应用同位素地球化学

贵州戈塘金矿萤石微量元素特征及钐—钕测年

  • 黄建国 ,
  • 李虎杰 ,
  • 李文杰 ,
  • 董 磊
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  • 1.西南科技大学环境与资源学院,四川 绵阳 621010;2.贵州大学资源与环境工程学院,贵州 贵阳 550003
黄建国(1980-),男,甘肃渭源人,助理研究员,主要从事地质学的教学和研究工作.E-mail:hjg0816@126.com

收稿日期: 2012-07-24

  修回日期: 2012-08-17

  网络出版日期: 2012-10-10

基金资助

全国危机矿山接替资源找矿项目“西南地区层控型多金属矿床成矿规律总结”(编号:20089943)资助.

Trace Element Characteristics of Fluorite and Its Sm-Nd Isotopic Dating in Getang Gold Deposit, Guizhou Province

  • Huang Jianguo ,
  • Li Hujie ,
  • Li Wenjie ,
  • Dong Lei
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  • 1.College of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, China;
    2.College of Resource and Environment Engineering, Guizhou University, Guiyang 550003, China)

Received date: 2012-07-24

  Revised date: 2012-08-17

  Online published: 2012-10-10

摘要

对与戈塘金矿共生的萤石微量元素特征研究表明:萤石中Mo,W,As,Cd,Bi等高温元素含量均高于地壳值,V,Cr,Cu,Cs,Th,Mo,Ga和Ge等元素变异系数大,活化能力强。萤石的稀土总量很低,仅为10.299×10-6~17.455×10-6,明显富集重稀土(LREE/HREE为0.48~0.69),并具有Eu和Ce的负异常(δEu为0.71~0.91,δCe为0.62~0.78),Tb/CaTb/La图解显示萤石为热液成因且为热液的晚期阶段。萤石的Rb/Sr比值和初始87Sr/86Sr比值均与地幔值较为接近,反映出其成矿流体主要来源于上地幔或(岩浆)深部。萤石的形成经历了长期演化的热液活动,成矿温度较低(<200°~250°),成矿年龄为(35.83±0.37)Ma(Sm-Nd等时线年龄)。

本文引用格式

黄建国 , 李虎杰 , 李文杰 , 董 磊 . 贵州戈塘金矿萤石微量元素特征及钐—钕测年[J]. 地球科学进展, 2012 , 27(10) : 1087 -1093 . DOI: 10.11867/j.issn.1001-8166.2012.10.1087

Abstract

Trace element characteristics of symbiotic fluorite with Getang gold deposit have shown that: Its high-temperature element (including Mo, W, As, Cd, Bi, etc.) have higher contents than the crustal values. Those elements (including V, Cr, Cu, Cs, Th, Mo, Ga, Ge, etc.) have bigger coefficient of variation and strong activation energy. Fluorite’s total REE is low, only 10.299×10-6~17.455×10-6, and enrichment of heavy rare earth is obvious (LREE/HREE is 0.48-0.69), and have negative anomalies of Eu and Ce (δEu=0.71-0.91,δCe=0.62-0.78). The Tb/Ca vs. Tb/La diagram shows that fluorite is hydrothermal and is in its late stage. Rb/Sr ratios of fluorite and its initial 87Sr/86Sr ratios are closer to the mantle value, which reflect that its ore-forming fluids are from the upper mantle or (magma) deep. The formation of fluorite experienced a long-term evolution of the hydrothermal activity, lower ore-forming temperature (<200°~250°), and mineralization age is 35.83±0.37 Ma (Sm-Nd isochron age)

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