Marine Geochemistry Approaches of Rare Earth Elements in Coastal and Estuarial Areas
Received date: 2003-10-14
Revised date: 2004-04-06
Online published: 2005-01-25
Rare Earth Elements (REEs) which form a coherent group of trace elements whose chemical properties change systematically across the series (La through Lu) are generally used to understand and investigate the geochemical processes of coastal and estuarial areas, which can be employed as geochemical tracer. In this paper, the reviews of separation, preconcentration, and determination of trace rare earth elements (REEs) in estuarine water and seawater, as well as the approaches of REEs geochemical studies in coastal and estuarial areas and the interactions of REEs between water, suspended particle matter, and sediment in these areas are included. The trend of REEs geochemical research and possible investigation in coastal and estuarial areas are also suggested.
Key words： Rare Earth Elements; Coastal and estuarine areas; Geochemistry
LI Jun, GONG Zhenbin, LI Yunchun, WEN Yuyun, YANG Yiping . Marine Geochemistry Approaches of Rare Earth Elements in Coastal and Estuarial Areas[J]. Advances in Earth Science, 2005 , 20(1) : 64 -073 . DOI: 10.11867/j.issn.1001-8166.2005.01.0064
［1］Elderfield H, Greaves M J. The Rare Earth Elements in seawater [J].Nature, 1982, 296:214.
［2］Sholkovitz E R. The aquatic chemistry of Rare Earth Elements in rivers and estuaries [J]. Aquatic Geochemistry, 1995, 1: 1-34.
［3］Elderfield H, Upstill-Goddard R, Sholkovitz E R. The Rare Earth Elements in rivers, estuaries and coastal seas and their significance to the composition of ocean waters [J].Geochimica et Cosmochimica Acta, 1990, 54: 971-991.
［4］Edward Sholkovitz, Ronald Szymczak. The estuarine chemistry of Rare Earth Elements: Comparison of the Amazon, Fly, Sepik and the Gulf of Papua systems [J].Earth and Planetary Science Letters, 2000, 179: 299-309.
［5］Dia Sotto Alibo, Yoshiyuki Nozaki. Rare Earth Elements in seawater: Particle association, shale-normalization, and Ce oxidation [J].Geochimica et Cosmoschimica Acta, 1999, 63(3/4):363-372.
［6］Sholkovitz E R. The geochemistry of Rare Earth Elements in the Amazon River estuary [J].Geochimica et Cosmochimica Acta, 1993 , 57: 2 181-2 190.
［7］Bertram C J, Elderfield H. The geochemical balance of the Rare Earth Elements and neodymium isotopes in the oceans [J].Geochimica et Cosmochimica Acta, 1993, 57:1 957-1 986.
［8］Shabani M B, Akagi T, Shimizu H. Determination of trace lanthanides and yttrium in seawater by inductively coupled plasma mass spectrometry after preconcentration with solvent extraction and back-extraction [J].Analytical Chemistry, 1990, 62: 2 709-2 714.
［9］Figueiredo A M G , Moraes N M P, Shihomatsu H M. A comparison of INAA and high performance liquid chromatography for the determination of Rare Earth Elements in geological materials[J].Journal of Radioanalytical and Nuclear Chemistry, 2000, 244(3): 615-618.
［10］Jiang Zucheng, Cai Ruxiu, Zhang Huashan. Analytical Chemistry of Rare Earth Element (second edition)[M]. Beijing: Science Press, 2000.[江祖成,蔡汝秀,张华山.稀土元素分析化学（第二版）[M]北京：科学出版社，2000.]
［11］Shinotsuka K, Ebihara M. Precise determination of Rare Earth Elements, thorium and uranium in chondritic meteorites by inductively coupled plasma mass spectrometry—A comparative study with radiochemical neutron activation analysis[J].Analytica Chimica Acta,1997, 338: 237-246.
［12］Aggarwal J K, Shabani M B, Palmer M R. Determination of the Rare Earth Elements in aqueous samples at sub-ppt levels by inductively coupled plasma mass spectrometry and flow injection ICPMS[J].Analytical Chemistry, 1996, 68: 4 418-4 423.
［13］Li Yunchun, Gong Zhenbin, Li Jun, et al. Determination of Rare Earth Elements in Estuarine Water by inductively coupled plasma mass spectrometry with pre-concentration of In(OH)3 Co-precipitation[J].Acta Oceanolohica Sinica, 2005,24(1):1-6.[李云春,弓振斌,李俊，等.河口水体中痕量稀土元素的共沉淀预富集—电感耦合等离子体质谱法测定研究[J].海洋学报, 2005,24(1):1-6.]
［14］Piepgras D G, Wasserburg G J, Dasch E J. The isotopic composition of Nd in different ocean masses[J].Earthand Planetary Science Letters, 1979, 45(2): 223.
［15］Shabani M B, Akagi T, Shimizu H, et al. Determination of trace Lanthanides and Yttrium in seawater by Inductively Coupled Plasma Mass Spectrometry after preconcentration with solvent extraction and back-extraction [J].Analytical Chemistry, 1990, 62: 2 709-2 714.
［16］Shabani M B, Akagi T, Masuda A. Preconcentration of Rare Earth Elements in seawater by complexation with bis(2-ethylhexyl) hydrogen phosphate and 2-ethylhexyl dihydrogen phosphate adsorbed on a C18 cartridge and determination by inductively coupled plasma mass spectrometry[J].Analytical Chemistry, 1992, 64(5): 737-743.
［17］Moller P, Dulski P, Luck J. Determination of Rare Earth Elements in seawater by inductively coupled plasma-mass spectrometry [J].Spectrochimica Acta,1992, 47(12): 1 379-1 387.
［18］Zhang T H, Shan X Q, Liu R X, et al. Preconcentration of Rare Earth Elements in seawater with poly (acrylaminophosphonic dithiocarbamate) chelating fiber prior to determination by inductively coupled plasma-mass spectrometry [J].Analytical Chemistry, 1998, 70(18): 3 964-3 968.
［19］Peng Chunlin. Determination of single Rare Earth Element in Rare-Earth Impurities[J].Chinese Journal of Analytical Chemistry, 1992, 20(11): 1 242-1 246.[彭春霖.混合稀土中单一稀土元素的化学分析[J].分析化学, 1992, 20(11): 1 242-1 246.]
［20］Zhang Haizheng, Yan Xin, Chen Zongtuan, et al. Determination of Ultra-trace REE in Sea water by ICP-MS with extractive chromatographic separation and preconcentration[J].Rock and Mineral Analysis, 1997,(16):201-205.[张海政,阎欣,陈宗团，等.萃取色谱富集—等离子体质谱测定海水中的超痕量稀土[J].岩矿测试, 1997,(16):201-205.]
［21］Song Jinru, Gong Zhixiang, Yu Kaichun. Study and application of the characteristics of adsorption Rare Earth Elements with P507 Latex Resin [J].Journal of East China Geological Institute, 2000, 23(4): 351-355.[宋金如,龚治湘,余锴纯.P507萃淋树脂吸附稀土的性能研究和应用[J].华东地质学院学报, 2000, 23(4): 351-355.]
［22］Willie S N, Sturgeon R E. Determination of transition and Rare Earth Elements in seawater by flow injection inductively coupled plasma time-of-flight mass spectrometry [J].Spectrochimica Acta, 2001, 56B:1 707-1 716.
［23］Hiraide M, Ito T, Baba M, et al. Multielement preconcentration of trace heavy metals in water by coprecipitation and flotation with indium hydroxide for inductively coupled plasma- atomic emission spectrometry [J].Analytical Chemistry, 1980, 52: 804-807.
［24］Li Yunchun. Study on the Analytical Method and Geochemistry of Rare Earth Elements in Yangtze estuary [D]. Xiamen: Xiamen University, 2003.[李云春.长江口稀土元素分析化学和地球化学研究[硕士论文D].厦门：厦门大学海洋系，2003.]
［25］Murty D S R, Chakrapani G. Preconcentration of Rare Earth Elements on activated carbon and its application to groundwater and sea-water analysis[J].Journal of Analytical Atomic Spectrometry, 1996, 11: 815-820.
［26］Millero F J. Thermodynamics of the carbon dioxide system in the oceans [J].Geochimca et Cosmochimica Acta, 1995, 59(4): 661-667.
［27］Wang Zhongwu, Qiu Yuzhou. The Re-Fractionation and activation of Rare Earth Elements in water during hypergene processes [J].Advances in Earth Science,1996, 11(4): 378-382.[王仲武,裘愉卓.表生过程中水的稀土元素行为及其再分配[J].地球科学进展,1996, 11(4): 378-382.]
［28］Byrne R H, Lee J H, Bingler L S. Rare Earth Element complexation by PO3-4 ions in aqueous solution[J].Geochimca et Cosmochimica Acta, 1991, 55: 2 729-2 735.
［29］Johannesson, Kevin H, Lyons W Berry. Rare Earth Element geochemistry of Colour Lake, an acidic freshwater lake on Axel Heiberg Island, Northwest Territories, Canada [J].Chemical Geology, 1995, 119: 209-223.
［30］Koeppenkastrop D, De Carlo E H. Uptake of Rare Earth Elements from solution by metal oxides [J].Environmential Science Technology, 1993, 27: 1 796-1 802.
［31］Tessier A, Campbell P G C, Bisson M. Sequential extraction procedure for the speciation of particulate trace metals [J].Analytical Chemistry, 1979, 51(7):844-851.
［32］Lydia L, Jean-Luc P, Pedro D, et al. REE distribution pattern in river sediments: Partitioning into residual and labile fractions [J].Earth and Planetary Sciences Letters, 1999, 329:45-52.
［33］Wang Zhongliang, Liu Congqiang, Xu Zhifang, et al. Advances in research on geochemistry of Rare Earth Elements in rivers[J].Advances in Earth Science, 2000, 15(5): 553-558.[王中良,刘丛强,徐志方，等.河流稀土元素地球化学进展[J].地球科学进展, 2000, 15(5): 553-558.]
［34］Johan Ingri, Anders Widerlund, Magnus Land, et al. Temporal variations in the fractionation of the Rare Earth Elements in a Boreal River: The role of colloidal particles[J].Chemical Geology, 2000, 166: 23-45.
［35］Nozaki Y, Lerche D, Alibo D S, et al. Dissolved rare earths and indium in three rivers and Tokyo Bay: Evidence for anthropogenic Gd and In[J].Geochimica et Cosmochimica Acta, 2000, 64(23):3 975-3 982.
［36］Nozaki Y, Lerche D, Alibo D S, et al. The estuarine geochemistry of Rare Earth Elements and indium in Chao Phraya River, Thailand[J].Geochimica et Cosmochimica Acta, 2000, 64(23):3 983-3 994.
［37］Nozaki Y, Alibo D S, Amakawa H, et al. Dissolved Rare Earth Elements and hydrography in the Sulu Sea[J].Geochimica et Cosmochimica Acta, 1999, 63(15):2 171-2 181.
［38］Sholkovitz E R, William M Landing, Brent L Lewis. Ocean particle chemistry: The fractionation of Rare Earth Elements between suspended particles and seawater[J].Geochimica et Cosmochimica Acta, 1994, 58(6): 1 567-1 579.
［39］MacRae N D, Nesbitt H W, Kronberg B I. Development of a positive Eu anomaly during diagenesis[J].Earth and Planetary Science Letters, 1992, 109: 585-591.
［40］Sholkovitz E R. Rare Earth Element in the sediments of the North Atlantic Ocean, Amazon delta, and East China Sea: Reinterpretation of terrigenous input patterns to the oceans[J].American Journal of Science, 1988, 288: 236-281.
［41］B Nagender Nath, M Bau, Ramalingeswara Bao B, et al. Trace and Rare Earth Elemental variation in Arabian Sea sediments through the transect across the oxygen minimum zone[J].Geochimica et Cosmochimica Acta, 1997, 61(12):2 375-2 388.
［42］Luo Y R, Byrne R H. Carbonate complexation of yttrium and the Rare Earth Elements in natural water[J].Geochimica et Cosmochimica Acta, 2004, 68(4): 691-699.
［43］Shaojun Z,Alfonso M. Partitioning of Rare Earth Elements (REEs) between calcite and seawater solution at 25oC and 1 atm, and high dissolved REE concentrations[J].Geochimica et Cosmochimica Acta，1995, 59(3): 443-453
［44］Atsuyuki O, Iwao K. REE (Ⅲ) adsorption on Mn dioxide (δ-MnO2) and Fe oxyhydroxide: Ce(Ⅲ) oxidation by δ-MnO2[J].Geochimica et Cosmochimica Acta，2001, 65(5): 695-703.
［45］Martin J M, Hogdahl O, Phillpott J C. Rare Earth Element supply to the ocean[J].Journal of Geophysical Research, 1976, 81: 3 119-3 124.
［46］Moore W S. Large groundwater inputs to coastal waters revealed by 226Ra enrichments[J].Nature, 1996 , 382: 612-614.
/
| 〈 |
|
〉 |
甘公网安备62010202000687
