BORON AND CHLORINE ISOTOPIC DETERMINATIONS AND APPLICATIONS FOR EARTH SCIENCES
Received date: 1998-03-23
Revised date: 1998-06-29
Online published: 1998-12-01
Boron has two stable isotopes (11B and 10B), chlorine also has two stable isotopes (37Cl and 35Cl). The large different in mass ( 11 and 10, 35 and 37) make both boron and chlorine exist big isotopic fractionation in the nature. Variations of boron and chlorine isotopic compositions had not been found in early investigations due to poor precision of determing boron and chlorine. Since 1980s, with some high precise methods of determing boron and chlorine isotopes, the variations of boron and chlorine isotopes in nature have been evidenced by high precise determination and a lot of investigations. δ11B range from -30‰ to 60‰, and δ37Cl range from -2‰ to 7‰.
Many significant work about boron and chlorine isotopic geochemistry have been maken in oceans, salt lakes, groundwater, evaporated sediment and hydrothermal fluids. This paper give a brief summary of including analytical methods and application in Earth sciences.
Key words： B and Cl isotopes; Methods of determination; Geochemistry.
Liu Weiguo，Peng Zicheng，Xiao Yingkai . BORON AND CHLORINE ISOTOPIC DETERMINATIONS AND APPLICATIONS FOR EARTH SCIENCES[J]. Advances in Earth Science, 1998 , 13(6) : 547 -554 . DOI: 10.11867/j.issn.1001-8166.1998.06.0547
[1] Ramakumer K L, Parab A R, Khodade P S. Determination of isotopic composition of boron. J Radioanal Nucl Chem Lett, 1985, 94: 53-62.
[2] Spivack A J, Edmond J M. Determination of boron isotope ratios by thermalionization mass spectrometry of the dicesium metaborate cation. Analyt Chem, 1986, 58: 31- 35.
[3] Xiao Y K, Beary E S, Fassett J D. An improved method for the high-precision isotopic measurement of boron by thermal ionization mass spectrometry. Int J Mass Spectrom Ion Processes, 1988, 5: 203- 213.
[4] Aggarwal J K, Palmer M R. Boron isotope analysis a review. Analyst, 1995, 120:1 301-1 307.
[5] Vengosh A, Chivas A R, McCullonch M t. Direct determination of boron and chlorine isotopes in geological materials by negative thermal-ionization mass spectrometry. Chem Geol, 1989, 79: 333-343.
[6] Kaufmann R S, Long A, Bentley H, et al. Natural chlorine isotope variations. Nature, 1984, 309: 338-340.
[7] Xiao Y K, Zhang C G. High precision isotopic measurement of chlorine by thermal ionization mass spectrometry of Cs2Cl+ ion. Int J Mass Spectrom Ion Processes, 1992, 116: 183- 192.
[8] Xiao Y K, Zhou Y M, Liu W G. Precise measurement of chlorine isotopes based Cs2Cl+ by thermal ionization mass spectrometry. Analytical Letters, 1995, 28: 1 295-1 300.
[9] Kakihana H, Kotaka M, Satoh S, et al. Fundamental studies on the ion-exchange separation of boron isotopes . Bull Chem Soc Japan, 1977, 50: 158-163.
[10] Palmer M R, Spivack A J, Edmond J M. Temperat ure and pH controls over isotopic fractionation during adsorption of boron on marine clay. Geochim Cosmochim Acta, 1987, 51: 2 319-2 323.
[11] Palmer M R, London D, Morgan G B, et al. Experimental determination of fractionation of 11B/10B between tourmaline and aqueous vapor: A temperature and pressure-dependent isotopic system. Chem Geol, 1992, 101: 123-129.
[12] Spivack A J, Palmer M R, Edmond J M. The sedimentary cycle of the boron isotope. Geochim. Cosmochim Acta, 1987, 51: 1 939-1 949.
[13] Xiao Y K, Sun D P, Wang Y H, et al. Boron isotopic compositions of brine, sediments, and source water in Da Qaidam Lake, Qinghai, China. Geochim Cosmochim Acta, 1992, 56: 1561.
[14] Vengosh A, Chivas A R, McCullonch Mt, et al. Boron isotopic geochemistry of Australian salt lakes. Geochim Cosmochim Acta,1991, 55: 2 591-2 606.
[15] Philips F M, Bentley H W. Isotopic fractionation during ion filtration: 1. theory. Geochim Cosmochim Acta, 1987, 1087, 51: 683-695.
[16] 肖应凯, 金琳, 刘卫国, 等. 大柴达木湖的氯同位素组成. 科学通报, 1994, 39(41): 1 319- 1 322.
[17] 刘卫国, 肖应凯, 孙大鹏, 等. 柴达木盆地盐湖氯同位素组成的初步研究. 科学通报, 1994, 39(20): 1 918-1 919.
[18] Kakihana H, Ossaka T, Qi T, et al. Boron isotopic ratios of some hot spring water in the Kausatsu-shirane area.Geochemistry Journal,1987,21:133-137.
[19] 肖应凯, Shirodkar P V , 刘卫国, 等. 柴达木盆地盐湖的硼同位素组成及硼同位素效 应的研究. 幔壳演化与成岩成矿同位素地球化学. 地震出版社, 1993. 232.
[20] Vengosh A, Heumann K G, Juraskes, et al. Boron isotope application for tracining source of contamination in groundwater. Env Sci Tech,1994,28:1 968.
[21] Kaufmann R S, Frape S K, McMutt R, et al. Chlorine stable isotopic distribution of Michigan Basin formation waters. Applied Geochemistry, 1993, 8: 403-407.
[22] Desaulniers D E, Kaufmann R S, Cherry J A, et al. 37Cl-35Cl variations in a diffusion controlled groundwater system. Geochim Cosmochim Acta,1986,31:1 757- 1 764.
[23] 肖应凯, 刘卫国, 周引民, 等. 盐卤水和盐类矿物的氯同位素组成. 科学通报, 1996, 41: 2 067.
[24] Liu W G, Xiao Y K, Sun D P, et al. Chlorine isotopic geochemistry of salt lakes in the Qaidam Basin, China. Chemical Geology,1997, 136: 271-279.
[25] Hershey J P, Fernandez M , Milne J, et al . The ioization of boric acid in Na- Cl , Na- Ca- Cl and Na- Mg- Cl solutions at 25
e.Geochim Coschim Acta, 1986, 50: 143- 148.
[26] V engosh A, Kolodny Y, Starinsky A, et al. Coprecipitation and isotopic fractionation of boron in modern biogenic carbonates. Geochim Cosmochim Acta, 1991, 55: 2 901-2 910.
[27] Heming N G, Hamson G N. Boron isotopic composition and concnetration in modern marine carbonates. Geochim Cosmochim Acta,1992, 56: 537-543.
[28] Sanyal A, Hemming N G, Hanson G N, et al. Evidence for a higher pH in the glacial ocean from boron isotopes in forarminifera. Nature, 1995, 373:234-236.
[29] Volpe C, Spivack A. Stable chlorine isotopic composition of marine aerosol particles in the westen Atlantic Ocean. Geophysical Research Letter, 1994, 21: 1 161-1 164.
[30] Spivack A J, Edmond J M. Boron isotope exchange between seawater and the oceanic crust. Geochim Cosmochim Acta, 1987, 51: 1 033-1 043.
[31] Campbell A C, Palmer M R, Klinkhammer G P. Chemistry of hot springs on the Mid-Atlantic Ridge. Nature, 1988, 335: 514-519.
[32] Palmer M R. Boron isotope systematics of Halmahera arc(indonesia) lavas: Evidence for involvement of the subducted slab. Geology, 1991, 19: 215-217.
[33] Palmer M R, Swihart G H. Boron isotope geochemistry : an overview. Rev Mineral, 1996, 33.
[34] You C F, Spivack A J, Smith J H. Mobilization of boron in convergent margins: Implications for the boron geochemical cycle. Geology,1993,21:207-210.
[35] Musashi M, Ossaka T, Qi T, et al. Nature brone isotope fractionation between hot spring water and rock in direct contact. Isotopen-raxis, 1991, 27: 163-166.
[36] Palmer M R, Slack J F. Boron isotopic composition of tourmaline from massive sulfide deposits and tourmalinites. Contrib Mineral Petrol, 1989, 103: 434-451.
[37] Palmer M R. Boron isotope systematics of hydrothermal fluids and tourmaline: A synthesis. Chem Geol, 1992, 94: 111-121.
[38] Swihart G H, Moore P B. A reconnaissance of the boron isotopic composition of tourmaline. Geochemi Cosmochim Acta, 1989, 53: 911-916.
[39] Magenheim A J, Spivack A J, Michael P J, et al. Chlorine stable isotope composition of the oceanic crust: Implication for Earth' distribution of chlorine. Earth and Planetary Science Letters, 1995, 131: 427- 432.
[40] Swihart G H, Moore P B. Boron isotopic composition of marine and non-marine evaporite borates. Geochim Cosmochim Acta, 1987,50: 1 297-1 301.
[41] 孙大鹏, 肖应凯, 王蕴慧, 等. 青海湖硼同位素地球化学初步研究. 科学通报, 1993, 38(9): 822- 825.
[42] 祁海平, 王蕴慧, 肖应凯, 等. 中国盐湖硼同位素的初步研究. 科学通报, 1993, 38(7), 634- 637.
[43] Eggenkamp H G M, Kreulen R. Chlorine stable isotopie fractionation in evaporites. Geochim Cosmochimi Acta, 1995, 59(24): 5 169- 5 175.
[44] Xiao Y K, Liu W G , Zhou Y M. The variations of isotopic composition of chlorine in the nature 38th IU PAC General Assembly. Guildford, UK , 1995.
[45] 刘卫国, 肖应凯, 孙大鹏, 等. 马海盐湖区卤水和盐类矿物的氯同位素特征及意义. 盐湖研究, 1995, 3(2) .
[46] Spivack A J, You C F, Smith H J. Foraminiferal boron isotope ratios as a proxy for surface ocean pH over the past 21-Myr. Nature,1993, 363: 149-151.
[47] Eastoe C J, Guilbert J M, Kaufmann R S. Preliminary evidence for fractionation of stable chlorine isotopes in ore-forming systems.Geology, 1989, 17: 285- 288.
/
| 〈 |
|
〉 |
甘公网安备62010202000687
