Articles

ILLITE FUNDAMENTAL PARTICLE AND ITS SIGNIFICANCES

Expand
  • 1. Faculty of Geosciences,China University of Geosciences,Wuhan  430074,China;2. Nanjing Institute of Geology and Mineral Resources,Nanjing  210016,China

Received date: 2002-01-14

  Revised date: 2002-05-24

  Online published: 2002-10-01

Abstract

The fundamental particle is the very fine clay particle composed of single crystal,and is the basic unit of mixed-layer clays formed by one or several kinds of silicates with the sheet structure. Most of illite fundamental particle were found to occur as “building blocks” of mixed-layer crystals(MacEwan crystallites). Between the “blocks”, the adjacent edges were joined with bonded blocks in a, b direction, and the adjacent surface interfaces are joined with blocks of longer bond in c direction. The recent achievements for illite fundamental particle including the formation mechanisms, the shape variations in the formation process, and the diagenetic stages division were also summarized in the paper. There are three stages in the formation process of illite fundamental particle:①the nucleation stage of 2-nm thick illite particle at the incipient process of montmorillonite illitization; ② the simultaneous nucleation and growth stage  and ③ the surface-controlled growth stage. Illite fundamental particles showed platy to lath shapes. Platy particles exhibited various spiral growth patterns, i.e. circular, malformed circular, polygonal single unit-cell layer spirals, polygonal parallel step spiral, interlaced spiral patterns, etc. The crystal thickness distribution of illite fundamental particle submit to the lognormal-type distribution which maximum value is 10.5nm. Because the major contents and methods of fundamental particle are basic similar to  those in the nanoscience and technology, it is suggested that the relationship between illite fundamental particle and the nano-clay mineralogy be regarded together in future.

Cite this article

YANG Xian-zhong . ILLITE FUNDAMENTAL PARTICLE AND ITS SIGNIFICANCES[J]. Advances in Earth Science, 2002 , 17(5) : 659 -663 . DOI: 10.11867/j.issn.1001-8166.2002.05.0659

References

[1]Nadeau P H,Wilson M J,McHardy W J,et al.Interstratified clay as fundamental particle[J]. Science,1984,225:923-935.
[2]Zhang Shengyang. A new concept in clay mineralogy—Fundamental particle and interparticle diffraction[J]. Geology-Geochemistry,1988,2:26-28. [张胜扬. 粘土矿物学中的新概念——单元粒子和粒间衍射现象[J]. 地质地球化学,1988,2:26-28.]
[3]Srodon V,Andreoli C,Elsass F,et al. Direct high-resolution transmition electron microscopic measurement of expandability of mixed-layer illite/smectite in bentonite rock[J]. Clays and Clay Minerals,1990,34:368-378.
[4]Reynolds R C,Jr. X-ray diffraction studies of illite/smectite from rocks,<1μm randomly oriented powders,and <1μm oriented powder aggregates: The absence of laboratory induced artifacts[J]. Clays and Clay Minerals,1992,40:387-396.
[5]Srodon J,Eberl D D,Drits V A. Evolution of fundamental-particle size during illitization of smectite and implications for reaction mechanism[J]. Clays and Clay Minerals,2000,48:446-458.
[6]Nadeau P H,Wilson M J,McHardy W J,et al. Interparticle diffraction:A new concept for interstratified clays[J]. Clay Minerals,1984,19:757-759.
[7]Drits V A,Eberl D D,Srodon J. XRD measurement of mean illite crystallite thickness:Reappraisal of the Kübler index and Scherrer equation[J]. Clays and Clay Minerals,1997,45:461-475.
[8]Scherrer P. Bestimmung der grosse und inneren Struktur von Kolloidteilchen mittels Rontgenstrahlen[J]. Nachrichten Gesellschaft Wissenschaft Gottingen,1918,26:98-100.
[9]Kübler B. les argiles indicateurs de metamorphisme[J]. Revue Institut Francais du Petrole,1964,XIX(10):1 093-1 113.
[10]Arkai P,Merriman R J,Roberts B,et al. Cryatsllinity,crystallite size and lattice strain of illite-muscovite and chlorite:Comparison of XRD and TEM data for diagenetic to epizonal pelites[J]. European Journal of Mineralogy,1996,8:1 119-1 137.
[11]Srodon J,Eberl D D. Illite[A]. In:Bailey S W, eds. Mica[C]. Chelsea,Michigan: Mineralogical Society of American,1984. 495-544.
[12]Srodon J. Precise identification of illite/smectite interstratification by X-ray powden diffration[J]. Clays and Clay Minerals,1980,28:401-411.
[13]Srodon J,Elsass F. Effect of the shape of fundamental particles on XRD characteristics of illitic minerals[J]. European Journal of Mineralogy,1994,6:113-122.
[14]Drits V A,Eberl D D,Srodon J. XRD measurement of mean thickness,thickness distribution and strain for illite and illite/smectite crystallites by the Bertaut-Warren-Averbach technique[J]. Clays and Clay Minerals,1998,46:461-475.
[15]Eberl D D,Nuesch R,Sucha V,et al.Measurement of fundamental illite particle thicknesses by X-ray diffraction using PVP-10 intercalation[J]. Clays and Clay Minerals,1998,46:89-97.
[16]Jaboyedoff M,Bussy F,Kübler B,et al. Illite “crystallinity” revisited[J]. Clays and Clay Minerals,2001,49:156-167.
[17]Altaner S P,Ylagan R F. Comparison of structural models of mixed-layer illite-smectite and reaction mechanisms of smectite illitization[J]. Clays and Clay Minerals,1997,45:517-533.
[18]Barronnet A. Polytypism and stacking disorder[A]. In:Buseck P R, ed. Minerals and Reactions at the Atomic Scale:Transmission Electron Microscopy[C]. Chelsea,Michigan: Mineralogical Society of American,1992. 231-288.
[19]Lanson B,Velde B,Meunier A. Late-stage diagenesis of illitic clay minerals as seen by decomposition of X-ray diffraction patterns:contrasted behaviors of sedimentary basins with different burial histories[J]. Clays and Clay Minerals,1998,46:69-78.
[20]Rajec P,Sucha V,Eberl D D,et al. Effect of illite particle shape on cesium sorption[J]. Clays and Clay Minerals,1999,47:755-760.
[21]Ylagan R F,Altaner S P,Pozzuoli A. Reaction mechanisms of smectite illitization associated with hydrothermal alteration from Ponza Island,Italy[J]. Clays and Clay Minerals,2000,48:610-631.
[22]Kuwahara Y,Uehara S,Aoki Y. Atomic force microscopy study of hydrothermal illite in Izumiyama Pottery stone from Arita,Saya Prefeture,Japan[J]. Clays and Clay Minerals,2001,49:300-309.

Options
Outlines

/