RARE EARTH ELEMENTS COMPOSITIONS OF HIGH-TEMPERATURE HYDROTHERMAL FLUIDS IN SEA FLOOR AND CONTROL FACTORS
Received date: 1999-06-21
Revised date: 1999-11-11
Online published: 2000-06-01
It is very important to study the behavior and control factors of rare earth elements in fluids for applying them to tracing of the geochemical processes. The REE compositions of the vent fluid show wide contents in concentration but similar on the REE distribution patterns among different seafloor hydrothermal system with various setting and rocks. The distribution patterns common possess high positive Eu anomalies and enriched LREE. The composition of the fluids is related to alteration and texture of rock or mineral and is controlled by environment conditions such as temperature, pressure, pH, Eh,complexing agents. The distribution patterns of high temperature fluids are the results of sorption,complexation, and mineral deposit process and the REE patterns were adjusted and redistributed during fluid circulation and migration. Some REE' s parameters such as Eu, Ce anomalies and Y/Ho ratios can be used to study processes concerning fluid. For example, the positive Eu anomalies, negative Ce anomalies and Y/Ho ratios as mark of involving high-temperature fluid and sea water may be used to trace geochemical processes concerning on mixing.
DING Zhenju, LIU Congqiang, YAO Shuzhen, ZHOU Zonggui . RARE EARTH ELEMENTS COMPOSITIONS OF HIGH-TEMPERATURE HYDROTHERMAL FLUIDS IN SEA FLOOR AND CONTROL FACTORS[J]. Advances in Earth Science, 2000 , 15(3) : 307 -312 . DOI: 10.11867/j.issn.1001-8166.2000.03.0307
〔1〕Henderson P. General geochemical properties and abundances of rare earth elements〔A〕. In: Hendersion P, ed. Rare Earth Element Geochemistry〔C〕. Amsterdam: Elsevier, 1984. 1～32.
〔2〕Fleet A J. Aqueous and sedimentary geochemistry of the rare earth elements〔A〕. In: Hendersion P, ed. Rare Earth Element Geochemistry〔C〕. Amsterdam: Elsevier, 1984. 343～373.
〔3〕Taylor S R, McLcnnan S M. The Continental Crust: Its Composition and Evolution〔M〕. Oxford: Blackwell Scientific Press, 1985.
〔4〕Guichard F, Church T M, Treuil M,et al. Rare earth in barite: distribution and effects on aqueous partitioning〔J〕.Geochimica et Cosmochimica Acta, 1979, 43(7): 983～997.
〔5〕Excey R A. Microprobe studies of REE-rich accessory minerals: implications for Skye granite petrogenesis and REE mobility in hydrothermal systems〔J〕. Earth Plant Sci Lett, 1980, 48(1): 97～110.
〔6〕Joliff B L, Papike J J, Laul J C. Mineral recorders of pegmatite internal evolution: REE contents of tourmaline from the Bob Ingersoll pegmatite, South Dakota〔J〕.Geochimica Cosmochimica Acta, 1987, 51(8): 2 225～2232.
〔7〕Fryer B J, Taylor R P. Rare-earth element distributions in uraninites: implications for ore genesis〔J〕. Chemical Geology, 1987, 63(1/2): 101～108.
〔8〕Bach W, Irber W. Rare earth element mobility in the oceanic lower sheeted dyke complex: evidence from geochemical data and leaching experiments〔J〕. Chemical Geology, 1998,151(2): 309～326.
〔9〕Bau M, Usui A, Pracejus B,et al. Geochemistry of low-temperature water-rock interaction: evidence from nature waters, andesite, and iron-oxyhydroxide precipitates at Nishiki-numa iron-spring, Hokkaaido, Japan〔J〕. Chemical Geology, 1998, 151(1): 293～307.
〔10〕Pagel M, Pimte G, Rotach-Toulhoat N. The rare earth elements in natural uranium oxides. Gebrudetr Borntrager Stuttgart, Monogr〔J〕. Series on Mineral Deposits, 1987,27: 81～85.
〔11〕Terakado Y, Masuda A. The coprecipitation of rare earth elements with calcite and aragonite〔J〕. Chemical Geology,1988, 69(1/2): 103～110.
〔12〕Michard A, Albarede F, Michard G,et al. Rare earth elements and uranium in high-temperature solutions from East Pacific Rise hydrothermal vent field (13°N)〔J〕. Nature,1983, 303(5920): 795～797.
〔13〕Michard A, Albarede F. The REE content of some hydrothermal fluids〔J〕. Chemical Geology, 1986, 55(1/2): 51～60.
〔14〕Michard A. Rare earth element systematics in hydrothermal fluids〔J〕. Geochimica et Cosmochimica Acta, 1989, 53(3):745～750.
〔15〕Campbell A C. Chemistry of hot springs on the Mid-Atlantic Ridge〔J〕. Nature, 1988, 335(6189/6190): 514～519.
〔16〕Klinkhammer G P, Elderfield H, Mitra A. Geochemical implications of rare earth element patterns in hydrothermal fluids from mid-ocean ridges〔J〕. Geochimica et Cosmochimica Acta, 1994, 58(23): 5 105～5 113.
〔17〕Bau M. Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium〔J〕. Chemical Geology,1991, 93(3/4): 219～230.
〔18〕Piepgras D J,Wasserburg G J. Strontium and neodymium isotopes in hot spring on the East Pacific Rise and Guaymas Basin〔J〕. Earth Planet Sci Leet, 1985, 72(4): 341～356.
〔19〕Hass J R, Shock E L, Sassani D C. Rare earth elements in hydrothermal systems: Estimates of standard partial molal thermodynamic properties of aqueous complexes of the rare earth elements at high pressures and temperatures〔J〕.Geochimica et Cosmochimica Acta, 1995, 59(21): 4 329～4 350.
〔20〕Sverjensky D A. Europium equilibria in aqueous solution〔J〕.Earth Planet Sci Lett, 1984, 67(1): 70～78.
〔21〕James R H, Elderfield H. Chemistry of ore-forming fluids and mineral formation rates in an active hydrothermal sulfide deposit on the Mid-Atlantic Ridge〔J〕. Geology, 1996, 24(12): 1 147～1 150.
〔22〕Mills R A, Elderfield H. Rare earth element geochemistry of hydrothermal deposits from the active TAG Mound, 26°N mid-Atlantic Ridge〔J〕. Geochimica et Cosmochimica Acta,1995, 59(17): 3 511～3 524.
〔23〕Bau M, Dulski P. Comparative study of yttrium and rare-earth element behaviors in fluorine-rich hydrothermal fluids 〔J〕. Contrib Mineral Petrol, 1995, 119: 213～223.
〔24〕Kawabe I, Kitahara Y, Naito K. Non-chondritic yttrium/holmium ratio and lanthanide tetrad effect observed in pre-Cenozoic limestones〔J〕. Geochemical Journal, 1991, 25(1):31～44.
〔25〕Douvlle E, Bienvenu P, Charlou J L,et al. Yttrium and rare earth elements in fluids from various deep-sea hydrothermal systems〔J〕. Geochimica et Cosmochimica Acta, 1999, 63(5): 627～643.
〔26〕Bau M, Dulski. Comparing yttrium and rare earths in hydrothermal fluids from the Mid-Atlantic Ridge: implications for Y and REE behaviour during near-vent mixing and Y/Ho ratio of Proterozoic seawater〔J〕. Chemical Geology, 1999,155(1): 77～90.
/
| 〈 |
|
〉 |
甘公网安备62010202000687
