Abstract:Ecosystem functions and services provided by soil in earth surface has been considered as the
key foundation supporting global society and environment sustainability. All of these functions and services are
closely linked to aggregate hierarchy system of the soil cover. In this review, key ecosystem functions and
services provided by soil including accumulation and stabilization of organic carbon, biodiversity conservation,
Extracellular Enzyme Activities (EEAs) mediating biogeochemical cycling are overviewed linking to
development of aggregate hierarchy system. In particular, understanding these functions and services by
aggregate system in line with methodology updating of aggregate separation, characterization and data analysis/
synthesis are discussed in depth. The discussions are focused on potential mechanistic linkage of multi-functions
of these soil carbon sequestration, microbial diversity protection and EEAs modulation to the diverse micro-scale
spatial pattern of the different hierarchies of aggregate size fractions. Following, the dual structure of soil
aggregates and the associated pore system is highlighted in the diverse provisioning of the above mentioned
functions and services. In the way, we point to the diversity of the aggregate-pore structure of the hierarchy
aggregate systems of or within a soil as the key to understand the formation and development of the above
mentioned functions and services for a give soil system. Meanwhile, through re-visiting and exploring the
original data in some cases of soil aggregate studies published, we propose some novel methods for better
characterizing the key roles of soil aggregate system in provisioning the ecosystem services and the improvement
with rational practices or reasonable interference so as to guide sustainable soil management. Finally, comments
on the importance of soil aggregate study in the research of Earth system sustainability. We urge a holistic
understanding of soil aggregates as fundamental soil functioning units, instead of a direct agent in field process.
Considering a key player in biogeochemical cycling and soil health, we call for a well-designed but long pursuing
study of soil hierarchy aggregate systems and a global unification of soil aggregate characterizing and
parameterization. This should be considered as a core foundation of soil system science in the late 21th century.