地球科学进展 ›› 2016, Vol. 31 ›› Issue (3): 320 -334. doi: 10.11867/j.issn.1001-8166.2016.03.0320.

上一篇    

闽西南基性岩脉中捕获锆石SIMS U-Pb年龄及Hf、O同位素特征
张文慧( ), 王翠芝, 李晓敏, 刘文元   
  1. 福州大学紫金矿业学院,福建 福州 350108
  • 收稿日期:2016-01-20 修回日期:2016-02-26 出版日期:2016-03-20
  • 基金资助:
    国家自然科学基金项目“福建紫金山矿集区岩浆锆石Hf-O同位素及微量元素研究——寻找岩浆含矿事件指纹”(编号:41173036);福建省自然科学基金项目“福建省紫金山铜金矿岩浆锆石Hf同位素及微量元素研究”(编号:2013J01160)资助

Zircon SIMS U-Pb Age, Hf and O Isotopes of Mafic Dikes, Southwest Fujian Province

Wenhui Zhang( ), Cuizhi Wang, Xiaomin Li, Wenyuan Liu   

  1. College of Zijin Mining, Fuzhou University, Fuzhou 350108,China
  • Received:2016-01-20 Revised:2016-02-26 Online:2016-03-20 Published:2016-03-10
  • About author:

    First author:Zhang Wenhui (1970-), female, Rizhao City, Shandong Province, Lecturer. Research area include petro geochemistry.E-mail:zhangw5@163.com

  • Supported by:
    Project supported by the National Natural Science Foundation of China “Unraveling the mineralisation event signature in the Zijianshan area, Fujian Province, Hf-O isotope and trace element study of Magmatic Zircons in the Mesozoic Granitoid Rocks” (No.41173036);The Natural Science Foundation of Fujian Province “Hf isotope and trace element study of Magmatic Zircons in the Zijianshan mine, Fujian Province” (No.2013J01160)

测定了闽西南地区5件基性岩脉的全岩主微量元素,锆石U-Pb年龄和Hf,O同位素。5件岩脉主要为辉绿岩,其全岩SiO2含量为45%~53%,稀土元素显示轻稀土富集的右倾配分模式。基性岩脉中大部分锆石具明显振荡环带和扇状环带,为典型岩浆结晶锆石特征。锆石U-Pb年龄(96~2 400 Ma)分布较为分散。除少量锆石年龄(96~142 Ma)可能指示岩脉形成年龄外,其余均为捕获锆石。捕获锆石年龄主要分布在4个范围:早元古代(2 467~1 796 Ma),中晚元古代—震旦纪(1 343~647 Ma),志留纪—晚三叠世(427~225 Ma),晚侏罗世(159~140 Ma)。Hf-O同位素显示早元古代锆石来源于接近球粒陨石均一储库的地幔。中晚元古代以后年龄的锆石其Hf-O同位素均具有亏损地幔岩浆与地壳组分混合的特征;志留纪—晚侏罗世锆石主要来源于S型壳源花岗岩的重熔;早白垩世晚期的锆石εHf(t) 值与δ18O值清晰地显示出亏损地幔与地壳岩浆混合的趋势。闽西南基性岩脉中锆石的二阶段Hf亏损地幔模式年龄(TDM2)峰值主要分布在1.6~1.9 Ga,说明早元古代晚期幔源岩浆作用形成的基性岩地壳可能是形成后期花岗岩的主要源区。

The study in this paper determined whole rock major and trace elements, zircon U-Pb age and Hf, O isotopes of 5 mafic dikes in the southwestern Fujian province. The 5 dikes are mainly diabase and the whole rock SiO2 content are between 45%~53%. Most zircons of the mafic dikes display obvious oscillatory zoning and fan-shaped zoning, and have the typical magmatic zircon crystallization characteristics. Zircon U-Pb age is dispersed with 96~2 400 Ma range. In addition to the minimum age (96~142 Ma) which might be the age of the formation of dikes, the remaining are captured zircon. The captured zircon age was mainly distributed in 4 groups: Early Proterozoic (2 467~1 796 Ma); Middle and late Proterozoic (1 343~647 Ma); Silurian to late Triassic Epoch (427~225 Ma); and Late Jurassic (159~140 Ma). Hf-O isotope shows that the early Proterozoic zircon was derived from the mantle of the homogeneous chondrite reservoir, and the others show magmatic mixing characteristics between depleted mantle and crust. Zircon’s εHf(t) and δ18O of the early Late Cretaceous clearly show the mixing trend of depleted mantle and crustal magma. The peak of zircon Hf two-stage depleted mantle model age TDM2 was mainly distributed in the 1.6~1.9 Ga. The Early Proterozoic mafic crust might be the main source for latter granite.

中图分类号: 

图1 闽西南地区地质简图及基性岩脉采样位置 [ 4 ]
Fig.1 Geological sketch map of southwestern Fujian and mafic dikes’ sampling positions [ 4 ]
图2 闽西基性岩脉岩相学特征
Act.阳起石;Hy.紫苏辉石;Pl.斜长石
Fig.2 The petrographic characteristics of mafic dikes
Act.Actinolite; Hy.Hypersthene; Pl. Plagioclase
表1 闽西南基性岩脉岩石学特征
Table 1 Petrological characteristics of mafic dikes
样品号 采样位置 岩性 锆石数量 样品描述
YY-1 25°09'39.7″N,
116°22'54.9″E
紫苏辉
绿岩
800 岩脉侵入到晚侏罗世二长花岗岩中,出露宽度约20 m。该岩石样品的结构不一致,以辉绿结构为主( 图2 a,b)。长石结晶程度较高,多呈柱状,粒径变化范围为0.1~1 mm,含量约占65%。辉石主要为紫苏辉石,结晶程度与其周围所布斜长石晶体特征有关。未蚀变的辉石其含量约占15%,蚀变后所生成的阳起石含量亦占15%左右。另可见少量的铁质分布,约占5%
SF-5 25°14'30.8″N,
116°25'59.9″E
强蚀变
辉绿岩
>1 000 岩脉侵入到早白垩世晚期四坊岩体,出露宽度3~4 m,沿着裂隙见黄铁矿化。岩石深灰色,块状构造。镜下呈显微晶质结构。矿物的粒径均小于0.1 mm,其中,石英和长石难以区分鉴别,两者总体含量约为65%;薄片中还可见少量铁质,含量约为1%。岩石的裂隙十分发育,局部呈碎裂构造,沿着裂隙可见方解石脉、石英脉充填。表明岩石受过多期次的热液影响
SH-1 25°06'02.4″N,
116°28'58.2″E
辉绿岩 110 辉绿岩脉侵入到早白垩世花岗斑岩中,出露宽度约5 m。岩石呈辉绿结构。斜长石多为半自形的柱状( 图2 c,d),粒径主要为0.5~2 mm,聚片双晶常见,其含量约占65%;阳起石多为他形粒状,粒径主要在0.5~1 mm,正中突起,单偏光下呈浅绿色,含量在30%,为辉石或角闪石的次生矿物;铁质矿物含量在5%左右。薄片中未见原生石英颗粒,故而其原岩可能为辉长岩
SH-2 25°25'45.3″N,
116°45'41.3″E
辉绿岩 90 岩脉侵入到晚侏罗世石英二长岩中。岩石为辉绿结构。斜长石多为半自形的柱状颗粒,粒径主要在1~5 mm,聚片双晶的纹路间距较宽,表明这些斜长石偏基性,其含量约占70%;阳起石多为他形粒状,粒径为0.5~2 mm,正中突起,单偏光下呈浅褐色至浅绿色,含量在20%左右,为辉石或角闪石的次生矿物;铁质矿物含量在10%左右。该样品与SH-1岩性较为相似,但SH-2的原生矿物粒径较大一些,其蚀变程度也更强,铁质矿物含量也较高
MK-1 马坑铁矿300 m中段8号穿脉盲竖井车场附近 辉绿岩 53 岩脉侵入到晚侏罗世二长花岗岩中。岩石呈辉绿结构( 图2 e,f),斜长石结晶程度较好,呈柱状,粒径为1~2 mm,聚片双晶现象明显,含量约为45%;阳起石呈他形粒状、板状并充填于斜长石之间,解理发育,其含量约占45%;白云母主要呈片状、板状,含量约占5%;样品内可见较多的铁质矿物,含量约占5%,多呈他形粒状,为原矿物(辉石)在蚀变成阳起石过程中的伴生矿物
图3 主量元素硅碱图(据参考文献[20]修改)
Pc.苦橄玄武岩;B.玄武岩;O1.玄武安山岩;O2.安山岩;O3.英安岩;R.流纹岩;S1.粗面玄武岩;S2.玄武质粗面安山岩;S3.粗面安山岩;T.粗面岩、粗面英安岩;F.副长石岩;U1.碱玄岩、碧玄岩;U2.响岩质碱玄岩;U3.碱玄质响岩;Ph.响岩;Ir.Irvine分界线,上方为碱性,下方为亚碱性
Fig.3 Silicon vs. alkali diagram of major elements (modified after reference [20])
Pc.Picrite basalt; B.Basalt; O1.Basaltic andesite; O2.Andesite;O3.Dacite; R.Rhyolite; S1.Trachybasalt; S2.Basaltic trachyandesite;S3.Trachyandesite; T.Trachyte and trachydacite; F.Feldspathoidite;U1.Tephrite and basanite; U2.Phonolitic tephrite; U3.Tephriticphonolite; Ph.Phonolite; Ir.Irvine boundary, upper is alkali series, lower is subalkali series
表2 闽西南基性岩脉全岩主量(%)及微量(μg/g)元素组成
Table 2 Major (%) and trace (μg/g) elements of mafic dikes
样品 YY-1 SF-5 Sh-1 Sh-2 MK-1 样品 YY-1 SF-5 Sh-1 Sh-2 MK-1
SiO2 50.5 53.5 50.9 45.8 48.4 Y 21.2 41.6 31.2 37.2 29.8
TiO2 1.00 0.81 1.29 3.67 1.78 La 28.5 58.9 21.4 38.5 9.1
Al2O3 16.3 19.9 16.6 14.6 14.4 Ce 58.8 121.3 44.5 87.6 20.8
Fe2O3 4.79 1.56 1.87 4.33 2.43 Pr 7.55 13.69 5.78 11.75 3.04
FeO 3.00 5.43 6.97 10.75 9.77 Nd 29.9 49.3 23.8 51.3 14.3
MnO 0.13 0.17 0.20 0.21 0.38 Sm 5.67 8.49 5.36 10.43 4.04
MgO 6.81 4.31 5.86 4.77 7.49 Eu 1.69 1.95 1.63 4.49 1.41
CaO 7.92 2.93 10.01 7.37 9.23 Gd 4.66 7.59 4.91 8.88 3.95
Na2O 2.84 2.15 2.87 2.98 1.95 Tb 0.76 1.25 0.96 1.45 0.87
K2O 1.88 3.57 1.34 2.48 0.89 Dy 3.98 6.98 5.65 7.50 5.39
P2O5 0.26 0.14 0.15 0.93 0.15 Ho 0.83 1.53 1.24 1.51 1.20
H2O+ 3.80 4.24 1.18 1.14 2.00 Er 2.34 4.48 3.55 3.91 3.32
H2O- 1.98 0.24 0.08 0.04 0.13 Tm 0.36 0.74 0.57 0.55 0.54
灼失量 4.38 5.32 1.81 1.75 3.00 Yb 2.00 4.22 3.28 3.07 3.12
总和 99.81 99.78 99.88 99.61 99.79 Lu 0.43 0.64 0.47 0.53 0.42
Li 28.4 124.2 33.2 29.5 42.2 Mo 0.46 0.74 0.84 1.21 1.12
Be 1.57 4.80 0.97 1.68 1.56 Cd 0.10 0.05 0.07 0.36 0.07
Sc 27.5 25.8 33.6 32.8 59.8 In 0.07 0.15 0.16 0.11 0.15
V 177 152 195 283 346 Cs 4.10 11.25 6.16 27.00 7.03
Cr 200 110 235 27 112 Ba 623 924 233 1290 89
Co 29.2 21.3 31.5 46.2 43.0 Hf 4.99 4.42 5.23 6.22 7.24
Ni 103.5 57.0 79.4 30.3 69.9 Ta 0.75 1.80 0.93 1.52 0.90
Cu 21.8 13.9 63.4 48.2 31.8 W 0.32 6.43 0.63 0.34 10.74
Zn 85 116 107 168 105 Tl 0.16 0.76 0.50 0.51 0.90
Ga 20.8 32.4 21.4 26.7 24.3 Pb 11.0 16.7 13.4 63.2 5.5
Rb 51.2 166.5 86.3 85.3 98.0 Bi 0.02 0.25 0.54 0.07 0.18
Sr 632 200 316 520 386 Th 6.20 18.82 5.01 2.35 1.59
Zr 175 151 144 230 112 U 1.28 4.41 1.12 0.36 0.44
Nb 12.8 21.4 13.3 26.3 10.2 Ag 0.02 0.07 0.08 0.07 0.04
图4 稀土(a)微量元素(b)标准化图解
闽北赤门晚白垩世角闪辉长岩,强不相容元素及Sr,Nd同位素显示富集岩石圈地幔源区特征 [ 19 ]; 球粒陨石及原始地幔值据参考文献[17]
Fig.4 Rare earth (a) trace element (b) standardized diagram
Late Cretaceous Chimen bojite in northern Fujian, strong incompatible element and Sr, Nd isotopes show characteristics of enriched lithospheric mantle source [ 19 ];The chondrite meteorites and the primitive mantle after reference[17]
表3 闽西南基性岩脉锆石 U/Pb 年龄组成
Table 3 Zircon U/Pb age of mafic dikes
点号 含量 比值 年龄
样品 U/
(μg/g)
Th/
(μg/g)
Th
/U
207Pb
/206Pb
±σ/
%
207Pb
/235U
±σ/
%
206Pb
/238U
±σ/
%
207Pb
/206Pb
±σ/
%
207Pb
/235U
±σ/
%
206Pb
/238U
±σ/
%
YY-1@1 276 159 0.58 0.04972 1.68 0.16857 2.26 0.0246 1.51 181.8 38.6 158.2 3.3 156.6 2.3
YY-1@2 229 132 0.58 0.04859 2.07 0.16620 2.57 0.0248 1.51 127.9 48.1 156.1 3.7 158.0 2.4
YY-1@4 963 527 0.55 0.04759 1.26 0.10962 2.12 0.0167 1.71 79.1 29.6 105.6 2.1 106.8 1.8
YY-1@5 207 150 0.72 0.05033 1.47 0.17192 2.11 0.0248 1.51 210.2 33.7 161.1 3.1 157.8 2.4
YY-1@6 459 281 0.61 0.04870 1.31 0.16328 2.00 0.0243 1.51 133.5 30.6 153.6 2.9 154.9 2.3
YY-1@7 112 78 0.69 0.05068 2.21 0.17368 2.67 0.0249 1.50 226.1 50.2 162.6 4.0 158.3 2.3
YY-1@8 479 24 0.05 0.04827 1.21 0.11145 1.95 0.0167 1.53 112.3 28.4 107.3 2.0 107.1 1.6
YY-1@9 725 258 0.36 0.04885 0.94 0.16583 1.82 0.0246 1.56 140.8 21.9 155.8 2.6 156.8 2.4
YY-1@10 365 235 0.64 0.04815 1.57 0.16460 2.19 0.0248 1.52 106.6 36.8 154.7 3.1 157.9 2.4
YY-1@11 154 70 0.45 0.04861 1.87 0.14697 2.41 0.0219 1.52 129.0 43.4 139.2 3.1 139.8 2.1
YY-1@12 238 122 0.51 0.04863 2.14 0.16062 2.62 0.0240 1.51 130.1 49.7 151.2 3.7 152.6 2.3
YY-1@13 327 22 0.07 0.04919 1.45 0.11368 2.10 0.0168 1.52 156.8 33.7 109.3 2.2 107.2 1.6
YY-1@14 880 286 0.33 0.04913 0.89 0.16355 1.76 0.0241 1.52 154.2 20.6 153.8 2.5 153.8 2.3
YY-1@15 206 138 0.67 0.04949 1.64 0.17025 2.23 0.0249 1.51 171.3 37.9 159.6 3.3 158.9 2.4
SF-5@1 338 158 0.47 0.08318 0.59 2.53884 1.62 0.2214 1.51 1 273.4 11.4 1 283.2 11.8 1 289.1 17.6
SF-5@2 476 271 0.57 0.04745 2.26 0.09974 2.72 0.0152 1.52 72.0 52.8 96.5 2.5 97.5 1.5
SF-5@3 573 64 0.11 0.07586 0.36 1.93274 1.56 0.1848 1.52 1 091.3 7.2 1 092.5 10.5 1 093.1 15.3
SF-5@4 428 630 1.47 0.07892 0.37 2.18154 1.55 0.2005 1.50 1 170.2 7.2 1 175.2 10.8 1 177.9 16.2
SF-5@5 1 148 372 0.32 0.06228 0.39 0.97977 1.55 0.1141 1.50 683.9 8.4 693.5 7.8 696.4 9.9
SF-5@6 495 102 0.21 0.07591 0.40 1.93906 1.56 0.1853 1.51 1 092.7 8.0 1 094.7 10.5 1 095.7 15.2
SF-5@7 419 243 0.58 0.08348 0.36 2.48669 1.54 0.2161 1.50 1 280.4 7.0 1 268.2 11.2 1 261.0 17.2
SF-5@9 634 351 0.55 0.15848 0.28 9.85425 1.53 0.4510 1.50 2 439.5 4.8 2 421.2 14.2 2 399.6 30.1
SF-5@10 654 262 0.40 0.07318 0.35 1.72979 1.54 0.1714 1.50 1 019.0 7.0 1 019.7 10.0 1 020.0 14.2
SF-5@11 341 146 0.43 0.07555 0.63 1.91387 1.63 0.1837 1.50 1 083.2 12.6 1 085.9 10.9 1 087.3 15.1
SF-5@12 1 487 624 0.42 0.06055 0.38 0.88177 1.75 0.1056 1.71 623.5 8.3 641.9 8.4 647.2 10.5
SF-5@13 1 649 933 0.57 0.07142 0.27 1.60534 1.53 0.1630 1.50 969.5 5.5 972.3 9.6 973.5 13.6
SF-5@14 278 162 0.58 0.06306 0.67 0.99840 1.65 0.1148 1.51 710.1 14.2 703.0 8.4 700.8 10.0
SF-5@15 1 000 795 0.79 0.07612 0.34 1.94049 1.54 0.1849 1.50 1 098.2 6.9 1 095.2 10.4 1 093.7 15.1
SH-1@1 228 306 1.34 0.04962 1.69 0.15645 2.26 0.0229 1.50 177.3 39.0 147.6 3.1 145.8 2.2
SH-1@2 242 120 0.49 0.04788 2.53 0.10078 2.95 0.0153 1.51 93.4 58.8 97.5 2.7 97.7 1.5
SH-1@3 619 341 0.55 0.04888 1.05 0.11643 1.92 0.0173 1.61 142.1 24.5 111.8 2.0 110.4 1.8
SH-1@4 483 280 0.58 0.04878 1.66 0.11753 2.30 0.0175 1.59 137.4 38.4 112.8 2.5 111.7 1.8
SH-1@5 355 236 0.67 0.05133 0.95 0.25182 1.79 0.0356 1.52 255.5 21.6 228.1 3.7 225.4 3.4
SH-1@6 325 53 0.16 0.07717 0.44 2.00244 1.57 0.1882 1.51 1 125.6 8.8 1 116.3 10.7 1 111.6 15.4
SH-1@7 159 119 0.75 0.05063 2.60 0.25403 3.01 0.0364 1.51 224.0 59.1 229.8 6.2 230.4 3.4
SH-1@8 255 150 0.59 0.08330 0.36 2.50036 1.55 0.2177 1.50 1 276.2 7.1 1 272.1 11.3 1 269.7 17.3
SH-1@9 539 385 0.71 0.04970 1.49 0.16790 2.12 0.0245 1.51 181.1 34.3 157.6 3.1 156.0 2.3
SH-1@10 579 459 0.79 0.04708 2.30 0.14201 2.76 0.0219 1.53 53.4 53.9 134.8 3.5 139.5 2.1
SH-1@12 170 128 0.75 0.07336 1.32 1.74233 2.01 0.1723 1.51 1 023.9 26.5 1 024.3 13.0 1 024.5 14.3
SH-1@13 1 552 1 842 1.19 0.04793 1.21 0.15483 1.92 0.0234 1.50 95.7 28.3 146.2 2.6 149.3 2.2
SH-1@14 186 81 0.44 0.05296 1.51 0.49950 2.13 0.0684 1.50 327.3 33.9 411.4 7.2 426.5 6.2
SH-2@1 980 846 0.86 0.04647 1.73 0.10071 2.30 0.0157 1.51 22.1 41.0 97.4 2.1 100.5 1.5
SH-2@4 434 414 0.95 0.04842 1.34 0.10013 2.02 0.0150 1.51 120.0 31.3 96.9 1.9 96.0 1.4
SH-2@9 787 916 1.16 0.04995 0.78 0.17133 1.70 0.0249 1.51 192.6 18.0 160.6 2.5 158.4 2.4
SH-2@10 455 238 0.52 0.04778 1.55 0.11258 2.24 0.0171 1.61 88.5 36.4 108.3 2.3 109.2 1.7
SH-2@11 281 298 1.06 0.05047 1.32 0.17226 2.01 0.0248 1.51 216.7 30.3 161.4 3.0 157.6 2.4
SH-2@13 760 842 1.11 0.04460 2.09 0.09428 2.58 0.0153 1.51 -77.5 50.3 91.5 2.3 98.1 1.5
SH-2@14 1 034 2 087 2.02 0.04769 1.51 0.10501 2.14 0.0160 1.52 83.7 35.3 101.4 2.1 102.1 1.5
SH-2@15 397 179 0.45 0.08625 0.36 2.68155 1.54 0.2255 1.50 1 343.8 6.9 1 323.4 11.5 1 310.8 17.8
MK-1@1 729 351 0.48 0.13473 0.25 7.21785 1.52 0.3885 1.50 2 160.5 4.4 2 138.7 13.7 2 116.1 27.1
MK-1@2 416 282 0.68 0.04954 1.15 0.15034 1.90 0.0220 1.51 173.4 26.6 142.2 2.5 140.4 2.1
MK-1@3 794 413 0.52 0.15012 0.25 9.06767 1.52 0.4381 1.50 2 347.3 4.2 2 344.9 14.0 2 342.0 29.6
MK-1@4 250 189 0.76 0.12395 0.64 5.91163 1.63 0.3459 1.50 2 013.9 11.2 1 962.9 14.3 1 915.0 25.0
MK-1@5 384 173 0.45 0.05134 1.24 0.28846 1.95 0.0407 1.50 256.2 28.2 257.3 4.4 257.5 3.8
MK-1@6 100 105 1.05 0.12633 0.40 6.24081 1.55 0.3583 1.50 2 047.6 7.0 2 010.2 13.7 1 974.0 25.6
MK-1@8 80 41 0.51 0.11961 0.61 5.71955 1.63 0.3468 1.51 1 950.4 10.8 1 934.3 14.1 1 919.3 25.1
MK-1@9 683 307 0.45 0.12229 0.29 5.98532 1.53 0.3550 1.50 1 989.9 5.2 1 973.7 13.4 1 958.3 25.4
MK-1@10 620 153 0.25 0.11446 0.47 5.13954 1.57 0.3257 1.50 1 871.4 8.4 1 842.7 13.5 1 817.3 23.9
MK-1@11 14 2 0.11 0.12222 1.44 5.85915 2.08 0.3477 1.50 1 988.8 25.4 1 955.2 18.2 1 923.6 25.0
MK-1@12 736 283 0.38 0.05168 1.18 0.30197 1.91 0.0424 1.50 271.2 26.8 267.9 4.5 267.6 3.9
MK-1@13 646 916 1.42 0.16109 0.13 9.46211 1.51 0.4260 1.50 2 467.1 2.2 2 383.9 13.9 2 287.7 29.0
MK-1@14 154 119 0.77 0.10979 0.49 4.79047 1.58 0.3164 1.50 1 796.0 9.0 1 783.2 13.4 1 772.3 23.3
MK-1@15 696 393 0.56 0.13742 0.59 7.55371 1.65 0.3987 1.54 2 195.0 10.2 2 179.4 14.9 2 162.9 28.4
MK-1@16 716 112 0.16 0.12149 0.39 5.92494 1.56 0.3537 1.51 1 978.3 7.0 1 964.9 13.7 1 952.2 25.5
图5 锆石的U-Pb年龄谱图和阴极发光(CL)图像
CL图像中白色圆代表U/Pb定年和Hf-O同位素分析的位置,数字表示U/Pb年龄/ε Hf( t)值/δ 18O值
Fig.5 Zircon U-Pb age spectra and cathode luminescence (CL) images
White circle represents the analysis location of Hf-O and U/Pb isotopes in the CL image, the digital means U/Pb age/ε Hf( t)/δ 18O values
图6 基性岩脉锆石中δ 18O值正态分布图
Fig.6 Normal distribution of δ 18O values in zircon
表4 闽西南基性岩脉锆石O同位素组成 *
Table 4 Zircon O isotopes of mafic dikes
样品 δ18O σ 样品 δ18O σ 样品 δ18O σ 样品 18O σ 样品 δ18O σ
YY-1@1 8.24 0.30 SF-5@1 8.45 0.32 SH-1@1 6.91 0.37 SH-2@1 7.04 0.26 MK-1@1 6.15 0.27
YY-1@2 8.55 0.26 SF-5@2 7.12 0.24 SH-1@2 7.09 0.19 SH-2@4 6.66 0.27 MK-1@2 7.42 0.33
YY-1@3 8.09 0.22 SF-5@3 8.07 0.28 SH-1@3 6.71 0.29 SH-2@5 8.19 0.23 MK-1@3 6.44 0.40
YY-1@4 5.80 0.30 SF-5@4 8.67 0.35 SH-1@4 6.84 0.24 SH-2@8 6.55 0.27 MK-1@5 8.43 0.26
YY-1@5 8.06 0.23 SF-5@5 7.16 0.36 SH-1@5 9.40 0.29 SH-2@9 7.53 0.32 MK-1@6 4.69 0.29
YY-1@6 7.75 0.28 SF-5@6 7.81 0.38 SH-1@6 8.77 0.39 SH-2@10 6.38 0.30 MK-1@7 6.17 0.25
YY-1@7 7.86 0.27 SF-5@7 6.37 0.26 SH-1@7 9.95 0.21 SH-2@11 7.58 0.37 MK-1@8 6.23 0.27
YY-1@8 8.18 0.33 SF-5@8 6.41 0.28 SH-1@8 6.78 0.26 SH-2@12 5.81 0.39 MK-1@9 6.13 0.22
YY-1@9 7.82 0.28 SF-5@9 5.76 0.30 SH-1@9 8.48 0.28 SH-2@13 7.16 0.23 MK-1@10 4.42 0.36
YY-1@10 8.17 0.21 SF-5@10 6.35 0.37 SH-1@10 8.05 0.34 SH-2@14 7.37 0.35 MK-1@11 8.09 0.24
YY-1@11 8.07 0.29 SF-5@11 8.77 0.25 SH-1@11 4.81 0.26 SH-2@15 6.91 0.25 MK-1@12 7.61 0.34
YY-1@12 8.58 0.27 SF-5@12 7.62 0.41 SH-1@12 6.22 0.28 SH-2@16 9.37 0.38 MK-1@13 5.05 0.25
YY-1@13 7.99 0.33 SF-5@13 7.34 0.32 SH-1@13 6.61 0.24 SH-2@17 6.13 0.24 MK-1@14 4.92 0.39
YY-1@14 8.05 0.32 SF-5@14 8.03 0.33 SH-1@14 10.77 0.34 SH-2@18 5.79 0.39 MK-1@15 4.95 0.39
YY-1@15 8.75 0.31 SF-5@15 7.78 0.45 SH-1@16 6.54 0.38 SH-2@19 7.87 0.27 MK-1@16 6.90 0.35
YY-1@16 9.59 0.29 SF-5@16 8.63 0.27 SH-1@17 12.22 0.33 SH-2@20 6.85 0.31 MK-1@17 11.04 0.26
YY-1@17 8.96 0.34 SF-5@17 7.50 0.31 SH-1@18 7.17 0.35 SH-2@21 7.84 0.19 MK-1@18 7.89 0.33
YY-1@18 8.78 0.22 SF-5@18 7.79 0.26 SH-1@19 8.01 0.31 SH-2@22 7.78 0.22 MK-1@19 4.03 0.42
YY-1@20 8.31 0.25 SF-5@19 11.12 0.48 SH-1@20 6.79 0.20 SH-2@23 6.56 0.23 MK-1@20 8.90 0.38
YY-1@21 8.42 0.28 SF-5@20 5.65 0.19 SH-1@21 5.61 0.27 SH-2@24 8.39 0.30 MK-1@21 6.11 0.30
YY-1@22 8.33 0.25 SF-5@21 6.69 0.55 SH-1@22 6.98 0.37 SH-2@25 7.45 0.28 MK-1@22 7.94 0.14
YY-1@23 8.04 0.26 SF-5@22 6.73 0.27 SH-1@23 7.62 0.22 SH-2@26 8.19 0.29 MK-1@23 6.58 0.27
YY-1@24 11.22 0.38 SF-5@23 7.61 0.36 SH-1@24 6.90 0.31
YY-1@25 9.95 0.29 SF-5@24 8.73 0.36 SH-1@25 7.31 0.24
YY-1@26 6.57 0.26 SF-5@25 5.97 0.33 SH-1@26 4.11 0.39
YY-1@27 6.53 0.38 SF-5@26 7.45 0.49 SH-1@27 7.10 0.20
YY-1@28 7.96 0.30 SF-5@27 5.88 0.26 SH-1@28 6.94 0.24
YY-1@29 6.67 0.32 SF-5@28 8.49 0.40 SH-1@29 5.86 0.27
YY-1@30 11.81 0.37 SF-5@29 8.87 0.28 SH-1@30 9.95 0.26
YY-1@31 11.78 0.38 SF-5@30 9.03 0.26 SH-1@31 7.40 0.27
YY-1@32 9.22 0.27 SF-5@31 7.81 0.34 SH-1@32 7.80 0.31
YY-1@33 8.80 0.38 SF-5@32 8.30 0.48
YY-1@34 8.56 0.26 SF-5@33 6.93 0.27
YY-1@35 8.15 0.46 SF-5@34 6.05 0.33
图7 闽西南基性岩脉锆石δ 18O值与年龄相关图
锆石δ 18O地幔值范围据参考文献[21, 22]
Fig.7 Zircon δ 18O vs. age diagram
Mantle δ 18O value after the references [21, 22]
表5 闽西南基性岩脉锆石Hf同位素组成
Table 5 Zircon Hf isotopes of mafic dikes
点号 176Yb
/177Hf
σ 176Lu
/177Hf
σ 176Hf
/177Hf
σ 176Hf
/177Hfi
εHf(0) εHf(t) TDM
/Ma
TDM2
/Ma
YY-1@1 0.029313 0.000048 0.001240 0.000002 0.282431 0.000024 0.282427 -12.1 -8.8 1 169 1 757
YY-1@2 0.016859 0.000075 0.000694 0.000002 0.282410 0.000023 0.282408 -12.8 -9.4 1 181 1 800
YY-1@4 0.023772 0.000523 0.001131 0.000021 0.282662 0.000022 0.282660 -3.9 -1.6 839 1 269
YY-1@5 0.023173 0.000256 0.000929 0.000009 0.282251 0.000026 0.282248 -18.4 -15.1 1 411 2 156
YY-1@6 0.028977 0.000218 0.001166 0.000010 0.282460 0.000027 0.282456 -11.0 -7.8 1 126 1 694
YY-1@7 0.026285 0.000195 0.001068 0.000007 0.282368 0.000026 0.282365 -14.3 -10.9 1 252 1 896
YY-1@8 0.009108 0.000020 0.000371 0.000001 0.282423 0.000024 0.282422 -12.3 -10.0 1 154 1 800
YY-1@9 0.030484 0.000153 0.001252 0.000005 0.282440 0.000022 0.282436 -11.7 -8.4 1 157 1 737
YY-1@10 0.023534 0.000060 0.000952 0.000002 0.282419 0.000027 0.282416 -12.5 -9.1 1 177 1 782
YY-1@11 0.016220 0.000056 0.000671 0.000002 0.282471 0.000027 0.282469 -10.6 -7.6 1 096 1 675
YY-1@12 0.035373 0.000887 0.001486 0.000037 0.282432 0.000036 0.282428 -12.0 -8.8 1 175 1 759
YY-1@13 0.006900 0.000014 0.000276 0.000001 0.282512 0.000024 0.282511 -9.2 -6.9 1 028 1 601
YY-1@14 0.034108 0.000234 0.001399 0.000009 0.282410 0.000025 0.282406 -12.8 -9.6 1 204 1 807
YY-1@15 0.029994 0.000172 0.001223 0.000007 0.282379 0.000029 0.282375 -13.9 -10.5 1 242 1 872
SF-5@1 0.049195 0.000262 0.002000 0.000009 0.282034 0.000036 0.281986 -26.1 0.4 1 762 2 030
SF-5@2 0.008705 0.000198 0.000439 0.000009 0.282445 0.000033 0.282444 -11.6 -9.5 1 125 1 757
SF-5@3 0.039487 0.001062 0.001544 0.000041 0.281877 0.000037 0.281845 -31.7 -8.7 1 962 2 456
SF-5@4 0.015149 0.000116 0.000573 0.000003 0.281662 0.000034 0.281649 -39.3 -13.8 2 205 2 836
SF-5@5 0.033856 0.000062 0.001315 0.000003 0.282462 0.000033 0.282445 -11.0 3.8 1 127 1 376
SF-5@6 0.036974 0.002080 0.001375 0.000079 0.282042 0.000029 0.282014 -25.8 -2.7 1 721 2 083
SF-5@7 0.010943 0.000183 0.000488 0.000008 0.282099 0.000032 0.282088 -23.8 4.2 1 603 1 801
SF-5@9 0.022590 0.000453 0.000926 0.000016 0.281332 0.000043 0.281289 -50.9 2.2 2 676 2 817
SF-5@10 0.024615 0.000069 0.000993 0.000003 0.281716 0.000037 0.281697 -37.3 -15.5 2 155 2 827
SF-5@11 0.008459 0.000223 0.000291 0.000008 0.281939 0.000033 0.281933 -29.5 -5.7 1 814 2 267
SF-5@12 0.018547 0.000158 0.000742 0.000007 0.282350 0.000034 0.282341 -14.9 -1.0 1 267 1 640
SF-5@13 0.023679 0.000157 0.000927 0.000006 0.281923 0.000038 0.281906 -30.0 -9.1 1 866 2 396
SF-5@14 0.042394 0.001331 0.001618 0.000049 0.282484 0.000035 0.282463 -10.2 4.5 1 105 1 334
SH-1@1 0.052407 0.002978 0.002301 0.000127 0.282361 0.000039 0.282355 -14.5 -11.6 1 304 1 926
SH-1@2 0.018414 0.000203 0.000865 0.000009 0.282538 0.000034 0.282536 -8.3 -6.2 1 008 1 551
SH-1@3 0.033331 0.001058 0.001610 0.000044 0.282583 0.000035 0.282580 -6.7 -4.4 963 1 446
SH-1@4 0.043479 0.000187 0.001996 0.000008 0.282534 0.000034 0.282530 -8.4 -6.1 1 044 1 557
SH-1@5 0.030341 0.000112 0.001229 0.000004 0.282431 0.000039 0.282426 -12.1 -7.3 1 169 1 717
SH-1@6 0.015187 0.000520 0.000580 0.000020 0.281851 0.000045 0.281839 -32.6 -8.1 1 947 2 448
SH-1@7 0.020139 0.000265 0.000875 0.000011 0.282256 0.000039 0.282252 -18.2 -13.3 1 402 2 101
SH-1@8 0.020725 0.000117 0.000894 0.000006 0.281902 0.000039 0.281880 -30.8 -3.3 1 893 2 261
SH-1@13 0.062233 0.000705 0.002917 0.000041 0.282374 0.000066 0.282366 -14.1 -11.1 1 308 1 899
SH-2@1 0.019693 0.000632 0.000891 0.000026 0.282510 0.000034 0.282508 -9.3 -7.1 1 048 1 612
SH-2@4 0.018621 0.000047 0.000869 0.000003 0.282596 0.000035 0.282594 -6.2 -4.2 926 1 422
SH-2@9 0.052782 0.001405 0.002237 0.000064 0.282434 0.000037 0.282427 -12.0 -8.7 1 196 1 756
MK-1@1 0.023303 0.000200 0.000970 0.000008 0.281289 0.000033 0.281249 -52.4 -5.6 2 738 3 080
MK-1@2 0.028600 0.000413 0.001170 0.000017 0.282447 0.000031 0.282444 -11.5 -8.5 1 144 1 731
MK-1@5 0.026217 0.000259 0.001179 0.000011 0.282415 0.000030 0.282409 -12.6 -7.2 1 190 1 734
MK-1@6 0.021939 0.000109 0.000942 0.000005 0.281413 0.000034 0.281376 -48.1 -3.7 2 567 2 876
MK-1@8 0.011552 0.000108 0.000475 0.000005 0.281555 0.000034 0.281537 -43.0 -0.2 2 344 2 586
MK-1@11 0.004902 0.000077 0.000244 0.000003 0.281582 0.000037 0.281573 -42.1 2.0 2 294 2 485
MK-1@13 0.030628 0.001058 0.001131 0.000039 0.280798 0.000412 0.280745 -69.8 -16.5 3 417 3 973
MK-1@16 0.019704 0.000271 0.000852 0.000013 0.281334 0.000030 0.281302 -50.8 -7.9 2 668 3 081
图8 闽西南基性岩脉锆石年龄与 ε Hf( t)值相关图
底图据参考文献[18]
Fig.8 Zircon age vs. ε Hf( t) diagram
Base map after the reference [18]
图9 ε Hf( t) vs. δ 18O图解
S型花岗岩锆石的Hf-O同位素范围根据广西印支期大容山堇青石花岗岩的数据计算获得 [ 3 ]
Fig.9 ε Hf( t) vs. δ 18O diagram
Zircon Hf-O isotope value of S type granite according to data calculation of indosinian cordierite granite from Darongshan, Guangxi [ 3 ]
图10 Hf二阶段模式年龄分布直方图
Fig.10 Hf two stage model age distribution histogram
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