地球科学进展 ›› 2025, Vol. 40 ›› Issue (12): 1283 -1296. doi: 10.11867/j.issn.1001-8166.2025.062

地质资源与开发利用 上一篇    下一篇

奈曼旗南部山区富锶—偏硅酸地下水形成机制与开发潜力
曹文庚1,2(), 鲁重生1,2(), 庄海艳3, 丛日辉3, 仝艳龙4, 任宇1,2, 李祥志1,2, 卢瑶1,2, 王妍妍1,2   
  1. 1.中国地质科学院水文地质环境地质研究所,河北 石家庄 050061
    2.河北省/中国地质调查局地下水 污染机理与修复重点实验室,河北 石家庄 050061
    3.奈曼旗水务局,内蒙古 通辽 028300
    4.奈曼旗自然资源局,内蒙古 通辽 028306
  • 收稿日期:2025-07-14 修回日期:2025-09-19 出版日期:2025-12-10
  • 通讯作者: 鲁重生 E-mail:caowengeng@mail.cgs.gov.cn;cugblcs4515@163.com
  • 基金资助:
    中国地质调查局水文地质调查项目(DD20242500-1);中国地质科学院基本科研业务费专项(SK202411)

Formation Mechanism and Exploitation Potential of Strontium and Metasilicic Acid -Rich Groundwater in the Southern Mountainous Area of Naiman Banner

Wengeng CAO1,2(), Chongsheng LU1,2(), Haiyan ZHUANG3, Rihui CONG3, Yanlong TONG4, Yu REN1,2, Xiangzhi LI1,2, Yao LU1,2, Yanyan WANG1,2   

  1. 1.The Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geosciences, Shijiazhuang 050061, China
    2.Key Laboratory of Groundwater Contamination and Remediation, Hebei Province & China Geological Survey, Shijiazhuang 050061, China
    3.Water Affairs Bureau of Naiman Banner, Tongliao Inner Mongolia 028300, China
    4.Natural Resources Bureau of Naiman Banner, Tongliao Inner Mongolia 028306, China
  • Received:2025-07-14 Revised:2025-09-19 Online:2025-12-10 Published:2026-01-17
  • Contact: Chongsheng LU E-mail:caowengeng@mail.cgs.gov.cn;cugblcs4515@163.com
  • About author:CAO Wengeng, research areas include hydrogeological and hydrogeochemical research. E-mail: caowengeng@mail.cgs.gov.cn
  • Supported by:
    the Hydrogeological Survey Project of China Geological Survey(DD20242500-1);Chinese Academy of Geological Science Basal Research Fund(SK202411)

奈曼旗作为科尔沁农牧交错带水源涵养区,区内发现的富锶—偏硅酸地下水可为地下水健康研究和矿泉水开发提供契机。以内蒙古奈曼旗南部山区为靶区,基于水文地质调查与37组地下水样品测试数据,采用水文地球化学分析方法,揭示了富锶—偏硅酸地下水空间分异规律与成因机制。结果表明,研究区地下水呈中性—弱碱性,水化学类型以HCO3-Ca型为主,锶含量介于0.24~1.83 mg/L,偏硅酸含量介于14.9~29.9 mg/L,富锶—偏硅酸复合型地下水分布在区内麦饭石矿区周边;碳酸盐岩与硅酸盐岩风化溶解以及阳离子交替吸附促进了地下水中锶的富集,室内实验表明,麦饭石的溶滤有利于偏硅酸地下水的形成;研究也指明了区内孔隙—裂隙含水层具备富锶—偏硅酸地下水矿泉水开发潜力,为乡村振兴与地质资源协同利用提供了科学依据。

As a water conservation area in the Horqin agro-pastoral ecotone, Naiman Banner boasts strontium and metasilicic acid-rich groundwater, which provides opportunities for groundwater health research and mineral water development. This study selected the southern mountainous area of Naiman Banner, Inner Mongolia, as the target area. Based on hydrogeological surveys and test data from 37 groups of groundwater samples, hydrogeochemical analysis methods were employed to reveal the spatial differentiation patterns and formation mechanisms of strontium-rich and metasilicic acid groundwater. Results indicated that the groundwater in the study area is neutral weak alkaline, with HCO3-Ca as the main hydrochemical type. The strontium content ranges from 0.24 to 1.83 mg/L, and the metasilicic acid content ranges from 14.9 to 29.9 mg/L. The strontium rich metasilicic acid composite groundwater is distributed around the Maifanshi mining area in the area. The weathering and dissolution of carbonate rocks and silicate rocks, as well as the alternating adsorption of cations, promote the enrichment of strontium in groundwater. Indoor experiments have shown that the leaching of vermiculite is beneficial for the formation of metasilicic groundwater. The study also indicates that the pore fissure aquifer in the area has the potential for industrialized development of strontium and metasilicic acid-rich mineral water, providing scientific basis for rural revitalization and coordinated utilization of geological resources.

中图分类号: 

图1 奈曼旗南部山区地理位置及地下水样品分布
Fig. 1 Location and distribution of groundwater samples in southern mountainous area of Naiman Banner
图2 奈曼旗区域地质概况(a)和含水岩组富水性分区(b
Fig. 2 Geological mapaand water-rich zoning of water-bearing rock groupbin Naiman Banner
图3 奈曼旗地下水的Piper三线图
Fig. 3 Piper diagram of groundwater in Naiman Banner
表1 奈曼旗南部山区地下水水化学参数统计 (mg/L)
Table 1 Statistics of groundwater hydrochemical parameters in southern mountainous area of Naiman Banner
样品K+Na+Ca2+Mg2+HCO3-Cl-SO42-NO3-SrH2SiO3游离CO2TDSF-FeTHpH
NQ10.28018.550.37.512212.662.223.20.26421.09.93160.760.036 41587.45
NQ20.43017.351.97.51468.854.315.40.33127.813.33231.060.096 61617.25
NQ30.18034.398.316.829616.1111.025.70.62322.429.26230.730.023 03167.14
NQ41.34023.491.216.029329.846.038.50.55223.422.85620.580.177 02957.35
NQ50.19920.165.49.418317.561.024.80.38724.715.54020.510.036 72037.40
NQ60.62626.796.214.820243.884.280.70.52029.921.55780.400.649 03047.13
NQ70.52119.248.712.218914.029.323.60.50323.013.33560.760.122 01737.65
NQ80.62621.291.914.031128.049.315.40.56026.121.95540.380.042 02887.37
NQ90.32624.9164.030.0329102.052.6187.01.19025.328.09180.460.037 15357.29
NQ100.44315.499.218.137021.512.052.20.71226.724.66080.570.007 33247.51
NQ110.21813.082.613.924026.935.448.50.50920.026.34780.32<0.004 52657.50
NQ121.47025.789.413.721612.5113.040.81.02026.313.85310.28<0.004 52817.79
NQ130.49210.260.612.920419.69.240.80.38323.411.53770.640.023 52067.26
NQ140.63936.4276.042.3304240.077.8365.01.64018.035.91 3730.310.497 08696.97
NQ150.51824.287.615.323235.044.859.70.56921.712.45210.340.033 82837.58
NQ160.33921.199.816.827341.044.958.60.64420.017.55740.420.013 73207.28
NQ170.28712.672.711.720419.620.364.20.42820.410.74220.370.049 22317.53
NQ180.52253.9147.017.226988.655.4232.00.79026.915.88920.330.019 34397.34
NQ190.77733.098.016.326672.168.41.40.69921.315.85740.540.013 33147.45
NQ200.60326.0141.031.421192.874.9223.01.09017.710.28140.660.137 04847.67
NQ210.50842.2165.032.5291114.059.8254.00.97719.420.59780.370.020 05487.37
NQ220.43424.7104.022.432841.034.662.60.97221.715.86330.42<0.004 53547.49
NQ230.66724.4125.022.541453.643.427.80.97620.925.67290.460.005 14077.39
NQ240.76441.4138.037.425587.565.5269.01.64014.914.19121.460.015 85017.47
NQ250.57624.8191.033.140377.082.4204.01.83022.828.61 0340.43<0.004 56167.26
NQ260.46318.365.211.51986.369.36.80.51917.710.73900.300.393 02137.49
NQ270.26612.6103.016.522654.339.087.80.58520.016.75580.290.017 03277.30
NQ280.52522.8142.021.036563.065.159.70.77521.028.27580.280.007 64437.21
NQ290.48912.441.66.61668.16.610.60.24027.212.42740.380.017 11327.44
NQ300.42716.994.616.019819.6128.025.20.42821.320.55150.180.009 03037.23
NQ310.40416.554.410.52488.86.714.50.34428.09.83820.64<0.004 51807.51
NQ320.21114.883.112.825417.521.657.50.57223.512.84800.480.027 42617.43
NQ330.38415.758.29.316722.820.446.30.33424.77.73620.430.007 81857.53
NQ340.44113.759.714.92858.84.57.40.44421.713.74120.750.010 51967.47
NQ350.59021.185.816.33729.112.26.50.57522.221.35420.59<0.004 52837.36
NQ360.33510.257.312.62482.16.49.90.45122.011.13610.510.009 31967.67
NQ372.18084.9222.045.7403184.0119.0330.01.51017.127.81 4160.690.005 87467.37
最小值0.18010.241.66.61222.14.51.40.24014.97.72740.180.005 11326.97
最大值2.18084.9276.045.7414240.0128.0365.01.83029.935.91 4161.460.649 08697.79
平均值0.55024.2102.818.426246.551.183.80.72022.518.06090.520.080 03347.40
标准差0.38014.151.19.77550.833.298.90.4103.47.12740.240.140 01660.17
图4 奈曼旗地下水SrH2SiO3 的分布特征
(a)Sr与H2SiO3空间分布;(b)富Sr地下水数据统计;(c)富H2SiO3地下水数据统计。
Fig. 4 Distribution characteristics of groundwater Sr and H2SiO3 in Naiman Banner
(a) The spatial distribution of Sr and H2SiO3; (b) Sr-rich groundwater data statistics; (c) H2SiO3-rich groundwater data statistics.
图5 奈曼旗富Sr-H2SiO3 地下水富集过程分析
富Sr (a)和H2SiO3 (b)地下水Gibbs图;富Sr (c)和H2SiO3 (d)地下水离子比值端元图;不同风化程度的麦饭石在不同温度下溶出Sr (e)和H2SiO3 (f)的能力;(g)基于PHREEQC的饱和指数计算结果。
Fig. 5 Analysis of the enrichment process of Sr-H2SiO3-rich groundwater in Naiman Banner
The Gibbs diagram of groundwater rich in Sr (a) and H2SiO3 (b); Endmember diagrams of ion ratio in groundwater rich in Sr (c) and H2SiO3 (d); The ability of maifanite with different weathering degrees to dissolve Sr (e) and H2SiO3 (f) at different temperatures; (g) Saturation index calculation results based on PHREEQC.
图6 奈曼旗地下水化学组分的相关性散点图
Fig. 6 Correlation scatter plot of groundwater chemical components in Naiman Banner
图7 奈曼旗地下水中阳离子交换比值(a)和氯碱指数(b)关系图
Fig. 7 Relationship between cation exchange ratioaand chlor alkali indexbin groundwater of Naiman Banner
图8 奈曼旗地下水深度与pH关系(a)、δ18OδD分布(b)以及氘盈余(c
Fig. 8 Relationship between groundwater depth and pHa), distributionof δ18O and δDband deuterium surpluscin Naiman Banner
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