis 2000”国际会议看我国地质分析的未来发展[J]. 地球学报,2001,22 (2):103-106.]

[6] Wang Yimin. Bulk Analysis, microanalysis and distribution analysis for elements in rock and mineral[J]. Chinese Journal of Analytical Chemistry,1992,20(7):850-856. [王毅民.岩石矿物元素的整体分析、显微分析与分布分析[J].分析化学,1992,20(7):850-856.]

[7] Van Grieken R E, Markowicz A A, eds. Handbook of X-Ray Spectrometry: Methods and Applications[M]. New York :Marcel Dekker,1993.

[8] Walsh J N. Inductively Coupled Plasma-Atomic Emission Spectrometry(ICP-AES), In Modern Analytical Geochemistry [M]. Sigapore:Longman,1997.41-66.

[9] Thompson M, Walsh J N. Handbook of Inductively Coupled Plasma Spectrometry[M]. London: Chapman & Hall,1989.316.

[10] Van Loon I C, Barefoot R T. Analytical Methods for Geochemical Exploration[M]. New York: Academic Press Inc,1989.344.

[11] Jarvis K E, Gray A L, Houk R S. A handbook of Inductively Coupled Plasma Mass Spectrometry [M]. Glasgow:Blackie,1992.380.

[12] Michael E L, Stephen F W, John M H, et al. Geochemical and cosmochemical materials[J]. Analytical Chemistry, 2001,73:2690.

[13] Jakubowski N, Moons L, Vanhaecke F. Sector field mass spectrometries in ICP-MS[J]. Spectrochimica Acta, 1998,B53(13):1 739-1 763.

[14] Klockendamper R. Total-Reflection X-Ray Fluorescence Analysis[M]. New York.: John Wiley & Sons, 1997.245.

[15] Walds chlager U. Book of Abstracts,48th Annul. Denver X-ray Conference[Z]. Steamboat Springs,CO,2-6,1999.

[16] Knoth J, Beaven P A, Michaelsen C, et al. A tunable focusing monochromator for total reflection X-Ray fluorescence spectrometry[J]. X-Ray Spectrometry,1999,28(6):110.

[17] Hoffman E L. Instrumental neutron activation in geoanalysis[J]. Journal of Geochemical Exploration, 1992, 44:297-319.

[18] Tian W, Ni B, Wang P, et al. Metrological role of neutron activation analysisIA [J].Accredition Quality Assurance, 2001,6:488-492.

[19] Reed S J B. Electron Microprobe Analysis (2nd)[M]. Cambridge: Cambridge University Press,1993.

[20] Goldstein J I, Newbury D E, Echlin P, et al. Scanning Electron Microscopy and X-ray Microanalysis(2nd)[M]. New York: Plenum Press,1992.

[21] Carpenter D T, Watanabe M, Barmak K, et al. Proceeding of Microscopy and Microanalysis[Z]. New York:Springer,1997.537-538.

[22] Sparks C J Jr. XRF microprobe for chemical analysis[A]. In: Winich H, Doniach S, eds. Synchrotron Radiation Research[C]. New York :Plenum Press, 1980.459-512.

[23] Johansson S A E, Campbell J L, Malmqvist k G. Particle Induced X-ray Emission Spectrometry(PIXE)[M]. New York: Wiley & Sons,1995.

[24] Fraser D G. Applications of high resolution scanning proton microprobe in the earth sciences: A review[J]. Chemical Geology,1990 ,83:27-37.

[25] Zhu Jieqing, Wang Yimin. A study on element distributions and the change of growth-rate in a Mn-nodule micro-area[J]. Science in China(B), 1993,234:417-422. [朱节清, 王毅民. 锰结核微区元素分布及生长速率变化研究[J].中国科学:B,1993,234:417-422.]

[26] Zhou S,Ren C,Tang J, et al. SPM study the distribution of Carlin-type gold mineral deposit in China[J]. Nuclear Instrument & Method in Physical Research, 1995, B104: 437-444.

[27] Hsu H, Huss G R, Wasserburg G J. Ion probe measurements of Os, Ir, Pt, and Au in individual phases of iron meterorites[J]. Geochimica Cosmochimica Acta, 2000, 64(6):1 133-1 147.

[28] Reed S J B. Ion microprobe analysis: A review of geological application[J]. Mineralogical Magazine, 1989, 53:3-24.

[29] Schaltegger, Fanning C M, Gunther D, et al. Growth, annealing and recrystallization of zircon and preservation of wonazite in high-grade metamorphism: conventional and in situ U-Pb isotope, cathodoluminescence and microchemical evidence[J]. Contributions to Mineralogy and Petrology,1999,134(2):186-201.

[30] Jarvis K E, Williams J G. Laser ablation inductively coupled plasma mass spectrometry: A rapid technique for the direct, quantitative determination of maJor, trace and REE in geological samples[J]. Chemical Geology, 1993, 106:251-262.

[31] Turber N H, Schreifels J A. Surface analysis:X-ray photoelectron spectroscopy and auger electron spectroscopy [J]. Analytical Chemistry, 2000, 72:99R-110R.

[32] Mosbah M, Duraud J P, Metrich N, et al. Micro-XANES with synchrotron radiation: A complementary tool of Micro-PIXE and Micro-SXRF for the determination of oxidation state of elements application to geological materials[J]. Nuclear Instrument & Method in Physical Research, 1999,158:214.

[33] Wang Erkang, ed. The Analytical Chemistry in 21th Century[M]. Beijing: Science Press,1999.[汪尔康主编.21世纪的分析化学[M].北京:科学出版社,1999.]

[34] Mernagh T P, Wilde A R. The use of the laser raman microprobe for the determination of salinity in fluid inclusions [J]. Geochimica Cosmochimica Acta ,1989,53:765-771.

[35] Capman J R. Practical Organic Mass Spectrometry: A Guide for Chemical and Biochemical Analysis (2nd)[M]. Chichester:Wiley,1993.

[36] Nasdala L,Gotze J,Pidgeon R T. Constraining a SHRIMP U-Pb age: Micron scale characterization of zircons from Saxonian Rotliegend rhyolites[J]. Contributions to Mineralogy and Petrology,1998,132(3):300-306.

[37] Griffin W L, Pearson N J, Belousova E, et al. The Hf isotope composition of Cratonic mantle: LAM-MC-ICPMS analysis of Zircon megacrysts in kimberlites[J]. Geochimica et Cosmochimica Acta,2000,64(1):133-147.

[38] Hotchkis M, FinkD, Tuniz C. Accelerator mass spectrometry analyses of environmental radionuclides: Sensitivity, precision and standardisation[J]. Applied Radiatation Isotope,2000,53:31.

[39] Sharp Z D. In situ Laser microprobe techniques for stable isotope analysis[J]. Chemical Geology(Isotope Geoscience), 1992,101:3-19.

[40] Holland G, Tanner S D. Plasma Source Mass Spectrometry New Developments and Applications[M]. London: Royal Society of Chemistry,1999.

[41] Adler I, Trombka J, Gerard J, et al. Apollo 16 Geochemical X-ray fluorescence experiment: Preliminary report[J].  Science,1972,177:256.

[42] Rieder R, Wanke H, Economu T, et al. Determination of the chemical composition of martian soil and rocks: The alpha proton X-ray spectrometry[J]. Geophysical Research, 1997, E102:4 027-4 044.

[43] Brinckerhoff W B, Managadze G G, McEntire R W, et al. Laser time-of-flight mass spectrometry for space[J]. Review on Science Instrument,2000,71:536.

[44] Wang Y, Liang G, Teng Y. Determination of multiple elements in manganese nodules on board using XRF[J]. Marine Mining,1991,10(3):259.

[45] Ivanenko V V, Kovalenko V V, Kustov V N, et al.Nuclear methods of elemental analysis of ocean bottom sediments [J]. Journal of Radioanalytical & Nuclear Chemistry, 1991,147(9):321.

[46] Civici N,van Grieken R. EDXRF analysis in geochemical mapping[J]. X-Ray Spectrometry,1997,26(4):147.

[47] Hou X D, Jones B J. Field instrumentation in atomic spectroscopy[J].Microchemical Journal, 2000, 66:115.

[48] Sun Chengquan, Qu Jiansheng. Status and trends of the international earth science studies[J]. Advances in Earth Sciences, 2002,17(3):344-347.[孙成权,曲建升.国际地球科学发展态势[J]. 地球科学进展,2002,17(3):344-347.]

[49] Gao Hong. The Front of Analytical Chemistry[M]. Beijing: Science Press,1991.1-30.[高鸿主编.分析化学前沿[M].北京:科学出版社,1991.1-30.]

[50] Gill R. Modern Analytical Geochemistry[M]. Singapore:Longman,1997.

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