Please wait a minute...
img img
高级检索
地球科学进展  2013, Vol. 28 Issue (1): 24-30    DOI: 10.11867/j.issn.1001-8166.2013.01.0024
综述与评述     
石英ESR测年信号衰退特征研究进展
刘春茹1,尹功明1,  Rainer Grün2
1.中国地震局地质研究所地震动力学国家重点实验室,北京100029;
2.Research School of Earth Sciences, The Australian National University, Canberra, ACT 0200, Australia
Research Progress of the Resetting Features of Quartz ESR Signal
Liu Chunru1, Yin Gongming1, Rainer Grün2
1.State Key Laboratory of Earthquake Dynamics, Institute of Geology, China Earthquake Administration,Beijing100029, China; 2. Research School of Earth Sciences, The Australian National University, Canberra, ACT 0200, Australia
 全文: PDF(1060 KB)  
摘要:

电子自旋共振 (ESR)测年法是第四纪地质年代学的重要测试方法之一,其测年范围广,特别是对于20万年至百万年尺度的第四纪样品有着重要意义。准确测量古剂量是影响ESR测年法精度和可信度的重要因素之一,而掌握ESR信号衰退特征及机制是获得准确、可信古剂量的重要前提。ESR测年法适用的地质样品种类较多,如热液石英脉、地质断层泥、水系沉积物等,不同样品的ESR信号衰退特征和机制有较大差异。近年来,国内外学者针对不同地质样品中石英ESR信号的衰退特征和机制深入开展了一系列的实验室模拟和野外观测研究,取得了诸多新认识。回顾了近年来在石英ESR信号衰退特征领域取得的进展,特别是水系沉积物石英ESR信号的衰退特征,并展望了这一领域的未来工作重点。

关键词: ESR测年法水系沉积物石英信号衰退    
Abstract:

 Electron Spin Resonance (ESR) has been becoming one of the key methods of Quaternary Geochronology with wide range of dating, especially for sample older than 200,000 years up to millionyear scale. ESR dating assesses the age of a sample by measuring the equivalent dose and annual dose. The accurate measurement of equivalent dose significantly impacts on accuracy and reliability of ESR dating method. Under ideal conditions, any previous acquired ESR intensity is reset to zero or a stable residual level that can be determined in the laboratory. Therefore, the study of the mechanisms of resetting processes is fundamental for accurate and reliable ESR dating. Since ESR dating method is applicable to the type of geological samples, including hydrothermal quartz veins, geological fault gouge and fluvial sediment, there are large differences in the mechanisms and characteristics of ESR signal resetting. In recent years, to understand the mechanism and characteristics of quartz ESR signal resetting of different geological samples, a series of laboratory simulation and field observation studies were carried out, which made lots of important breakthrough. In this paper, we summarize progress in ESR dating of quartz in Quaternary sediments and studies of resetting mechanisms with particular emphasis on fluvial sediments and prospects for future work.

Key words: ESR dating method    Fluvial sediment    Quartz    ESR signal resetting
收稿日期: 2012-07-31 出版日期: 2013-01-10
:  P597  
基金资助:

中央级公益性科研院所基本科研业务费专项“河流机械作用对石英ESR信号衰退特征的研究”(编号:IGCEA1216);地震动力学国家重点实验室自主研究课题“汶川地震断层泥ESR和释光测年信号特征研究”(编号:LED2009A04);国家自然科学基金项目“第四纪河湖相沉积物石英ESR年代学研究——以泥河湾盆地为例”(编号:40902051)资助.

通讯作者: 刘春茹(1980-),女,吉林通化人,副研究员,主要从事新构造与第四纪年代学研究.     E-mail: liuchunru0821@126.com
作者简介: 刘春茹(1980-),女,吉林通化人,副研究员,主要从事新构造与第四纪年代学研究.E-mail:liuchunru0821@126.com
服务  
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章  
刘春茹
尹功明
Rainer Grün

引用本文:

刘春茹,尹功明,Rainer Grün. 石英ESR测年信号衰退特征研究进展[J]. 地球科学进展, 2013, 28(1): 24-30.

Liu Chunru, Yin Gongming, Rainer Grün. Research Progress of the Resetting Features of Quartz ESR Signal. Advances in Earth Science, 2013, 28(1): 24-30.

链接本文:

http://www.adearth.ac.cn/CN/10.11867/j.issn.1001-8166.2013.01.0024        http://www.adearth.ac.cn/CN/Y2013/V28/I1/24

[1]Su Zhen, Shi Yafeng, Zheng Benxing. Quaternary glacial remains on the Gongga Mountain and the division of glacial period[J].Advances in Earth Science, 2002, 17(5):639-647.[苏珍, 施雅风, 郑本兴. 贡嘎山第四纪冰川遗迹及冰期划分[J]. 地球科学进展, 2002,17(5):639-647.]

[2]Yang Kunguang, Liang Xingzhong, Xie Jianlei, et al. ESR dating, the principle and application of a method to determine active ages of brittle faults[J]. Advances in Earth Science, 2006, 21(4):430-435.[杨坤光,梁兴中,谢建磊,等. ESR定年: 一种确定脆性断层活动年龄的方法原理与应用[J]. 地球科学进展, 2006, 21(4):430-435.]

[3]Zhu Zhaoyu, Wu Yi, Qiu Shifan, et al. The problems of stratigraphy and chronology of like-vermicular red earth formed in the quaternary along the coast of South China[J]. Advances in Earth Science, 2010, 25(4):391-399.[朱照宇, 吴翼, 邱世藩, 等.华南沿海第四纪类网纹红土的赋存层位及其年代问题[J]. 地球科学进展, 2010, 25(4):391-399.]

[4]Grün R. Electron spin resonance dating[C]∥Luminescence Dating/Electron Spin Resonance Vating. Elsevier B. V.,2007:1 505-1 516.

[5]Grün R. Electron Spin Resonance (ESR) dating[J]. Quaternary International, 1989, 1: 65-109.

[6]Grün R. Remarks on ESR dating of fault movements[J]. Journal of the Geological Society of London, 1992, 149: 261-264.

[7]Ikeya M. Dating a stalactite by electron paramagnetic resonance[J]. Nature, 1975, 255: 48-50.

[8]Fukuchi T, Imai N, Shimokawa K. Dating of the fault movement by various ESR signals in Quartz—Cases of the faults in the South Fossa Magna, Japan[M]∥Ikeya M,Miki T, eds. ESR Dating and Dosimetry. Tokyo: IONICS, 1985:211-217.

[9]Fukuchi T, Imai N, Shimokawa K. ESR dating of fault movement using various defect centers in quartz, the case of the western southern Fosse Magna, Japan[J]. Earth and  Planet Science Letters, 1986, 78: 121-128.

[10]Fukuchi T. Application of ESR dating using multiple centres to fault movement—The case of the Itoigava-Shizuoka tectonic line, a major fault in Japan[J]. Quarternary Science Reviews, 1988, 7:509-514.

[11]Buhay W M, Schwarcz H P, Grün R. ESR dating of fault-gouge: The effect of grain size[J]. Quaternary Science Reviews, 1988, 7: 515-522.

[12]Ariyama T. Conditions of resetting the ESR clock during faulting[M]∥Ikeya M,Miki T, eds. ESR Dating and Dosimetry. Tokyo: IONICS, 1985: 249-256.

[13]Tanaka K. Investigations on the Ages of Fault Movement by Electron Spin Resonance (ESR) Dating Method-experiments on the Zero-Setting of the Paramagnetic Defects at the Time of Faulting[R]. Central Research Institute, Electric Power Industry, Abiko Research Laboratory Report, 1987.

[14]Tanaka K. Experimental Study on the Stability of Radiation Defects in Quartz by Ring-Shearing Test[Z]. Abstract of the Annual Meeting of the Geological Society of Japan, 1989:316.

[15]Fukuchi T. ESR studies for absolute dating of fault movements[J]. Journal of the Geological Society, 1992, 149: 264-272.

[16]Ikeya M. A model of linear uranium accumulation for ESR age of heidelberg (Mauer) and Tautavel bones[J]. Japanese Journal of Applied Physics,1982, 21: L690-L692.

[17]Parenti F, Mercier N, Valladas H. The oldest hearths of Pedra Furada, Brasil: Thermoluminescence analysis of heated stones[J]. Currence Research in the  Pleistaence,1990, 7:36-38.

[18]Miallier D, Sanzelle S, Fain J, et al. Intercomparisons of red TL and ESR signals from heated quartz grains [J]. Radiation Measurement, 1994, 23:143-153.

[19]Ikeya M, Tani A, Yamanaka C. Electron spin resonance isochrone dating of fracture age: Grain-size dependence of dose rates for fault gouge [J].Japanese Journal of Applied Physics, 1995, 34:334-337.

[20]Fukuchi T. Direct ESR dating of fault gouge using clay minerals and the assessment of fault activity [J].Engineering Geology, 1996, 43:201-211.

[21]Fukuchi T, Imai N. Resetting experiment of E′ centers by natural faulting—The case of the Nojima earthquake fault in Japan[J]. Quaternary Science Reviews, 1998, 17(11): 1 063-1 068.

[22]Miki T, Ikeya M. Physical basis of fault dating with ESR[J]. Naturwissenschaften, 1982, 69:90-91.

[23]Ikeya M, Miki T, Tanaka K, et al. ESR dating of faults at Rokko and Atotsugawa[J]. PACT, 1983, 9:411-419.

[24]Ikeya M. ESR studies of geothermal boring core at Hachobara power station[J].Journal of Applied Physics, 1983, 22:763-765.

[25]Lee H K, Schwarcz E P. An experimental study of shear induced zeroing of ESR signals in quartz[J]. Applied Radiation and Isotopes, 1993, 44(1/2): 191-195.

[26]Toyoda S, Rink W J, Schwarcz H P, et al. Crushing effects on TL and OSL on quartz: Relative to fault dating[J]. Radiation Measurements, 2000, 32(5/6): 667-672.

[27]Takeuchi A, Nagahama H, Hashimoto T. Surface resetting of thermoluminescence in milled quartz grains[J]. Radiation Measurements, 2006, 41(7/8): 826-830.

[28]Takeuchi A, Hashimoto T. Milling-induced rest of thermoluminescence and deformation of hydroxyl species in the near-surface layer of quartz grains[J]. Geochronometria, 2008, 32: 61-68.

[29]Zhao Xingtian, Gao Hong, Li Desheng, et al. Effect of light irradiation on E′ center ESR signal measurement of quartz samples[J]. Nuclear Techniques,1991,14(2): 87-89.[赵兴田, 高红, 李德生, 等. 石英E′心ESR光效应研究[J]. 核技术, 1991, 14(2): 87-89.]

[30]Jin Sizhao, Deng Zhong, Huang Peihua. The light effect research of loess quartz E′ center[J]. Chinese Science Bulletin,1991, 36(10):741-744.[金嗣炤, 邓中, 黄培华. 黄土石英E′中心光效应研究[J]. 科学通报, 1991, 36(10): 741-744.]

[31]Toyoda S, Ikeya M. Thermal stabilities of paramagnetic defect and impurity centers in quartz: Basis for ESR dating of thermal history[J].Geochemical Journal, 1991, 25:437-445.

[32]Nie G Z. Zeroing mechanisms of loess quartz in ESR dating[J]. Scientia Geological Sinica, 1992, 1(3/4): 217-224.

[33]Falguères C, Miallier D, Sanzelle S. Potential use of the E′ center as an indicator of initial resetting in TL/ESR of volcanic materials[J]. Quaternary Geochronology (Quatneray Science Reviews), 1994, 13: 19-623.

[34]Toyoda S, Voinchet P, Falgueres C, et al. Bleaching of ESR signals by the sunlight: A laboratory experiment for establishing the ESR dating of sediments[J]. Applied Radiation and Isotopes, 2000, 52:1 357-1 362.

[35]Tanaka K, Sawada S, Ito T. ESR dating of late Pleistocene near shore and terrace sands in southern Kanto, Japan[M]∥Ikeya M,Miki T, eds. ESR Dating and Dosimetry. Tokyo: IONICS, 1985:275-280.

[36]Ye Yuguang, He Jie, Diao Shaobo, et al. Study on ESR ages of late Pleistocene coastal aeolian sands[J]. Marine Geology & Quaternary Geology, 1993,13(3): 85-90.[业渝光, 和杰, 刁少波, 等. 晚更新世海岸风成砂ESR年龄的研究[J]. 海洋地质与第四纪地质, 1993, 13(3): 85-90.]

[37]Yokoyama Y, Falgueres C, Quaegebeur J P. ESR dating of quartz from Quaternary sediments: First attempt[J]. Nuclear Tracks, 1985,10:921-928.

[38]Voinchet P, Falgueres C, Laurent M, et al. Artifical optical bleaching of the aluminium center in quartz implications to ESR dating of sediments[J].Quaternary Science Reviews, 2003, 22:1 335-1 338.

[39]Yoshida H. Quaternary Dating Studies Using ESR Signals with Emphasis on Shell,Coral,Tooth Enamel and Quartz[D]. Canberra:Australian National University,1996.

[40]Tanaka K, Hataya R, Spooner N A, et al. Dating of marine terrace sediments by ESR, TL, and OSL methods and their applicabilities[J]. Quaternary Science Reviews, 1997, 16:257-264.

[41]Rink W J, Bartoll J, Schwarcz H, et al. Testing the reliability of ESR dating of optically exposed buried quartz sediments[J]. Radiation Measurements, 2007, 4:1 618-1 626.

[42]Gao L, Yin G M, Liu C R, et al. Natural sunlight bleaching of the ESR titanium center in quartz[J]. Radiation Measurement, 2009, 44:501-504.

[43]Shimokawa K, Imai N. Simultaneous determination of alteration and eruption ages of volcanic rocks by electron spin resonance[J]. Geochimica et Cosmochimical Acta, 1987, 51: 115-119.

[44]Rink W J. Electron Spin Resonance (ESR) dating and ESR applications in Quaternary science and archaeology[J]. Radiation Measurements, 1997, 27: 975-1 025.

[45]Rink W J, Odom A L. Natural alpha recoil partical radiation and ionizing radiation sensitivities in quartz detected with EPR: Implications for geochronometry[J].Nuclear Tracks and Radiation Measarement, 1991, 18:163-173.

[46]Walther R, Zilles D. ESR studies on bleached sedimentary quartz[J]. Quaternary Science Reviews, 1994, 13:635-639.

[47]Voinchet P, Bahain J J, Falguères C, et al. ESR dating of quartz extracted from Quaternary sediments application to fluvial terraces system of northern France[J].Quaternaire,2004, 15:135-141.

[48]Lin Min, Yin Gongming, Ding Yanqiu, et al. A preliminary study of ESR dating for aluminum centre in quartz from sediments[J]. Acta Geoscientica Sinica,2005, 26: 255-257.[林敏,尹功明,丁艳秋,等. 碎屑沉积物中石英低温Al心的ESSR测年初探[J].地球学报, 2005, 26: 255-257.]

[49]Yin G M, Lin M, Lu Y C, et al. Preliminary ESR dating results on loess samples from the loess-paleosol sequence at Luochuan, Central Loess Plateau, China[J]. Quaternary Geochronology, 2007, 2: 381-385.

[50]Yin G M, Bahain J J, Shen G J, et al. ESR/U-series study of teeth recovered from the palaeoanthropological stratum of the Dali Man site (Shanxi Province, China)[J]. Quaternary Geochronology, 2011, 6: 98-105.

[51]Liu C R, Yin G M, Gao L, et al. ESR dating of Pleistoncene archaeological localities of the Nihewan Bsain, North China-Preliminary results[J].Quaternary Geochronology, 2010, 5: 385-390.

[52]Moreno D, Falgueres C, Perez-Gonzalez A, et al. ESR chronology of alluvial deposits in the Arlanzon valley (Atapuerca, Spain): Contemporaneity with Atapuerca Gran Dolina site[J]. Quaternary Geochronology, 2012,dio:10.1016/j.quageo.04.018.

[53]Olley J M, Pietsch T, Roberts R G. Optical dating of Holocene sediments from a variety of geomorphic settings using single grains of quartz[J]. Geomorphology, 2004, 60:337-358.

[54]Liu Chunru, Yin Gongming, Gao Lu, et al. Reliability of quartz Ti-centre in ESR dating of fluvial sediment[J]. Nuclear Techniques, 2009, 32(2): 110-112.[刘春茹,尹功明,高璐,等. 水相沉积物石英Ti心ESR测年可靠性初探[J]. 核技术, 2009, 32(2): 110-112.]

[55]Tissoux H, Falguères C, Volnchet P, et al. Potential use of Ti-center in ESR dating of fluvial sediment[J]. Quaternary Geochronology, 2007,2(1/4):367-372.

[56]Tissoux H, Toyoda S, Falguères C, et al. ESR dating of sedimentary quartz from two Pleistonce deposits using Al and Ti-centres[J].Geochronometria, 2008, 30: 23-31.

[57]Voinchet P, Falguères C, Tissoux H, et al. ESR dating of fluvial quartz: Estimate of the minimal distance transport required for getting a maximum optical bleaching[J].Quaternary Geochronology,2007, 2: 363-366.

[58]Liu C R, Grün R. Fluvio-mechanical resetting of the Al and Ti centres in quartz[J]. Radiation Measurement,2011, 46:1 038-1 042.

[59]Marfunin A S. Spectroscopy, Luminescence and Radiation Centers in Minerals[M]. New York:Springer-Verlag, 1979.

[1] 张创, 罗然昊, 张恒昌, 周雪, 王成龙, 邢华, 钱成. 中等地温场、长深埋期石英砂岩类储层成岩作用与孔隙度演化模式——以鄂尔多斯盆地延安地区下石盒子组为例[J]. 地球科学进展, 2017, 32(7): 744-756.
[2] 杨宏宇, 赵晖, 王兴繁, 耿建伟. 光释光测年中石英颗粒全球标准曲线法(gSGC)与单片再生法(SAR)等效剂量(De)的比对[J]. 地球科学进展, 2017, 32(10): 1111-1118.
[3] 魏传义, 刘春茹, 李长安, 尹功明, 李文朋, 赵举兴, 张增杰, 张岱, 孙习林, 李亚伟. 石英ESR法物源示踪:认识与进展[J]. 地球科学进展, 2017, 32(10): 1062-1071.
[4] 李艳青,佘振兵,马昌前. 石英SEM-CL微结构及其在岩石学中的应用[J]. 地球科学进展, 2011, 26(3): 325-331.
[5] 陈翠华,倪师军,何彬彬,张成江. 基于GIS技术的江西德兴地区水系沉积物重金属污染的潜在生态危害研究[J]. 地球科学进展, 2008, 23(3): 312-322.
[6] 李国强,赵晖,范育新,彭海梅,陈发虎. 光释光测年中石英样品提纯方法的改进[J]. 地球科学进展, 2008, 23(3): 284-289.