收稿日期: 2003-03-24
修回日期: 2003-08-13
网络出版日期: 2004-08-01
基金资助
高校博士点基金项目“我国西南地区三叠系煤层中碳笼的分布、赋存及成因”（编号：20010290014）；中国矿业大学科学基金项目“云南—平浪矿区三叠系煤中碳笼的地质分布与成因”（编号：OF1066）资助
OCCURRENCE AND GENESIS OF NATURAL FULLERENCE
Received date: 2003-03-24
Revised date: 2003-08-13
Online published: 2004-08-01
天然富勒烯研究是富勒烯科学和地质科学相交叉的一个新兴研究领域，迄今为止已在桑加岩、闪电熔岩、陨石撞击坑中的含碳质角砾岩、古近系/白垩系地层界线(E/K)的含碳粘土岩、三叠系/二叠系(T/P)界线岩石(粘土岩、硅质岩)、恐龙蛋壳、煤、重质油、固体沥青以及半天然的烟灰、木炭、书墨等物质中检测到富勒烯的存在，但含量很低。多数天然富勒烯的地质分布、成因机制与陨石撞击、野火、闪电等有关，但部分天然富勒烯的成因尚不清楚。天然富勒烯研究扩展了人们对自然界碳结构及其演化的认识，在地质事件、事件地层如陨石撞击事件、E/K界线、T/P界线等的研究中充分显示了其独特的方法和应用价值。
李壮福 , 秦勇 . 天然富勒烯的地质产状与成因[J]. 地球科学进展, 2004 , 19(4) : 682 -686 . DOI: 10.11867/j.issn.1001-8166.2004.04.0682
The study of natural fullerenes is a new area of across fullerene science and geological science. So far natural fullerenes have been found in shungite, fulgurite, carbonaceous conglomerates in impact crater, E/K boundary carbonrich clay rock layer, T/P boundary layer, dinosaur eggshell, coal, heavy crude oil, solid bitumen and socalled seminatural fullerenes in common soots, Chinese ink sticks, commercial char, [WTBX]et al[WTBZ]., only with low concentrations. The geological distribution and genesis of most natural fullerenes have relations with meteoritic impact, wildfire, lightning strike, [WTBX]et al[WTBZ]. and the causes of formation of some natural fullerenes are uncertain. The study of natural fullerenes expands the knowledge about the carbon texture and its evolution in nature and reveals its particular methods and application value adequately in the study of geological events and event stratigraphy, for instance, meteorite impact event, E/K boundary and T/P boundary, et al.
［1］Kroto H W, Heath J R, Brien S C,et al. C60: Buckminsterfullerene［J］. Nature, 1985, 318 (14): 162-163.
［2］Kratschmer W, Lamb L D, Fostoropoulos K, et al. Solid C60: A new form of carbon［J］.Nature, 1990, 347 (27): 354-357.
［3］Iijima S. Helical microtubules of graphic carbon ［J］. Nature, 1991, 354 (7): 56-58.
［4］Ma Tiejun(马铁军), Li Jiajun(李家骏). The study actuality and developing trends of fullerene materials［J］. Chemical Industry Late-model Materials(化工新型材料), 1998，26(11):11-15（in Chinese）.
［5］Kroto H W. Space, stars, C60 and soot［J］. Science, 1988, 242:1 139-1 145.
［6］Buseck P R, Tsipursky S J, Hettich R. Fullerenes from the geological environment［J］. Science, 1992, 257 (10): 215-217.
［7］Gu Y, Wilson M A, Fisher K J,et al. Fullerenes and shungite ［J］.Carbon, 1995, 34 (4): 862-863.
［8］Ebbesen T W, Hiura H, Hedenquist J W, et al. Origins of fullerenes in rocks ［J］. Science, 1995,268(16): 1 634-1 635.
［9］Heymann D. Search for ancient fullerenes in anthraxolite,shungite,and thucholite［J］. Carbon, 1995, 33 (2): 237-239.
［10］Buseck P R, Tsipursky S J. Origins of fullerenes in rocks, reply to comment［J］. Science, 1995, 268(16): 1 634-1 635.
［11］Hettich R L, Buseck P R. Concerning fullerenes in shungite［J］. Carbon, 1996, 34(4): 685-687.
［12］Jehlickas J, Rouzaud J-N. Glass-like Carbon: New type of natural carbonaceous matter from precambrian rocks［J］. Carbon, 1993, 31:1 134-1 135.
［13］Zaidenberg A Z, Rozhkova N N, V V Kovalevski N N, et al. Shungite carbon and fullerenes［J］. Fullerene Science & Technology, 1998, 6 (3)：511-517.
［14］Parthasarathy G, Srinivasan R, Vairamani M, et al. Occurrence of natural fullerenes in low grade metamorphosed Proterozoic shungite from Karelia, Russia［J］. Geochimica et Cosmochimica Acta, 1998, 62(21/22):3 541-3 544.
［15］Osipov E V, Reznikov V A. Synthesis of fullerene-like particles during fullerene extraction from shungite［J］. Carbon, 2002, 40: 961-965.
［16］Daly T K, Buseck P R, Williams P, et al. Fullerenes from a Fulgurite［J］. Science, 1993, 259 (12): 1 599-1 601.
［17］di Brozolo F R, Bunch T E, Fleming R H, et al. Fullerenes in an impact crater on the LDEF spacecraft［J］. Science, 1994, 369 (5): 37-40.
［18］Becker L, Bada J L, Winans R E, et al. Fullerenes in the 1.85-billion-year-old sudbury impact structure［J］. Science, 1994, 265 (29): 642-645.
［19］Becker L, Bada J L, Winans R E, et al. Fullerenes in Alende Meteorite［J］. Nature, 1994, 372 (8): 50.
［20］Becker L,Poreda R J, Bada J L. Extraterrestrial Helium Trapped in Fullerenes in the Sudbury Impact Structure［J］. Science, 1996, 272(12): 249-251.
［21］Becker L, Poreda R J, Bunch T E. Fullerenes: An extraterrestrial carbon carrier phase for noble gases［J］. Proceedings of Natural Academy of Science USA，2000, 97: 2 979-2 983.
［22］Becker L, Bunch T E, Allamandola L J. Higher Fullerenes in Alende Meteorite ［J］. Nature, 1999, 400: 227-228.
［23］Osawa E. Natural Fullerens - Will They Offer a Hint to the Selective Synthesis of Fullerenes?［J］. Fullerene Science & Technology, 1999, 7(4)：637-652.
［24］Jehlicka J, Osawa M, Slanina Z, et al. Fullerenes in the Solid Btumens from Pillow Lava of Precambrian age (Mitov, Bohemian Massif )［J］. Fullerene Science & Technology, 2000, 8(4): 449-452.
［25］Heymann D, Felipe Chibante L P, Brooks R R, et al.Fullerenes in the Cretaceous-Tertiary Boundary Layer［J］. Science, 1994, 265 (29): 645-647.
［26］Osawa E, Hirose Y, Kimura A, et al. Fullerenes in Chinese Ink, A Correction ［J］. Fullerene Science & Technology, 1997,5(1)：177-194.
［27］Shibuya M, Koto M, Ozawa M, et al. Detection of Buckminnsterfullerene in Usual Soots and Commercial Charcoals［J］. Fullerene Science & Technology, 1999,7(2)：181-194.
［28］Becker L, Poreda R J, Hunt A G, et al. Impact Event at the Permian-Triassic Boundary: Evidence from Extraterrestrial Noble Gases in Fullerenes［J］. Science, 2001, 291 (23): 1 530-1 533.
［29］Taylor R, AbdulSada A K. There are no Fullerenes in the K-T Boundary Layer ［J］. Fullerene Science & Technology, 2000, 8 (1~2)：47-54.
［30］Chijiwa T, Arai T, Sugai T, et al. Fullerenes Found in the Permo-Triassic Mass Extinction Period［J］. Geophysical Research Letters, 1999, 26: 767-770.
［31］Wang Zenxia, Li Xuepeng, Wang Wenmin, et al. Fullerenes in the Fossil of Dinosaur Egg［J］. Fullerene Science & Technology, 1998, 6 (4)：715-720.
［32］Yang Zunyi(杨遵仪), Wu Shunbao(吴顺宝), Yin Hongfu(殷鸿福), et al. Permo-Triassic Events of South China［M］. Beijing: Geological Publishing House, 1991（in Chinese）.
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