Please wait a minute...
img img
高级检索
地球科学进展  2011, Vol. 26 Issue (9): 997-1005    DOI: 10.11867/j.issn.1001-8166.2011.09.0997
IODP研究     
有孔虫Mg/Ca温度计研究进展——盐度影响及校正
徐建,李建如,乔培军
1.西北大学大陆动力学国家重点实验室和地质学系,陕西 西安 710069;
2.同济大学海洋地质学国家重点实验室和海洋与地球科学学院,上海 200092
Progresses in Study of Foraminiferal Mg/Ca-Thermometer: Salinity Effect and Its Correction
Xu Jian1, Li Jianru2, Qiao Peijun2
1.State Key Laboratory of Continental Dynamics and Department of Geology, Northwest University, Xi′an 710069, China;
2.State Key Laboratory of Marine Geology and School of Ocean and Earth Science, Shanghai 200092, China
 全文: PDF(1603 KB)  
摘要:

有孔虫壳体Mg/Ca温度计是近10年来发展最快、应用最广的恢复古海水温度的方法之一。随着研究的深入,这一方法面临的问题也越来越突出。其中,海水盐度影响壳体对Mg元素的吸收,是对Mg/Ca温度计“忠诚度”最具威胁性、也是近来最受人们关注的因素之一。查阅了最近2年有关Mg/Ca温度计中盐度效应的最新研究成果,整理出对盐度因素进行校正的方法和解决方案,以供国内同行借鉴和参考。

关键词: Mg/Ca盐度温度计有孔虫    
Abstract:

Mg/Ca-thermometer is one of the most rapidly developed and as well widely used tools to reconstruct paleo-seawater temperatures in the last decade. There is, however, a growing body of evidence showing that the thermometer is significantly biased by a variety of factors. Of them, salinity effect on Mg uptake into biogenic shell calcites is most recently highlighted, with intensive discussions on the “fidelity” of the Mg/Ca-thermometer in reconstructing paleo-seawater temperature, and in turn in calculating salinity when combining Mg/Ca and oxygen isotope on a same foraminiferal sample. In this article, we reviewed the most recent publications with respect to salinity effects on Mg/Ca-thermometer and summarized solutions and/or methods to correct for salinity effects. The objective of this article is to provide helpful and state-of-the-art references for scientists within the country who are engaged in paleoceanographic study using Mg/Ca-thermometer.

Key words: Mg/Ca    Salinity    Thermometer    Foraminifera
收稿日期: 2011-07-21 出版日期: 2011-10-10
:  P736.22  
基金资助:

国家自然科学基金青年基金项目“末次冰消期印尼穿越流的古海洋学变化及其影响”(编号:40906032);高等学校博士学科点专项科研基金“早全新世印尼穿越流古海洋学变化及对ENSO的响应”(编号:20096101120025);大陆动力学国家重点实验室自主研究课题“激光剥蚀ICPMS分析有孔虫壳体生源方解石Mg/Ca特征及其古海洋学应用”(编号:BJ11052)资助.

通讯作者: 徐建   
作者简介: 徐建(1977-),男,江苏新沂人,副教授,主要从事海洋微体古生物学、生物地球化学和古海洋学研究.E-mail:jx08@live.cn
服务  
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章  

引用本文:

徐建,李建如,乔培军. 有孔虫Mg/Ca温度计研究进展——盐度影响及校正[J]. 地球科学进展, 2011, 26(9): 997-1005.

Xu Jian, Li Jianru, Qiao Peijun. Progresses in Study of Foraminiferal Mg/Ca-Thermometer: Salinity Effect and Its Correction. Advances in Earth Science, 2011, 26(9): 997-1005.

链接本文:

http://www.adearth.ac.cn/CN/10.11867/j.issn.1001-8166.2011.09.0997        http://www.adearth.ac.cn/CN/Y2011/V26/I9/997

[1] Lea D W, Pak D K, Spero H J. Climate impact of late Quaternary Equatorial Pacific sea surface temperature variations[J].Science,2000,289(5 485):1 719-1 724.
[2] Visser K, Thunell R, Stott L. Magnitude and timing of temperature change in the Indo-Pacific warm pool during deglaciation[J].Nature, 2003, 421(6 919):152-155.
[3] Stott L, Timmerman A, Thunell R. Southern Hemisphere and deep-sea warming led deglacial atmospheric CO2 rise and tropical warming[J].Science, 2007,318(5 489): 435-438,doi:10.1126/science.1143791.
[4] Pfaumann U, Jian Z. Modern distribution patterns of planktonic foraminifera in the South China Sea and western Pacific: A new transfer technique to estimate regional sea-surface temperatures[J].Marine Geology, 1999, 156(1/4): 41-83.
[5] Yu K F, Chen T,  Huang D, et al. The high-resolution climate recorded in the δ18O of Porites lutea from the Nansha Islands of China[J].Chinese Sciences Bulletin, 2001, 46(24): 2 097-2 102.
[6] Yu K F, Zhao J X, Wei G J, et al. δ18O, Sr/Ca and Mg/Ca records of Porites lutea corals from Leizhou Peninsulanorthern South China Sea and their applicability as paleothermometers[J].Palaeogeography Palaeoclimatology Palaeoecology, 2005, 218:57-73.
[7] Wei Gangjian, Li Xianhua, Nie Baofu, et al. A high-resolution Mg/Ca thermometer in Porites Coral from the northern South China Sea[J].Chinese Sciences Bulletin,1998, 43(15): 1 658-1 661.[韦刚健, 李献华, 聂宝符, 等. 南海北部滨珊瑚高分辨率Mg/Ca温度计[J]. 科学通报,1998, 43(15):1 658-1 661.][8] Herbert T D. Alkenone paleotemperature determinations[C]Elderfield H ed. The Oceans and Marine Geochemistry Vol. 6 Treatise on Geochemsitry.Oxford: Elsevier-Pergamon,2003.
[9] Kim J H, Schouten S, Hopmans E C,et al. Global sediment core-top calibration of the TEX86 paleothermometer in the ocean[J].Geochimica et Cosmochimica Acta,2008,72(4):1 154-1 173, doi:10.1016/j.gca.2007.12.010.
[10] Ghosh P, Adkins J, Affek H, et al.13C-18O bonds in carbonate minerals: A new kind of paleothermometer[J].Geochimica et Cosmochimica Acta,2006,70(6):1 439-1 456, doi:10.1016/j.gca.2005.11.014.
[11] Gussone N, Eisenhauer A, Heuser A, et al.Model for kinetic effects on calcium isotope fractionation (δ44Ca) in inorganic aragonite and cultured planktonic foraminifera[J].Geochimica et Cosmochimica Acta,2003,67(7):1 375-1 382, doi: 10.1016/S0016-7037(02)01296-6.
[12] Bemis B E, Spero H J, Bijma J, et al.  Reevaluation of the oxygen isotopic composition of planktonic foraminifera: Experimental results and revised paleotemperature equations[J].Paleoceanography, 1998,13(2):150-160.
[13] Nürnberg D, Bijma J, Hemeleben C.  Assessing the reliability of magnesium in foraminiferal calcite as a proxy for water mass temperatures[J].Geochimica et Cosmochimica Acta,1996,60(5):803-814.
[14] Li Jianru.The application of foraminiferal shell Mg/Ca ratio in Paleo-environmental studies[J].Advances in Earth Science,2005,20(8):815-822.[李建如. 有孔虫壳体的Mg/Ca比值在古环境研究中的应用[J].地球科学进展, 2005,20(8):815-822.]
[15] Deng Wenfeng, Wei Gangjian, Li Xianhua. High-precision analysis of foraminiferal Mg/Ca ratios by ICP-AES[J].Marine Geology & Quaternary Geology,2005,25(2):147-151.[邓文峰, 韦刚健, 李献华.有孔虫的高精度Mg/Ca比值的ICP-AES[J]. 海洋地质与第四纪地质,2005,25(2):147-151.]
[16] Mortyn P G, Elderfield H, Anand P, et al.  An evaluation of controls on planktonic foraminiferal Sr/Ca: Comparison of water column and core-top data from a North Atlantic transect[J].Geochemostry Geophysics Geosystems,2005,6(12):Q12007,doi:10.1029/2005GC001047.
[17] Arbuszewski J,deMenocal P, Kaplan A,et al. On the fidelity of shell-derived δ18O seawater estimates[J].Earth and Planetary Science Letters,2010,300(3/4):185-196, doi:10.1016/j.epsl.2010.10.035.
[18] Lea D W. Elemental and isotopic proxies of past ocean temperatures[C]Elderfield H ed. The Oceans and Marine Geochemistry Vol. 6 Treatise on Geochemsitry. Oxford: Elsevier-Pergamon, 2003.
[19] Barker S, Cacho I, Benway H, et al. Planktonic foraminiferal Mg/Ca as a proxy for past oceanic temperatures: A methodological overview and data compilation for the Last Glacial Maximum[J].Quaternary Science Reviews,2005, 24(7/9):821-834, doi:10.1016/j.quascirev.2004.07.016.
[20] Huang K F, You C F,Lin H L, et al.  In situ calibration of Mg/Ca ratio in planktonic foraminiferal shell using time series sediment trap: A case study of intense dissolution artifact in the South China Sea[J].Geochemistry Geophysics Geosystems,2008,9: Q04016, doi:10.1029/2007GC001660.
[21] Farmer E C,Kaplan A, de Menocal P B, et al. Corroborating ecological depth preferences of planktonic foraminifera in the tropical Atlantic with the stable oxygen isotope ratios of core top specimens[J].Paleoceanography,2007,22, PA3205, doi:10.1029/2006PA001361.
[22] Mohtadi M,Steinke S, Groeneveld J, et al.  Low-latitude control on seasonal and interannual changes in plaktonic foraminferal flux and shell geochemistry off south Java: A sediment trap study[J]. Paleoceanography,2009, 24, PA1201, doi:10.1029/2008PA001636.
[23] Elderfield H,  Ganssen G. Past temperature and δ18O of surface ocean waters inferred from foraminiferal Mg/Ca ratios[J].Nature,2000,405(6 785):442-445.
[24] Xu Jian. Effect of shell size on planktonic foraminiferal biogeochemical records[J].Bulletin of Mineralogy, Petrology and Geochemistry,2010,29(2):109-118.[徐建. 壳体大小对浮游有孔虫生物地球化学记录的影响[J]. 矿物岩石地球化学通报,2010,29(2):109-118.]
[25] Rosenthal Y, Lohmann G P. Accurate estimation of sea surface temperatures using dissolution-corrected calibrations for Mg/Ca paleothermometry[J].Paleoceanography, 2002, 17(3):1 044, doi:10.1029/2001PA000749.
[26] Regenberg M, Nürnberg D, Steph S, et al. Assessing the effect of dissolution on planktonic foraminiferal Mg/Ca ratios: Evidence from Caribbean core tops[J].Geochemistry Geophysics Geosystems, 2006,7(7),doi:10.1029/2005GC001019.
[27] Pena L D, Cacho I, Calvo E,et al. Characterization of contaminant phases in foraminifera carbonates by electron microprobe mappin[J].Geochemistry Geophysics Geosystems,2008,9,Q07012, doi:10.1029/ 2008GC002018.
[28] Sadekov A, Eggins S M, de Deckker P, et al.  Surface and subsurface seawater temperature reconstruction using Mg/Ca microanalysis of planktonic foraminifera Globigerinoides ruber, Globigerinoides sacculifer, and Pulleniatina obliquiloculata[J].Paleoceanography,2009,24, PA3201, doi:10.1029/2008PA001664.
[29] Hoogakker B A A, Klinkhammer G P, Elderfield H, et al. Mg/Ca paleothermometry in high salinity environments[J].Earth and Planetary Science Letters,2009,284(3/4):583-589, doi:10.1016/j.epsl.2009.05.027.
[30] Boyle E A, Rosenthal Y. Chemical hydrography of the South Atlantic during the last glacial maximum: D13C vs. Cd[C]Wefer G, et al,eds. The South Atlantic: Present and Past Circulation. New York:Springer-Verlag,1996:423-443.
[31] Rosenthal Y, Perron-Cashman S, Lear C H, et al. Interlaboratory comparison study of Mg/Ca and Sr/Ca measurements in planktonic foraminifera for paleoceanographic research[J].Geochemistry Geophysics Geosystems, 2004, 5(4): Q04D09, doi:10.1029/2003GC00650.
[32] Yu J M, Elderfield H, Greaves M, et al. Preferential dissolution of benthic foraminiferal calcite during laboratory reductive cleaning[J].Geochemistry Geophysics Geosystems,2007,8,Q06016, doi:10.1029/2006GC001571.
[33] Xu J, Holbourn A, Kuhnt W, et al. Centennial changes in the thermocline structure of the Indonesian outflow during Terminations I and II[J].Earth and Planetary Science Letters, 2008, 273(40 545):152-162, doi:10.1016/j.epsl.2008.06.029.
[34] Bian N, Martin P A. Investigating the fidelity of Mg/Ca and other elemental data from reductively cleaned planktonic foraminifera[J].Paleoceanography, 2010, 25, PA2215, doi:10.1029/2009PA001796.
[35] Greaves M, Caillon N, Rebaubier H,et al. Interlaboratory comparison study of calibration standards for foraminiferal Mg/Ca thermometry[J].Geochemistry Geophysics Geosystems,2008,9(8):1-2, doi:10.1029/2008GC001974.
[36] Anand P,Elderfield H, Conte M H. Calibration of Mg/Ca thermometry in planktonic foraminifera from a sediment trap time series[J].Paleoceanography, 2003,18(2):1 050, doi: 10.1029/2002PA000846.
[37] Ferguson J E, Henderson G M, Kucera M, et al. Systematic change of foraminiferal Mg/Ca ratios across a strong salinity gradient[J].Earth and Planetary Science Letters,2008,265(1/2):153-166, doi:10.1016/j.epsl.2007.10.011.
[38] Duenas-Bohorquez A, da Rocha R E, Kuroyanagi A, et al. Effect of salinity and seawater calcite saturation state on Mg and Sr incorporation in cultured planktonic foraminifera[J].Marine Micropaleontology,2009,73(3/4):178-189, doi:10.1016/j.marmicro.2009.09.002.
[39] Mathien-Blard E,  Bassinot F. Salinity bias on the foraminifera Mg/Ca thermometry: Correction procedure and implications for past ocean hydrographic reconstructions[J].Geochemistry Geophysics Geosystems,2009,10, Q12011, doi:10.1029/2008GC002353.
[40] Xu J, Kuhnt W, Holbourn A, et al.Indo-Pacific Warm Pool variability during the Holocene and Last Glacial Maximum[J].Paleoceanography,2010,25, PA4230, doi:10.1029/2010PA001934.
[41] Boussetta S, Bassinot F, Sabbatini A, et al. Diagenetic Mg-rich calcite in Mediterranean sediments: Quantification and impact on foraminiferal Mg/Ca thermometry[J].Marine Geology,2011,280(1/4):195-240, doi:10.1016/j.margeo.2010.12.011.
[42] Lea D W, Mashiotta T A, Spero H J.  Controls on magnesium and strontium uptake in planktonic foraminifera determined by live culturing[J].Geochimica et Cosmochimica Acta,1999,63(16):2 369-2 379.
[43] Kisakuerek B, Eisenhauer A, Boehm F, et al. Controls on shell Mg/Ca and Sr/Ca in cultured planktonic foraminifern, Globigerinoides ruber (white)[J].Earth and Planetary Science Letters,2008,273(3/4):260-269, doi:10.1016/j.epsl.2008.06.026.
[44] Dekens P S, Lea D W, Pak D K, et al.  Core top calibration of Mg/Ca in tropical foraminifera: Refining paleotemperature estimation[J].Geochemistry Geophysics Geosystems,2002,3(4):1 022, doi:10.1029/2001GC000200.
[45] Rosenthal Y, Lohmann G P, Lohmann K C, et al. Incorporation and preservation of Mg in Globigerinoides sacculifer: Implication for reconstructing the temperature and 18O/16O of seawater[J].Paleoceanography,2000,15(1):135-145.
[46] Jian Z, Wang P, Chen M P, et al. Foraminiferal responses to major Pleistocene paleoceanographic changes in the southern South China Sea[J].Paleoceanography,2000,15(2):229-243.
[47] Rosenthal Y, Oppo D W, Linsley B K. The amplitude and phasing of climate change during the last deglaciation in the Sulu Sea, western equatorial Pacific[J].Geophysical Research Letters, 2003,30(8):1 428, doi:10.1029/2002GL016612.
[48] Li B, Wang J, Huang B, et al.  South China Sea surface water evolution over the last 12 Myr: A south-north comparison from Ocean Drilling Program Sites 1143 and 1146[J].Paleoceanography, 2004,19(1), PA1009, doi:10.1029/2003PA000906.
[49] Cheng X, Huang B, Jian Z, et al. Foraminiferal isotopic evidence for monsoonal activity in the South China Sea: A present-LGM comparison[J].Marine Micropaleontology, 2005,54(1/2):125-139, doi:10.1016/j.marmicro.2004.09.007.
[50] Tian J, Pak D K, Wang P, et al.  Late Pliocene Monsoon linkage in the tropical South China Sea[J].Earth and Planetary Science Letters,2006,252(1/2):72-81.
[51] Locarnini R A, Mishonov A V, Antonov J I, et al.  World Ocean Atlas 2005, Volume 1: Temperature[C]Levitus S ed. NOAA Atlas NESDIS 61.  Washington DC:U.S. Government Printing Office,2006:182.
[52] Barker S, Greaves M, Elderfield H. A study of cleaning procedures used for foraminiferal Mg/Ca paleothermometry[J].Geochemistry Geophysics Geosystems,2003, 4(9):1-25,doi:10.1029/ 2003GC000559,2003.
[53] Brown S J, Elderfield H. Variations in Mg/Ca and Sr/Ca ratios of planktonic foraminifera caused by postdepositional dissolution: Evidence of shallow Mg dependent dissolution[J].Paleocanography,1996,11(5):543-551.
[54] Russell A D, Hönisch B, Spero H J, et al. Effects of seawater carbonate ion concentration and temperature on shell U, Mg and Sr in cultured planktonic foraminifera[J].Geochimica et Cosmochimica Acta, 2004,68(21):4 347-4 361.
[55] Lohmann G P. A model for variation in the chemistry of planktonic foraminifera due to secondary calcification and selective dissolution[J].Paleoceanography,1995,10(3):445-457.
[56] Tachikawa K, Sépulcre S, Toyofuku T, et al. Assessing influence of diagenetic carbonate dissolution on planktonic foraminiferal Mg/Ca in the South-eastern Arabian Sea over the past 450 k years: Comparison between Globigerinoides ruber and Globigerinoides sacculifer[J].Geochemistry Geophysics Geosystems,2008,9, Q04037, doi:10.1029/2007GC001974.
[57] Sadekov A Y, Eggins S M, Klinkhammer G P, et al. Effects of seafloor and laboratory dissolution on the Mg/Ca composition of Globigerinoides sacculifer and Orbulina universa tests-A laser ablation ICPMS microanalysis perspective[J].Earth and Planetary Science Letters,2010,292(3/4):312-324, doi:10.1016/j.epsl.2010.01.039.
[58] Sadekov A, Eggins S M, De Deckker P, et al. Uncertainties in seawater thermometry deriving from intratest and intertest Mg/Ca variability in Globigerinoides ruber[J].Paleoceanography,2008,23, PA1215, doi:10.1029/2007PA001452.
[59] Benway H M, Haley B A, Klinkhammer G P,et al. Adaptation of a flow-through leaching procedure for Mg/Ca paleothermometry[J].Geochemistry Geophysics Geosystems, 2003,4(2): 8 403, doi:10.1029/2002GC000312.
[60] Schmidt G A, Bigg G R, Rohling E J. Global Seawater Oxygen-18 Database[EB/OL].http:data.giss.nasa.gov/o18data/,1999.
[61] LeGrande A N,  Schmidt G A. Global gridded data set of the oxygen isotopic composition in seawater[J].Geophysical Research Letters,2006, 33(12), L12604, doi:10.1029/2006GL026011.

[1] 张鹏, 袁洪林, 徐建, 高莲凤, 张振国, 杨策. 印尼海区浮游有孔虫壳体Mg/Ca值的LA-ICP-MS原位微区分析[J]. 地球科学进展, 2016, 31(5): 494-502.
[2] 孙永明,史久新,阳海鹏. 海水热力学方程TEOS-10及其与海水状态方程EOS-80的比较[J]. 地球科学进展, 2012, 27(9): 1014-1025.
[3] 简星, 关平, 张巍. 碎屑金红石:沉积物源的一种指针[J]. 地球科学进展, 2012, 27(8): 828-846.
[4] 梁丹,刘传联. 颗石藻元素地球化学研究进展[J]. 地球科学进展, 2012, 27(2): 217-223.
[5] 李琪,李前裕,王汝建. 20万年来南海古海洋研究的主要进展[J]. 地球科学进展, 2012, 27(2): 224-239.
[6] 陈小红,胡建宇,邳青岭,刘广平,陈照章. 厦门—泉州近岸海域海表温、盐度密集走航观测[J]. 地球科学进展, 2009, 24(6): 629-635.
[7] 李建如. 有孔虫壳体的Mg/Ca比值在古环境研究中的应用[J]. 地球科学进展, 2005, 20(8): 815-822.
[8] 赵平. 地热系统气体地球化学研究进展[J]. 地球科学进展, 1994, 9(1): 8-13.