地球科学进展 ›› 1997, Vol. 12 ›› Issue (6): 553 -563. doi: 10.11867/j.issn.1001-8166.1997.06.0553

全球变化研究 上一篇    下一篇

沿海海—气界面的化学物质交换
高原 1,Robert A. Duce 2   
  1. 1.美国Rutgers大学沿海海洋科学研究所;2.美国德克萨斯A&M大学地学院
  • 收稿日期:1997-01-13 修回日期:1997-05-22 出版日期:1997-12-01
  • 通讯作者: 高原,女,1955年10月出生,副研究员,主要从事海洋大气化学的研究。

AIR-SEA CHEMICAL EXCHANGE IN COASTAL OCEANS

GAO Yuan 1,Robert A.Duce 2   

  1. 1.Institute of Marine and Coastal Sciences,Rutgers University,USA;2.College of Geology,Texas A&M Universty,USA
  • Received:1997-01-13 Revised:1997-05-22 Online:1997-12-01 Published:1997-12-01

 沿海海—气界面化学物质的交换对生物地球化学循环起着十分重要的作用。大气沉降过程(包括干沉降和湿沉降等过程)是化学物质进入沿海区域的重要途径之一。物质平衡估算的结果指出,在某些沿海区域,经由大气输入的若干痕量物质的总量几乎相当于河流的输入量,有的甚至更多。大气沉降作用是一些沿海区域氮化物的重要来源,并与富营养化有紧密关系。目前大气沉降通量的估算还存在着相当大的误差,有待于进一步的发展和完善。 

Chemical exchange at the air coastal sea interface plays an important role in coastal biogeochemical cycles.Atmospheric deposition (dry plus wet)can be a significant process for chemical entering coastal waters.Mass balance estimates suggest that in some coastal regions,the atmospheric input of certain trace elements can be similar to or greater than that from rivers.Atmospheric deposition can be a significant non point source for nitrogen entering coastal systems,which could be an important mechanism responsible for coastal eutrophication.Currently estimates of atmospheric deposition rates have considerable uncertainty.Improvements in these estimates require the developments of methods for the direct measurements of both dry and wet fluxes. 

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1 Hu M H, Stallard R F, Edmond J M. Major ion chemistry of some large Chinese rivers. Nature,1982,298:550-553.
2 Shiller A M. Dissolved zinc in rivers. Nature,1985,317:49-52.
3 Windom H L, Smith R G,Maeda M. The geochemistry of lead in rivers, estuaries and the continental shelf of the southeastern United States. Mar Chem,1985,17:43-46.
4 Elbaz-Poulichet F, Martin J M, Wang W W, et al. Dissolved Cd behavior in some selected French and Chinese estuaries: Consequences on Cd supply to the ocean. Mar Chem,1987,22:125-136.
5 Shiller A M, Boyle E A. Variability of dissolved metals in the Mississippi River. Ceochim Cosmochim Acta,1987,51:3273-3277.
6 Zhang J, Huang W W. Concentrations of trace metals in the Qiangtang-Jiang River and its estuary in Southern China. Ambio,1988,17:36-39.
7 Van der Weijden C H, Middelburg J J. Hydrochemistry of the river Rhine: long term and seasonal variability, elemental budgets, base levels and pollution. Water Research,1989,23:1247-1266.
8 Duce R A, Hoffman G L, Ray B J, et al.Trace metals in the marine atmosphere: Sources and fluxes. In: Winelom H, Duce R A,e ds. Marine Pollutant Transfer. Lexington Books,Lexington,Mass,1976.77-120.
9 Rodhe H, Soederlund R, Ekstedt J. Deposition of airborne pollutants on the Baltic.Ambio,1980,9:168-173.
10 Dulac F, Buat-Menard P, Arnold M, et al. Atmospheric input of trace metals to the western Mediterranean Sea 1,Factors controlling the variability of atmospheric concentrations. J Geophys Res,1987,92:8437-8453.
11 Duce R A. Chemical exchange at the air-coastal sea interface.In:Mantoura R F C,Martin J M, Wollast R, eds. Ocean Margin Processes in Global Change.John Wiley &Sons,1991.92-109.
12 Bergametti G, Dutor A L, Buat-Menard P, et al. Seasonal variability of the elemental composition of atmospheric aerosol particles over the northwestern Mediterranean. Tellus,1989,41B:353-361.
13 Gao Y, Arimoto R, Duce R A, et al. Input of atmospheric trace elements and mineral matter to the Yellow Sea during the spring of a low-dust year. J Geophys Res,1992,97:3767-3777.
14 Injuk J, Grieken R van. Atmospheric concentrations and deposition of heavy metals over the North Sea: A literature review. J Atmos Chem,1995,20:1179-1212.
15 GESAMP (Group of Experts on Scientific Aspects of Marine Pollution) Working Group 14. The atmospheric input of trace species to the world ocean. Rep Stud 38, Geneva: World Meteorol Organ, 1989.106.
16 Duce R A. The impact of atmospheric nitrogen, phosphorus, and iron species on marine biological productivity In: Bu-at-Menard ed. The Role of Air-Sea Exchange in Geochemical Cycles. D.Reidel,Norwell,Mass,1986.497-529.
17 Martin J M, Gordon R M. Northeast Pacific iron distributions in relation to phytoplankton productivity. Deep-Sea Res, 1988,35:177-196.
18 Nriagu J O,Pacyna J M. Quantitative assessment of worldwide contamination of air, water and soils by trace metals.Nature,1988,333:134-139.
19 Paerl H W. Enhancement of marine primary production by nitrogen enriched acid rain.Nature,1985,315:747-749.
20 Arimoto R, Duce R A. Dry deposition models and the air-sea exchange of trace elements. J Geophys Res,1986,91:2787-2792.
21 Dulac F, Buat-Menard P, Ezat U, et al. Bergametti, Atmospheric input of trace metals to the westerm Mediterranean: uncertainties in modeling dry deposition from cascade impactor data. Tellus,1989,41:362-378.
22 Gao Y, Arimoto R, Duce R A, et al. Temporal and spatial distributions of dust and its deposition to the China Sea.Tellus,1996,in press.
23 Merrill J T. Atmospheric long-range transport to the Pacific Ocean, In: Riley J P, Chester R, Duce R A, eds Chemical Oceanography Vol.10.San Diego: Academic Press,1989.15-50.
24 Hayasaka T, Nakajima T, Yanaka M. The coarse particle aerosols in the free troposphere around Japan. J Geophys Res,1990,95:14039-14047.
25 Liu T S, et al. Loess and the Environment. China Ocean Press,1985.251.
26 Pattenden N J, Branson J R. Relation between lead in air and in petrol in two urban areas of Britain. Atmos Environ,1987,21:2481-2483.
27 Dedeuwaerder H. Study of the dynamic transport and of the fallout of some ecotoxicological heavy metals in the troposphere of the southern Bight of the North Sea, PhD dissertation, Vrije University,Brussels,Belgium,1988.
28 Cambray R S, Jefferies D F, Topping G. The atmospheric input of trace elements to the North Sea. Mar Sci Comm,1979,5:175-194.
29 Krell U, Rockner E. Model simulations of the atmospheric input of lead and cadmium into the North Sea. Atmos Environ,1988,22:375-381.
30 Van Aalst R M,van Ardenne R A M,de Kreuk Jr J F, et al. Pollution of the North Sea from the atmosphere, TNO, Report CL 82/152,Delft:Netherlands Organization for Applied Scientific Research.1982.
31 Cawse P A.A survey of atmospheric trace elements in the UK (1972~1973). AERE, Harwell, England (AERE Report R 7669),1974.
32 PARCOM. Current estimates of atmospheric inputs to the North Sea,North Annual Report on the Activities of the Paris Commission.Annex,1987.38-42.
33 Chester R, Saydam A C, Sharples E J. An approach to the assessment of local trace metal pollution in the Mediterranean atmosphere. Mar Poll Bull,1981,12:426-431.
34 Schneider B. Source characterization for atmospheric trace metals over Kiel Bight. Atmos Enviren,1987,21:1275-1283.
35 Schneider B. Input of atmospheric trace metals to the Baltic Sea area-an estimate based on the EGAP (HELCOM) monitoring data. Baltic Environment Protection Commission,HELCON,1989.
36 Oblad M, Selin E, Measurements of elemental composition in the background aerosol on the west coast of Sweden. Atmos Environ,1986,20:1419-1432.
37 Petersen G, Weber H, Grassl H. Modeling the atmospheric transport of trace metals from Europe to the North Sea and Baltic Sea. NATO Workshop on Control and Fate of Atmospheric Heavy Metals,Oslo,Norway,1989.
38 Church T M, Scudlark J R. Trace elements in precipitation at the middle Atlantic coast: A successful record since 1982. In: Deposition and Fate of Trace Metals in Our Environment. USDA Forest Service Report NC-150,Symposium Proceedings,Philadelphia,PA,1991.45-56.
39 Scudlark J R, Conko K M, Church T M. Atmospheric wet deposition of trace elements to Chesapeake Bay: CBAD study year 1 results. Atmos Environ,1994,28:1487-1498.
40 Dugdale R C. Nutrient limitation in the seas, dynamics, identification, and significance. Limnol Oceanogr,1967,12:685-695.
41 Carpenter E J, Capone D G. Nitrogen in the marine environment. New York: Academic Press,1983.
42 Paerl H W. Emerging role of atmospheric nitrogen deposition in coastal eutrophication: biogeochemical and trophic perspectives. Can J Fish Aquat Sci,1993,50:2254-2269.
43 Paerl H W. Dynamics of Blue-green Algal (Microcystis aeruginosa) Blooms in the Lower Neuse River, North Carolina: Causative Factors and Potential Controls. Report 87-229,Water Resources Research Institute, North Carolina State University, Raleigh, NC,NC 27695-7912,1987.164.
44 Ambio. Marine Eutrophication (whole issue). Ambio,1990,19:101-171,1990.
45 Zhang J. Atmospheric wet deposition of nutrient elements: correlation with harmful biological blooms in northwest Pacific coastal zones .Ambio,1994,23:464-468.
46 Nixon S W, Ammerman J W, Atkinson L P, et al. The fate of nitrogen and phosphorus at the land-sea margin of the North Atlantic Ocean.Biogeochemistry,1997,in press.
47 Wolfe G V, Bates T S, Charlson R J. Climatic and environmental implications of biogas exchange at the sea surface: modeling DMS and the marine biologic sulfur cycle. In: Manloura R F C, Martin J M, Wollast R, eds. Ocean Margin Processes in Global Change. John Wiley &Sons,1991.383-400.
48 Ayers G P, Gras J L. Seasonal relationship between cloud condensation nuclei and aerosol methanesulfonate in marine air.Nature,1991,353:834-835.
49 Burgermeister S, Georgii H W. Distribution of methanesulfonate,nss sulfate and dimethylsulfide over the Atlantic and the North Sea. Atmos Environ,1991,25A 587-595.
50 Watts S F, Brimblecombe P, Watson A J. Methanesulphonic acid, dimethyl sulphoxide and dimethy1 sulphone in aerosol. Atmos Environ,1990,24A:353-359.
51 Berresheim H.Distribution of atmospheric sulfur species over various wetland regions in the Southeastern USA.Atmos Environ,1993,27A:211-221.
52 Quinn P K, Covert D S, Bates T S, et al. Dimethylsulfide/cloud condensation nuclei/climate system:Relevant sizeresolved measurements of the chemical and physical properties of atmospheric aerosol particles. J Geophy Res,1993,98:10411-10427.
53 Mukai H, Yokouchi Y, Suzuki M. Seasonal variation of methanesulfonic acid in the atmosphere over the Oki Islands in the Sea of Japan. Atmos Environ,1995,29:1637-1648.
54 Gao Y, Arimoto R, Duce R A, et al. Atmospheric non-sea-salt sulfate, nitrate and methanesulfonate over the China Sea. J Geophys Res,1996,101:12601-12611.
55 Arimoto R, Duce R A, Savoie D L, et al. Relationships among aerosol constituents from Asia and the North Pacific during PEM-West A.J Geophys Res,1996,101:2011-2023.
56 Fitzgerald W F. Cycling of mercury between the atmosphere and oceans In: Buat-Menard,ed. The Role Air Sea Exchange in Geochemical Cycling. Reidel Publishing Company,1986.363-408.
57 Nriagu J O, Pacyna J M. Quantitative assessment of worldwide contamination of air, water and soils by trace metals.Nature,1988,333:134-139.
58 Fitzgerald W F. Atmospheric and oceanic cycling of mercury. In: Riley R P, Chester R, Duce R A, eds. Chemical Oceanography vol.10.New York: Academic Press,1989.152-186.
59 Mason R P,O’Donnell J, Fitzgerald W F. Elemental mercury cycling within the mixed layer of the equatorial Pacific Ocean. In: Watras C J, Huckabeeeds J W. Mersury as a Global Pollutant: Towards integration and synthesis. Lewis Publishers,1994.83-97.
60 Eisenreich S J, Looney B B, Thornton J D. Airborne organic contaminants in the Great Lakes ecosystem. Environ Sci Tech,1981,15:30-38.
61 Baker J E, Eisenreich S J. Concentrations and fluxes of PAHs and PCBs across the air-water interface of Lake Superi-or. Environ Sci Tech,1990,24:342-352.
62 Bopp R F. Revised parameters for modeling the transport of PCB components across an air-water interface. J Geophys Res,1983.88:2521-2529.
63 Leister D L, Baker J E. Atmospheric deposition of organic contaminants to the Chesapeake Bay. Atmos Environ,1994,28:1499-1520.

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