Advances in Earth Science ›› 2019, Vol. 34 ›› Issue (2): 124-139. doi: 10.11867/j.issn.1001-8166.2019.02.0124

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Review of the Study on the Stable Isotopes of Nitrogen and Oxygen in Atmospheric Nitrate

Rui Qin( ),Guitao Shi *( ),Zhenlou Chen   

  1. 1. Key Laboratory of Geographic Information Science Ministry of Education, School of Geographic Sciences, East China Normal University, Shanghai 200241, China
  • Received:2018-08-23 Revised:2018-12-20 Online:2019-02-10 Published:2019-03-26
  • Contact: Guitao Shi E-mail:843128305@qq.com;gtshi@geo.ecnu.edu.cn
  • About author:Qin Rui(1991-), female, Lankao City, Henan Province, Master student. Research areas include stable isotope in environment. E-mail:843128305@qq.com|Shi Guitao (1982-), male, Zaozhuang City, Shandong Province, Professor. Research areas include polar environment. E-mail: gtshi@geo.ecnu.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China “Investigating mechanisms of post-depositional processing of nitrate in the snowpack on the traverse from coastal Zhongshan station to inland Kunlun station, East Antarctica: Evidence of δ15N, δ18O and Δ17O”(No. 41576190);Project supported by the National Natural Science Foundation of China “Investigating mechanisms of post-depositional processing of nitrate in the snowpack on the traverse from coastal Zhongshan station to inland Kunlun station, East Antarctica: Evidence of δ15N, δ18O and Δ17O” (No. 41576190).

Rui Qin,Guitao Shi,Zhenlou Chen. Review of the Study on the Stable Isotopes of Nitrogen and Oxygen in Atmospheric Nitrate[J]. Advances in Earth Science, 2019, 34(2): 124-139.

Due to the emissions from intensive human activities and rapid development of industry and agriculture, atmospheric nitrate (NO 3 - ) contamination is becoming more serious and now is a worldwide environmental problem. The isotopic compositions of NO 3 - 15N, δ18O and Δ17O) can deliver more information than the concentration alone, i.e., the nitrogen and oxygen isotopes can suggest the sources of NO 3 - and oxidation capability of the atmosphere, providing a powerful tool for investigating atmospheric nitrogen cycling and atmospheric NO 3 - pollution control. The δ15N of different sourced NO 3 - in the atmosphere, as well as the seasonal variation of δ15N (NO 3 - ) and the associated mechanisms were reviewed. In addition, the oxygen isotopes of various oxidants and NO 3 - 18O and Δ17O) in the atmosphere were summarized, and the global distribution patterns of the oxygen isotopes of NO 3 - were discussed. Lastly, the available analysis techniques of isotopic compositions of NO 3 - were reviewed. Based on the research progress of NO 3 - isotopes in the atmosphere, it was suggested that further investigations should focus on measuring the isotopic compositions of oxidants and NOx from different sources, characterizing the production mechanisms of NO 3 - , as well as investigating chemical recycling between NOx and NO 3 - with the aid of atmospheric chemical models.

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