地球科学进展 ›› 2013, Vol. 28 ›› Issue (1): 51 -61. doi: 10.11867/j.issn.1001-8166.2013.01.0051

综述与评述 上一篇    下一篇

高砷地下水研究的热点及发展趋势
贾永锋,郭华明 *   
  1. 1.中国地质大学(北京)生物地质与环境地质国家重点实验室,北京100083;
    2.中国地质大学(北京)水资源与环境学院,北京100083
  • 收稿日期:2012-08-16 修回日期:2012-11-13 出版日期:2013-01-10
  • 通讯作者: 郭华明(1975-),男,江西乐安人,教授,主要从事地下水环境研究. E-mail:hmguo@cugb.edu.cn
  • 基金资助:

    国家自然科学基金项目“地下水生物地球化学”(编号:41222020)和“高砷地下水溶解性有机物特征及其对砷的生物地球化学作用机理”(编号:41172224);国家重点基础研究发展计划项目“人类活动条件下地下水数量和质量演变机理与趋势”(编号:2010CB428804)资助.

Hot Topics and Trends in the Study of High Arsenic Groundwater

Jia Yongfeng, Guo Huaming   

  1. 1.State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Beijing100083, China; 2.School of Water Resources and Environment, China University of Geosciences, Beijing100083, China
  • Received:2012-08-16 Revised:2012-11-13 Online:2013-01-10 Published:2013-01-10

全球范围内广泛分布的高砷地下水给人们的健康造成了极大的威胁。高砷地下水的形成机理是一项世界性的科学问题。介绍了高砷地下水的分布特点、富集机理,阐明了溶解性有机物、地下水流动特征对高砷地下水形成的影响机制。现今的研究揭示了有机物和微生物协同作用下高砷地下水的形成过程,并且在高砷地下水的空间分布、时间变化特征以及人类活动对高砷地下水形成的影响等方面取得了一些创新性成果。这3方面的研究也逐渐成为近些年高砷地下水研究的热点。这些研究不仅丰富了砷迁移转化的理论成果,而且有助于开辟低砷水源,保障水资源的可持续利用,具有重要的理论和现实意义。

High-arsenic groundwater widely spreads in the world, which has posed a great threat to human health. Mechanisms of arsenic mobilization in aquifer systems have been considered to be worldwide scientific issues. We outline characteristics of spatial distribution of high-arsenic groundwater and arsenic enrichment mechanisms. Controls of dissolved organic matter and groundwater flow on arsenic mobilization in groundwater are reviewed and discussed. Recent studies reveal synergistic effect of dissolved organic matter and microbial processes on genesis of high arsenic groundwater. Spatial and temporal variations of higharsenic groundwater and anthropogenic activities affecting the high-arsenic groundwater distribution have recently been characterized, and gradually become the hot topics in this field. These aspects are of great significance in enriching our understanding of transportation and transformation in aquifer systems and finding low-arsenic water resources for sustainable water development in arsenic-affected areas.

中图分类号: 

[1]Fendorf S, Michael H A, van Geen A. Spatial and temporal variations of groundwater arsenic in South and Southeast Asia [J]. Science, 2010, 328(5 982): 1 123-1 127.

[2]Guo H M, Zhang B, Li Y, et al. Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao Basin, Inner Mongolia [J]. Environmental Pollution, 2011, 159(4): 876-883.

[3]British Geological Survey and Department of Public Health Engineering, Bangladesh. Arsenic Contamination of Groundwater in Bangladesh: Final Report & BGS Technical Report WC/00/19[R]. Keyworth, UK: British Geological Survey,  2001.

[4]Mukherjee A, Bhattacharya P, Shi F, et al. Chemical evolution in high arsenic groundwater in Huhhot basin (Inner Mongolia, PR China) and its difference from Western Bengal Basin (India)[J]. Applied Geochemistry, 2009, 24: 1 835-1 851.

[5]Guo H M, Yang S Z, Tang X H, et al. Groundwater geochemistry and its implications for arsenic mobilization in shallow aquifers of the Hetao Basin, Inner Mongolia [J]. Science of the Total Environment, 2008, 393: 131-144.

[6]Guo Huaming, Yang Suzhen, Shen Zhaoli. High arsenic groundwater in the world: Overview and research perspectives [J]. Advances in Earth Science, 2007, 22 (11):1 109-1 117.[郭华明, 杨素珍, 沈照理. 富砷地下水研究进展[J]. 地球科学进展, 2007, 22(11) : 1 109-1 117.]

[7]Appelo C A, Postma D. Geochemistry, Groundwater and Pollution [M]. Leiden: Balkema Publishers, 1996. 

[8]Chowdhury T, Basu G K, Mandal B K, et al. Comment on Nickson et al. 1998, Arsenic poisoning of Bangladesh groundwater [J]. Nature, 1999, 401: 545-546.

[9]Acharyya S K, Chakraborty P, Lahiri S, et al. Arsenic poisoning in the Ganges Pelta[J]. Nature, 1999, 401: 545.

[10]Appelo C A, Van Der Weiden M J, Tournassat C, et al. Surface complexation of ferrous iron and carbonate on ferrihydrite and the mobilization of arsenic [J]. Environmental Science & Technology, 2002, 36(14): 3 096-3 103.

[11]Nickson R T, McArthur J M, Burgess W, et al. Arsenic poisoning of Bangladesh groundwater [J]. Nature, 1998, 395(6 700): 338.

[12]McArthur J M, Ravenscroft P, Safiulla S, et al. Arsenic in groundwater: Testing pollution mechanisms for sedimentary aquifers in Bangladesh [J]. Water Resources Research, 2001, 37(1): 109-117.

[13]Smedley P L, Kinniburgh D G. A review of the source,behavior and distribution of arsenic in natural waters [J]. Appllied Geochemistry, 2002, 17:517-568.

[14]Dowling C. The groundwater geochemistry of the Bengal Basin: Weathering, chemsorption, and trace metal flux to the oceans [J]. Geochimica et Cosmochimica Acta, 2003, 67(12): 2 117-2 136.

[15]Guo H M, Tang X H, Yang S Z. Effect of indigenous bacteria on geochemical behavior of arsenic in aquifer sediments from the Hetao Basin, Inner Mongolia: Evidence from sediment incubation [J]. Applied Geochemistry, 2008, 23: 3 267-3 277.

[16]Guo H M, Zhang B, Wang G C, et al. Geochemical controls on arsenic and rare earth elements approximately along a groundwater flow path in the shallow aquifer of the Hetao Basin, Inner Mongolia [J]. Chemical Geology, 2010, 270: 117-125.

[17]Senn D B, Hemond H F. Nitrate controls on iron and arsenic in an Urban Lake [J]. Science, 2002,296: 2 373-2 376.

[18]Harvey C F, Swartz C H, Badruzzaman B, et al. Arsenic mobility and groundwater extraction in Bangladesh[J].Science,2002,298(5 598):1 602-1 606.

[19]Polizzotto M L, Kocar B D, Benner S G, et al. Near-surface wetland sediments as a source of arsenic release to ground water in Asia [J]. Nature, 2008, 454(7 203): 505-508.

[20]Neumann R B, Ashfaque K N, Badruzzaman A B, et al. Anthropogenic influences on groundwater arsenic concentrations in Bangladesh [J]. Nature Geoscience, 2010, 3(1): 46-52.

[21]van Geen A, Zheng Y, Goodbred S, et al. Flushing history as a hydrogeological control on the regional distribution of arsenic in shallow groundwater of the Bengal Basin [J]. Environmental Science & Technology, 2008, 42: 2 283-2 288.

[22]Stute M, Zheng Y, Schlosser P, et al. Hydrological control of As concentrations in Bangladesh groundwater [J]. Water Resources Research, 2007, 43, doi:10.1029/2005WR004499.

[23]Aziz Z, van Geen A, Stute M, et al. Impact of local recharge on arsenic concentrations in shallow aquifers inferred from the electromagnetic conductivity of soils in Araihazar, Bangladesh [J]. Water Resources Research, 2008, 44: W07416, doi:10.1029/2007WR006000.

[24]Oremland R S, Stolz J F. Arsenic, microbes and contaminated aquifers[J]. Trends in Microbiology, 2005, 13(2): 45-49.

[25]Guo H M, Zhang B, Zhang Y. Control of organic colloids on arsenic partition and transport in high arsenic groundwaters in the Hetao Basin, Inner Mongolia [J]. Applied Geochemistry, 2011, 26: 360-370.

[26]Takahashi Y, Minai Y, Ambe S, et al. Comparison of adsorption behavior of multiple inorganic ions on kaolinite and silica in the presence of humic acid using the multitracer technique [J]. Geochimica et Cosmochimica Acta, 1999, 63: 815-836. 

[27]Grafe M. Arsenic Adsorption on Iron Oxides in the Presence of Soluble Organic Carbon and the Influence of Arsenic on Radish and Lettuce Development [D]. Virginia : Virginia Polytechnic Institute and State University, 2001.

[28]Grafe M, Eick M J, Grossl P R, et al. Adsorption of arsenate and arsenite on ferrihydrite in the presence and absence of dissolved organic carbon [J]. Journal of Environmental Quality, 2002, 31:1 115-1 123.

[29]Redman A D, Macalady D, Ahmann D. Natural organic matter affects arsenic speciation and sorption onto hematite [J]. Environmental Science & Technology, 2002, 36: 2 889-2 896.

[30]Ritter K, Aiken G R, Ranville J F. Evidence for the aquatic binding of arsenate by natural organic matter-suspended Fe(III) [J]. Environmenal Science & Technology, 2006, 40(17): 5 380-5 387.

[31]Bauer M, Blodau C. Arsenic distribution in the dissolved, colloidal and particulate size fraction of experimental solutions rich in dissolved organic matter and ferric iron [J]. Geochimica et Cosmochimica Acta, 2009, 73(3): 529-542.

[32]Guo H M, Zhang B, Yang S Z, et al. Role of colloidal particles for hydrogeochemistry in As-affected aquifers of the Hetao Basin, Inner Mongolia [J]. Geochemical Journal, 2009, 43: 227-234. 

[33]Islam F S, Gault A G, Boothman C, et al. Role of metal-reducing bacteria in arsenic release from Bengal delta sediments [J]. Nature, 2004, 430: 68-71.

[34]Campbell K M, Malasarn D, Saltikov C W, et al. Simultaneous microbial reduction of Iron(III) and Arsenic (V) in suspensions of Hydrous Ferric Oxide [J]. Environmental Science & Technology, 2006, 40 (19): 5 950-5 955.

[35]Rowland H A L, Pederick R L, Polya D A, et al. The control of organic matter on microbially mediated iron reduction and arsenic release in shallow alluvial aquifers, Cambodia [J]. Geobiology, 2007, 5(3): 281-292.

[36]Rowland H A L, Polya D A, Lloyd J R, et al. Characterisation of organic matter in a shallow, reducing, arsenic-rich aquifer, West Bengal [J]. Organic Geochemistry, 2006, 37(9): 1 101-1 114.

[37]Bhattacharya P, Chatterjee D, Jacks G. Occurrence of arsenic-contaminated groundwater in alluvial aquifers from delta plains, Eastern India: Options for safe drinking water supply [J]. Water Resoures Development, 1997, 13(1): 79-92.

[38]Nickson R T, McArthur J M, Ravenscroft P, et al. Mechanism of arsenic release to groundwater, Bangladesh and West Bengal [J]. Applied Geochemistry, 2000, 15(4): 403-413.

[39]Meharg A A, Scrimgeour C, Hossain S A, et al. Codeposition of organic carbon and arsenic in Bengal Delta aquifers [J]. Environmental Science & Technology, 2006, 40: 4 928-4 935.

[40]McArthur J M, Banerjee D M, Hudson-Edwards K A, et al. Natural organic matter in sedimentary basins and its relation to arsenic in anoxic ground water: The example of West Bengal and its worldwide implications [J]. Applied Geochemistry, 2004, 19(8): 1 255-1 293.

[41]Harvey C F, Ashfaque K N, Yu W, et al. Groundwater dynamics and arsenic contamination in Bangladesh [J]. Chemical Geology, 2006, 228(1/3): 112-136.

[42]Wang Yanxin, Su Chunli, Xie Xianjun, et al. The genesis of high arsenic groundwater: A case study in Datong Basin [J]. Geology In China, 2010, 37(3): 771-780. [王焰新, 苏春利, 谢先军,等. 大同盆地地下水砷异常及其成因研究[J]. 中国地质,2010,37(3): 771-780.]

[43]van Geen A, Zheng Y, Versteeg R, et al. Spatial variability of arsenic in 6000 tube wells in a 25 km2 area of Bangladesh [J]. Water Resources Research, 2003, 39:1140, doi:10,1029/2002WR001617.

[44]Guo H M, Zhang Y, Xing L N, et al. Spatial variation in arsenic and fluoride concentrations of shallow groundwater from the town of Shahai in the Hetao Basin, Inner Mongolia [J]. Applied Geochemistry, 2012, doi:10.1016/j.apgeochem.

[45]Tang Jie, Lin Nianfeng, Bian Jianmin, et al. Envrionmental geochemistry of arsenic in arseniasis areas in Hetao Plain, Inner Mongolia [J]. Hydrogeology &Engineering Geology, 1996,(1): 49-54. [汤洁,林年丰,卞建民, 等. 内蒙河套平原砷中毒病区砷的环境地球化学研究[J]. 水文地质工程地质, 1996, (1): 49-54.]

[46]Gao Cunrong. Research on the mechanism of arsenic pollution in groundwater in the Hetao Plain, Inner Mongolia, China[J].The Chinese Journal of Geological Hazard and Control, 1999, 10(2):25-32. [高存荣. 河套平原地下水砷污染机理的探讨[J].中国地质灾害与防治学报, 1999, 10( 2): 25-32.]

[47]Anawar H M, Komaki K, Akai J, et al. Diagenetic control on arsenic partitioning in sediments of the Meghna River Delta, Bangladesh [J]. Environmental Geology, 2002, 41: 816-825.

[48]Nath B, Berner Z, Mallik S B, et al. Characterization of aquifers conducting ground waters with low and high arsenic concentrations: A comparative case study from West Bengal, India [J]. Mineralogical Magazine, 2005, 69:841-854.

[49]van Geen A, Aziz Z, Horneman A, et al. Preliminary evidence of a link between surface soil properties and the arsenic content of shallow groundwater in Bangladesh [J]. Journal of Geochemical Exploration, 2006, 88: 157-161.

[50]Quicksall A N, Bostick B C, Sampson M. Linking organic matter deposition and iron mineral transformations to groundwater arsenic levels in the Mekong delta, Cambodia [J]. Applied Geochemistry, 2008, 23: 3 088-3 098.

[51]Polya D A, Gault A G, Diebe N. Arsenic hazard in shallow Cambodian groundwaters [J]. Mineralogical Magazine, 2005, 69: 807-823.

[52]Buschmann J, Berg M, Stengel C, et al. Arsenic and manganese contamination of drinking water resources in Cambodia: Coincidence of risk areas with low relief topography [J]. Environmental Science & Technology,2007,41:2 146-2 152.

[53]McArthur J M, Ravenscroft P, Banerjee D M, et al. How paleosols influence groundwater flow and arsenic pollution: A model from the Bengal Basin and its worldwide implication [J]. Water Resources Research, 2008, 44: W11411, doi:10.1029/2007WR006552. 

[54]McArthur J M , Nath B, Banerjee D M, et al. Palaeosol control on groundwater flow and pollutant distribution: The example of arsenic[J]. Environmental Science & Technology, 2011, 45(4): 1 376-1 383.

[55]Goovaerts P, AvRuskin G, Meliker J, et al. Geostatistical modeling of the spatial variability of arsenic in groundwater of southeast Michigan [J]. Water Resources Research, 2005, 41: W07013, doi:10.1029/2004WR003705. 

[56]Twarakavi N K C, Kaluarachchi J J. Aquifer vulnerability assessment to heavy metals using ordinal logistic regression [J]. Ground Water, 2005, 43: 200-214.

[57]Amini M, Abbaspour K C, Berg M, et al. Statistical modeling of global geogenic arsenic contamination in groundwater [J]. Environmental Science & Technology, 2008, 42:3 669-3 675.

[58]Winkel L, Berg M, Amini M, et al. Predicting groundwater arsenic contamination in Southeast Asia from surface parameters [J]. Nature Geoscience, 2008, 1(8): 536-542.

[59]Cheng Z, van Geen A, Seddique A A, et al. Limited temporal variability of arsenic concentrations in 20 wells monitored for 3 years in Araihazar, Bangladesh [J]. Environmental Science & Technology, 2005, 39: 4 759-4 766.

[60]Berg M, Tran H C, Nguyen T C, et al. Arsenic contamination of groundwater and drinking water in Vietnam: A human threat [J]. Environmental Science & Technology, 2001, 35: 2 621-2 626.

[61]Guo H M, Zhang Y, Zhao K, et al. Dynamic behaviors of water levels and arsenic concentration in shallow groundwater from the Hetao Basin, Inner Mongolia [J]. Journal of Geochemical Exploration, 2012, doi:10.1016/j.gexplo.2012.06.010.

[62]Central Ground Water Board. High Incidence of Arsenic in Groundwater in West Bengal[R]. Central Groundwater Board, Ministry of Water Resources, Fariadabad, India, 1999.

[63]Asia Arsenic Network. Arsenic Contamination of Groundwater in Bangladesh, Interim Report of the Research at Samta Village[R]. Asia Arsenic Network, Research Group for Applied Geology, Department of Occupational and Environmental Health, National Institute of Preventive and Social Medicine, Dhaka, Bangladesh, 1999.

[64]van Geen A, Ahmed K M, Seddique A A, et al. Community wells to mitigate the current arsenic crisis in Bangladesh [J]. Bulletin of the World Health Organization, 2003, 82: 632-638.

[65]Chakraborti D, Basu G K, Biswas B K, et al. Characterization of arsenic bearing sediments in Gangetic delta of West Bengal-India[C]∥Chappell W R, Abernathy C O, Caledenron R L, eds. Arsenic Exposure and Health Effects. New York: Elsevier Science, 2001: 27-52.

[66]Rosenboom J W. Arsenic in 15 Upazilas of Bangladesh: Water Supplies, Health and Behaviours—An Analysis of Available Data[R]. Report for the Department of Public Health Engineering (Bangladesh), the Department for International Development (U. K.), and UNICEF, 2004. 

[67]BBS/UNICEF (Bangladesh Bureau of Statistics/United Nations Children’s Fund) Bangladesh National Drinking Water Quality Survey of 2009[R]. Dhaka, Bangladesh, 2011.

[68]Michael H A, Voss C I. Evaluation of the sustainability of deep groundwater as an arsenic-safe resource in the Bengal Basin [J]. Proceedings of the National Academy of Sciences, 2008, 105: 8 531-8 536.

[69]Burgess W G, Hoque M A, Michael H A, et al. Vulnerability of deep groundwater in the Bengal Aquifer System to contamination by arsenic [J]. Nature Geoscience, 2010, 3: 83-87.

[70]Radloff K A, Zheng Y, Michael H A, et al. Arsenic migration to deep groundwater in Bangladesh influenced by adsorption and water demand [J]. Nature Geoscience, 2011, 11(4): 793-798.

[71]van Geen A, Zheng Y, Stute M, et al. Comment on “Arsenic mobility and groundwater extraction in Bangladesh” (II) [J].Science, 2003, 300: 584c.

[72]Aggarwal P K, Basu A R, Kulkarni K M. Comment on “Arsenic mobility and groundwater extraction in Bangladesh” (I) [J].Science, 2003, 300: 584b.

[73]Klump S, Kipfer R, Cirpka O, et al. Groundwater dynamics and arsenic    mobilization in Bangladesh assessed using noble gases and tritium[J].Environmental Science & Technology, 2006, 40(1): 243-250.

[74]Sengupta S, McArthur J M, Sarkar A, et al. Do ponds cause arsenic-pollution of groundwater in the Bengal Basin? An answer from West Bengal [J]. Environmental Science & Technology, 2008, 42(14): 5 156-5 164.

[75]Kim K, Moon J T, Kim S H, et al. Importance of surface geologic condition in regulating As concentration of groundwater in the alluvial plain [J]. Chemosphere, 2009, 77: 478-484.

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