BIOGEOCHEMICAL PROCESSES OF HEAVY METALS AT THE SEDIMENT-WATER INTERFACE OF ESTUARY:A REVIEW
Received date: 1996-10-15
Revised date: 1997-03-24
Online published: 1997-10-01
Various factors governing the accumulation, dispersion and form exchanges of heavy metals at sediment water interface of estuaries are discussed and reviewed. Concentrations and bioavailabilities of heavy metals in estuaries depended on many different processes, including:①mobilization of metals of the porewater and their chemical properties;②transportation of metals at sediment water interface;③sediment components;④organism activities, and⑤effect of water current washing and disturbance, bioturbulence, salinity, redox and pH on the processes. So far some conclusions have been achieved:①concentration and distribution of heavy metals in major estuaries and adjacent areas were measured;②sequential extraction procedure for the specification for heavy metals have been presented and widely applied to study on metal behaviors in water environment;③research on relationship between organism growth and content of heavy metal in organism was made by in situ measures and indoor toxic culture experiments;④lots of experiments for sorption and desorption of heavy metals on various material have been completed and presented many isotherm equations;⑤several methods for determining background values of metals have been set up. Some problems to be resolved in near future are those:①quantitative study on biogeochemical cycling model of heavy metals;②metal release from sediments would become another source of pollution and must be pay attention to;③international standard analysis for heavy metals, especially for specification determinations, should be set up.
Key words: Biogeochemical processes; Heavy metals; Sediment-water interface; Estuary.
CHEN Zongtuan, XU Li, HONG Huasheng . BIOGEOCHEMICAL PROCESSES OF HEAVY METALS AT THE SEDIMENT-WATER INTERFACE OF ESTUARY:A REVIEW[J]. Advances in Earth Science, 1997 , 12(5) : 434 -439 . DOI: 10.11867/j.issn.1001-8166.1997.05.0434
1 Gibbs R J. Transport phase of transition metals in the Amazon and Yukon river. Geology Society of American Bullion,1977,88:829-843.
2 Stumm W, Brauner P A. Chemical Speciation. In:Riley J P, Skirrow G K, eds. Chemical Oceanography, Vol.1, New York: Academic Press,1975.173-279.
3 Tessier A, Cambell P G C, Bisson M. Sequential extraction procedure for the speciation of particulate trace metal.Analysis Chemistry, 1979, 51(7):844-851.
4 陈静生,周家义.中国水环境重金属研究.北京:中国环境科学出版社, 1992. 1-387.
5 金相灿.沉积物污染化学.北京:中国环境科学出版社,1992.1-365.
6 陈宗团.湘江沉积物中重金属污染物的运移机理及沉积速率的研究.长春地质学院研究生论文集, 1985,1:24-39.
7 Modak D D . Mobile and bound forms of trace metals in sediments of the lower Ganges. Water Research, 1994, 26(11): 1541-1548.
8 Singer P C. Influence of dissolved organics on the distribution, transportation, and fate of heavy metals in aquatic system. In: Suffet I H, ed. Fate of Pollutants in the Air and Water Environment, Part 1. New York:1977.155-182.
9 Kumaqai H, Sacki K. Variation pattern of heavy metal content of short neck clam Tapes Japonica with its growth.Bull Jap Soc Fish, 1981, 47(11): 1511-1513.
10 陈水土,杨慧辉.九龙江口和厦门西港海域若干重金属元素的生物地球化学特性.台湾海峡,1993,12(4): 376-384.
11 Schumnacner M . Variations of heavy metals in water, sediment and biota from the delta of Ebro River, Spain. Journal of Env Science and Health, Part A. 1995 ,30(6):1361-1372.
12 Cline J T, Upchurch S B. Mode of heavy metal migration in the upper strata of lake sediment. Proc 16th Conf Great Lakes Research. Int Assoc Great Lakes Res, 1973.349-356.
13 Warren L A, Zimmerman A P. Suspended particulate oxides and organic matter interactions in trace metal sorption reaction in a small urban river. Biogeochmistry , 1994, 24(1): 21-34.
14 Evens D W, Cutshall N H, Cross F A, et al. Manganese cycling in the Newport River Estuary. N C Estuarine Coastal Maine Science, 1977,5: 71-80.
15 Calmano W, Hong J, Forstner U . Binding and mobilization of heavy metal in contaminated sediment affected by the pH and redox potential. Water Science and Technology , 1993, 28 (8-9) : 223-235.
16 Lu C S J, Chen K Y. Migration of trace metals in interfaces of seawater and polluted surface sediments. Environ Sci Technol,977, 11: 174-182.
17 Brugrnann L. Metals in sediment and suspended matter of the river Elbe. Science of the Total Environment, 1995,159 (1) : 53-65.
18 Bubby J M. The behavior of mercury within a contaminated tidal river system. Water Science and Technology, 1993(8-9):329-338.
19 Windom HL. Investigations of changes in heavy metal concentrations resulting from maintenance dredging of Mobile Bay ship channel. Mobile Bay, Alabama, Rep U S Armey Corps of Engineers, Mobile Distribution, 1973.46-56.
20 Basu A, Molinaroli E. Toxic metal in Venice lagoon, observation and possible removal. Environmental Geology,1994 , 24 : 203-216.
21 Presley B J, Trefry J H. Sediment-water interactions and the geochemistry of interstitial waters. In: Olausson E, Cato I, eds. Chemistry and Biogeochemistry of Estuaries. John Wiley and Sons Ltd, 1980. 187-232.
22 Berner R A. Distribution and diagenesis of sulfur in some sediments from the Gulf of California. Marine Geology,1964,(1): 117-140.
23 Gehlen M , Malschaert H, Vanraaphorst W R. Special and temporal variability of benthic silica fluxes in the southeastern North Sea. Continental Shelf Research, 1995, 15 (21) : 1675-1691.
24 Maran S, Ciaeri G, Matrinotti W. Mathematical models for estimating fluxes at the sediment-water interface in benthic chamber experiments. Hydrobiologia, 1995, 297 (1): 67-74.
25 Huang W ,Campredom R, Abrao J J, et al. Variation of heavy metals in recent sediments from Piratininga Lagoon( Brazil )-interpretation of geochemical data with the aid of multivariate analysis. Environmental Geology, 1994, 23( 4 ) : 241-247.
26 Hanson P J, Evans D W, Colby D R, et al. Assessment of elemental contamination in estuarine and coastal environment based on geochemical and statistical modeling of sediments. Marine Environmental Research, 1993, 36(4):237-266.
/
〈 |
|
〉 |