地球科学进展 ›› 2008, Vol. 23 ›› Issue (8): 821 -829. doi: 10.11867/j.issn.1001-8166.2008.08.0821

综述与评述 上一篇    下一篇

三氯乙烯污染土壤和地下水污染源区的修复研究进展
高霏,刘 菲*,陈鸿汉   
  1. 中国地质大学水资源与环境工程北京市重点实验室,北京 100083
  • 收稿日期:2008-01-21 修回日期:2008-05-09 出版日期:2008-08-10
  • 通讯作者: 刘菲(1969-),女,河北定兴人,副教授,主要从事地下水有机污染治理及环境监测研究. E-mail:feiliu@cugb.edu.cn
  • 基金资助:

    中国科技部合作项目“污染场地的土壤地下水有机污染健康风险评价与修复研究”(编号:2006DFA21180);国家自然科学基金项目“地下水中氯代烃污染的生物活化共代谢降解研究”(编号:40372109)和“地下水中单环芳烃和氯代有机溶剂混合污染羽的化学生物联合处理技术研究”(编号:40572146)资助.

Progress on Remediation of Trichloroethylene (TCE) in Soil and Groundwater Contaminated Source Area

Gao Fei,Liu Fei,Chen Honghan   

  1. Key Laboratory of Water Resources and Environmental Engineering, China University of Geosciences, Beijing 100083,China
  • Received:2008-01-21 Revised:2008-05-09 Online:2008-08-10 Published:2008-08-10

作为现代工业中广泛使用的氯代溶剂,三氯乙烯(TCE)对土壤和地下水的普遍污染及其对人体健康的影响已经引起了人们的重视,关于其处理方法也受到人们的广泛关注。通过查阅国内外文献资料,对化学氧化、热修复及生物修复3种原位修复TCE污染的土壤和地下水污染源区的方法进行了总结,并在此基础上重点讨论了Fenton氧化、过硫酸盐氧化、蒸汽强化提取法及电阻加热法等原位修复方法。

Trichloroethylene (TCE) has been the most prevalent contaminant in soil and groundwater due to its wide use in modern industrial production. However, its impact on human health has also been a growing concern. Four kinds of In-Situ remediation of TCE-contaminated soil and groundwater source area, including In-Situ Chemical Oxidation (ISCO), In-Situ Thermal Treatment (ISTR) and In-Situ Bioremediation, were summarized in detail based on the exrtensive review of the worldwide literatures. Other In-Situ remediation techniques were also discussed, such as Fenton Oxidation, Persulfate Oxidation, Steam Enhanced Extraction (SEE) and Electrical Resistance Heating (ERH).

中图分类号: 

[1] Fountain J C. Technology for Dense Non-aqueous Phase Liquid Source Zone Remediation [R]. Groundwater Remediation Technologies Analysis CenterTE-98-021998.

[2] Palmer C JJohnson R L. Physical processes controlling the transport of non-aqueous phase liquids in the subsurface [C]Seminar Publication: Transport and Fate of Contaminants in the SubsurfaceEnviromental Protection AgencyWashington DCEPA-625-4-89-0191989:23-28.

[3] Jerald L S. Environmental Modeling: Fate and Transport of Pollutants in WaterAir and Soil [M]. New York: John Wiley & SonsInc1996.

[4] Grathwohl PTeutsch G. In-situ remediation of persistent organic contaminants in groundwater [C]International Conference on Groundwater Quality ProtectionTaipei1997:85-99.

[5] USEPA. Field Application of In Situ Remediation Technologies: Permeable Reactive Barriers [R]. Office of Solid Waste and Emergency ResponseTechnology Innovation OfficeEPA-542-R-99-0021999.

[6] USEPA1998 Metal-Enhanced Dechlorination of Volatile Organic Compounds Using an In-Situ Reactive Iron WalNational Risk Management Research Laboratory and Office of Research and Development [R]. EPA-540-R-98-5011998.

[7] Bedient P BRifai H SNewell C J. Groundwater Contamination: Transport and Remediation2nd[M]. New Jersey: PTR Prentice-Hall1999.

[8] Siegrist R LUrynowicz M AWest O Ret al. Genesis and effects of particles produced during in situ chemical oxidation using permanganate [J]. Journal of Environmental Engineering2002128:1 068-1 079.

[9] Schnarr MTruax CFarquhar Get al. Laboratory and controlled field experiments using potassium permanganate to remediatetrichloroethylene and perchloroethylene DNAPLs in porous media [J]. Journal of Contaminant Hydrology199829:205-224.

[10] Thomson N RHood E DMacKinnon J K. Source zone removal using permanganate: Expectation and potential limitations [C]Second International Conference on Remediation of Chlorinated and Recalcitrant Compound. MontereyCaliforniaUSA May 22-252000.

[11] Mckay DHewitt AReitsma Set al. In situ oxidation of trichloroethylene using potassium permanganate Part 2: Pilot study [C]Proceedings of the First International Conference on Remediation of Chlorinated and Recalcitrant Compounds. MontereyCalifornia1998.

[12] West O RCline S RHolden W Let al. A Full Scale Demonstration of In Situ Chemical Oxidation Through Recirculation at the X-701B Site: Field Operations and TCE Degradation [R]. Oak Ridge National LaboratoryORNL/TM-135561998.

[13] Parker B LAl T A. Full scale permanganate remediation of a solvent DNAPL source zone [C]Proceedings of the Third International Conference on Remediation of Chlorinated and Recalcitrant Compounds. MontereyCaliforniaMay 20-232002.

[14] Yan Y ESchwartz F W. Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate [J]. Journal of Contaminant Hydrology1999374:343-365.

[15] Gates DSiegrist R L. In-situ chemical oxidation of trichloroethylene using hydrogen peroxide [J]. Environmental Engineering19951219: 639-644.

[16] Droste E XMarley M CParikh J Met al. Observed enhanced reductive dechlorination after in situ chemical oxidation pilot test [C]Gavaskar A RChen A S Ceds. Proceedings of the Third International Conference on Remediation of Chlorinated and Recalcitrant Compounds. Columbus:Battelle Press2002.

[17] Cheng P WOlvey C E. Removal of Halomethanes From Water with Ozonation [R]. Natural Resources Library. US Deptment of the Interior. Final Report Project #A-072-RI. 1972.

[18] Glaze W HKang J.Advanced Oxidation Processes for Treating Groundwater Contaminated with TCE and PCE: Laboratory Studies [R]. Journ AWWA 571988:63.

[19] Francis P D. Oxidation by UV and Ozone of organic contaminants dissolved in deionized and raw mains water [J]. Ozone Science and Engineering19879:369-390.

[20] Fenton H J H. Oxidation of tartaric acid in presence of iron [J]. Journal of Chemical Society18945:889-910.

[21] Watts R JUdell M DRauch P A. Treatment of pentachlorophenol contaminated soil using Fenton's reagent [J]. Hazardous Waste and Hazardous Materials19907: 335-345.

[22] Ravikumar J XGurol M D. Chemical oxidation of chlorinated organics by hydrogen peroxide in the presence of sand [J]. Environmental Science and Technology1994283: 394-400.

[23] Ye GuijunLi ShangzhangWu Hongminget al. Study on the removal of TCE DNAPL in the subsurface Aquifer using Fenton’s reactions [C]The Fourth Conference on Groundwater Resources and Water Quality Protection.Taipei2001:109-116.[叶桂君,李尚璋,吴鸿明,等.Fenton氧化法去除地下水层中的TCE DNAPL之探讨[C]第四届地下水资源及水质保护研讨会论文集,台北,2001:109-116.]

[24] Watts J RHaller R DJones P Aet al. A foundation for the risk-based treatment of gasoline-contaminated soils using modified Fenton’s reactions [J]. Journal of Hazardous Materials200076: 73-89.

[25] Chapelle F HBradley P MCasey C C. Behavior of a chlorinated ethane plume following source-area treatment with Fenton's reagent [J]. Gound Water Monitoring and Remediation2005252:131-141.

[26] Brown R ARobinson DSkladany Get al. Response to naturally occurring organic material: Permanganate versus persulfate [C]Proceedings of Consoil2003-8th International FZK/TNO Conference on Contaminated Soil. May 12-16Genter Belgium. 2003:1 692-1 698.

[27] Kelly K LMarley M CSperry K L. In situ chemical oxidation on MTBE [C]Proceedings of 2002 Joint CSCE/EWRI of ASCE International Conference on Environmental Engineering. July 21-24Niagara FallsOntarioCanada2002.

[28] Bruell C J. Kinetics of Thermally Activated Persulfate Oxidation of TrichloroethyleneTCE and 111-TrichloroethaneTCA[C]The First International Conference on Oxidation and Reduction Technologies for In-Situ Treatment of Soil and GroundwaterNiagara FallsOntarioCanadaJune 25-292001.

[29] Liang CBruell C JMarley M Cet al. Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple [J]. Chemosphere2004559: 1 213-1 223.

[30] Sperry K LMarley M CBruell C Jet al. Iron catalyzed persulfate oxidation of chlorinated solvents [C]Third International Conference on Remediation of Chlorinated and Recalcitrant CompoundsMonterey. CA; USA; 20-23 May 20032002.

[31] Meyer M. Sodium Persulfate Oxidation of TCE Plume In Belgium [C]The Second International Conference on Oxidation and Reduction Technologies for In-Situ Treatment of Soil and GroundwaterTorontoOntarioNovember 19-222002.

[32] Block P A. Novel activation technologies for sodium persulface in-situ chemical oxiolation [C]Proceeding of the Fourth International Conference on the Remediation of Chlorinated and Recalcitrant Compounds. MontereyCalifornia2004.

[33] Fruchter J SCole C RWilliam M Det al. Creation of a Subsurface Permeable Treatment Barrier Using In Situ Redox Manipulation [R]. Pacific Northwest National LaboratoryRichlandWA1995.

[34] Siegrist R L. In situ chemical oxidation: Technology features and applications [C]Conference on Advances in Innovative Ground-water Remediation Technologies. AtlantaGA. 15 December1998.

[35] USEPA. In Situ Remediation Technology: In Situ Chemical Oxidation. Office of Solid Waste and Emergency Response [R]. Washington DC: EPA 542-R-98-0081998.

[36] Masten S JDavies S H R. Efficacy of In-situ ozonation for the remediation of PAH contaminated soils [J]. Journal of Contaminant Hydrology199728: 327-335.

[37] Davis E. How heat can enhance in-situ soil and aquifer remediation: Important chemical properties and guidance on choosing the appropriate technique. EPA/540/S-97/502 Robert S[R]. Kerr Environmental Research Laboratory1997.

[38] Udell K S. Thermally enhanced removal of liquid hydrocarbon contaminants from soils and groundwater [C]Ward C HCherry J AScalf M Reds. Subsurface Restoration. ChelseaMI: Ann Arbor Press1997:251-270.

[39] Udell K SSitar NHunt J Ret al. Process for In Situ Decontamination of Subsurface Soil and Groundwater [R]. United States Patent 50185761991.

[40] Udell K SStewart L D. Field study of in situ steam injection and vacuum extraction for recovery of volatile organic solvents [R]. UCB-SEEHRL Report No. 89-2. BerkeleyCalifornia: University of CaliforniaBerkeley1989.

[41] Smith L AHinchee R E. In Situ Thermal Technologies for Site Remediation [M]. Boca Raton: Lewis Publishers1993.

[42] Heron GChristensen T HHeron Tet al. Thermally enhanced remediation at DNAPL sites: The competition between downward mobilization and upward volatilization [C]Proceedings of the First International Conference on Remediation of Chlorinated and Recalcitrant CompoundsMontereyCaliforniaColunbusMay 18-21Ohio: Battelle Press1998.

[43] Kaslusky S FUdell K S. A theretical model of air and steam co-injection to prevent the downward migration of DNAPLs during steam-enhanced extraction [J]. Journal of Contaminant Hydrology200255: 213-232.

[44] Buelt J LOma K H. In-Situ Heating to Detoxify Organic Contaminated Soils[R]. US Patent #49573931990.

[45] Heron GVan Zutphen MChristensen T Het al. Soil heating for enhanced remediation of chlorinated solvents: A laboratory study on resistive heating and vapor extraction in a siltylow-permeable soil contaminated with trichloroethylene [J]. Environmental Science and Technology19983210: 1 474-1 481.

[46] Beyke G. Electrical Resistance Heating for In-Situ Remediation of Soil and Groundwater. Presented at: In Situ Treatment of Groundwater Contaminated with NAPL: Fundamentals and Case Studies [R]. Sponsored by Technology Innovation OfficeUS EPA. Washington DCChicagoIL. 2002.

[47] Truex MPowell TLynch K. In situ dechlorination of TCE during aquifer heating [J]. Ground Water Monitoring and Remediation2007272: 96-105.

[48] Heron GCarroll SNielsen S G. Full-scale removal of DNAPL contituents using steam-enhanced extraction and electrical resistance heating [J]. Ground Water Monitoring and Remediation2005254: 92-107.

[49] USEPA.In Situ Treatments of Chlorinated Solvents: Fundamentals and Field Applications [R]. EPA-542-R-04-010March2004:1-34.

[50] Newmark R LAines R D. Lawrence Livermore National Laboratory [R]. Berkeley Environmental Restoration CenterUCRL-ID-1204161995.

[51] United States Department of EnergyUS DOE. Pinellas Environmental Restoration ProjectNortheast Site Area A NAPL Remediation Final Report [R]. GJO-2003-482-TAC. September2003.

[52] Udell K SItamura M T. Removal of dissolved solvents from heated heterogeneous soils during depressurization [C]Wickramanayake G BHinchee R Eeds.PhysicalChemicaland Thermal Technologies: Remediation of Chlorinate and Recalcitrant Compounds. Columbus: Battelle Press1998:57-62.

[53] Knauss K GCopenhaver S CAines R D. Hydrous Pyrolysis/Oxidation Process for In Situ Destruction of Chlorinated Hydrocarbon and Fuel Hydrocarbon contaminants in Water and Soil [R]. U S Patent 6127592. Date Issued: 3 October2000.

[54] Betts K S. Technology combination cuts DNAPL cleanup time at Superfund site [J]. Environmental Science and Technology199832:359.

[55] Friis A KAlbrechtsen H JHeron Get al. Redox processes and release of organic matter after thermal treatment of a TCE-contaminated aquifer [J]. Environmental Science and Technology20053915: 5 787-5 795.

[56] Friis A KHeimann A CJakobsen Ret al. Temperature dependence of anaerobic TCE-dechlorination in a highly enriched Dehalococcoides-containing culture[J]. Water Research200741: 355-364.

[57] Nielsen R BKeasling J D. Reductive dechlorination of chlorinated ethene DNAPLS by a culture enriched from contaminated Groundwater [J]. Biotechnology and Bioengineering199962:160-165.

[58] Davis J WCarpenter C. Aerobic biodegradation of vinyl chloride in groundwater samples [J]. Applied and Environmental Microbiology199056:3 870-3 880.

[59] Fogel M MTaddeo A RFogel S. Biodegradation of chlorinated ethenes by a methane-utilizing mixed culture [J]. Applied and Environmental Microbiology198651: 720-724.

[60] Malachowsky K JPhelps T JTeboli A Bet al. Aerobic Mineralization of trichloroethylenevinyl chloride and aromatic compounds by rhodococcus species [J]. Applied and Environmental Microbiology199460: 542-548.

[61] Nelson Y MJewell W J. Methanotrophic biodegradation of vinyl chloride [J]. Journal of Environmental Engineering1993119: 890-907.

[62] Vogel T MCriddle C SMcCarty P L. Transformation of halogenated aliphatic compounds [J]. Environmental Science and Technology198721: 722-736.

[63] Wilson J TWilson B H. Biotransformation of trichloroethylene in soil [J]. Applied and Environmental Microbiology198549: 242-243.

[64] Little C DPalumbo A VHerbes S Eet al. Trichloroethylene biodegradation by a methaneoxidizing bacterium [J]. Applied and Environmental Microbiology198854: 951-956.

[65] Fliermans C BPhelps T JRingelberg Det al. Mineralization of trichloroethylene by heterotrophic enrichment cultures [J]. Applied and Environmental Microbiology198854:1 709-1 714.

[66] Folsom B RChapman P J. Performance characterization of a model bioreactor for the biodegradation of trichloroethylene by pseudomonas cepacia G4 [J]. Applied and Environmental Microbiology1991576:1 602-1 608.

[67] Leahy J GByrne A MOlsen R H. Comparison of factors influencing trichloroethylene degradation by toluene-oxidizing bacteria[J]. Applied and Environmental Microbiology199662: 825-833.

[68] Wackett L PGibson D T. Degradation of tricholoethylene by toluene dioxygenase in whole-cell studies with Pseudomonas putida F1 [J]. Applied and Environmental Microbiology198854: 1 703-1 708.

[69] Seprini L. Strategies for the Aerobic Co-metabolism of Chlorinated Solvents [M]. Current Opinion in Biotechnology1997.

[70] Chen CuibaiYang QiShang Haitaoet al. Biodegradation of trichloroethyleneTCE under aerobic conditions [J]. Techniques and Equipment for Environmental Pollution Control200111: 35-37.[陈翠柏,杨琦,尚海涛,等. 三氯乙烯耗氧生物降解的初步研究[J]. 环境污染治理技术与设备,200111:35-37.]

[71] Yang Y RMcCarty P L. Competition for hydrogen within a chlorinated solvent dehalogenating anaerobic mixed culture [J]. Environmental Science and Technology19983222:3 591-3 597.

[72] Suthersan SPayne F. In Situ Remediation Engineering [M]. Boca Raton: CRC Press2005.

[1] 黄婉彬,鄢春华,张晓楠,邱国玉. 城市化对地下水水量、水质与水热变化的影响及其对策分析[J]. 地球科学进展, 2020, 35(5): 497-512.
[2] 李云春,王显祥,赵茂俊. 纳米零价铁原位修复有机卤化物的影响因素[J]. 地球科学进展, 2013, 28(10): 1106-1118.
[3] 滕彦国,苏洁,翟远征,王金生. 地下水污染风险评价的迭置指数法研究综述[J]. 地球科学进展, 2012, 27(10): 1140-1147.
[4] 周爱国,李小倩,刘存富,周建伟,蔡鹤生,余婷婷. 氯代挥发性有机物(VOCs)氯同位素测试技术及其在地下水污染中的应用研究进展[J]. 地球科学进展, 2008, 23(4): 342-349.
[5] 吴剑锋;郑春苗. 地下水污染监测网的设计研究进展[J]. 地球科学进展, 2004, 19(3): 429-436.
阅读次数
全文


摘要