自生黄铁矿指示海底甲烷渗漏

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  • (1. 中国海洋大学 海洋地球科学学院,海底科学与探测技术教育部重点实验室,山东 青岛 266100; 2. 青岛海洋科技中心海洋地质过程与环境功能实验室,山东 青岛 266237)
张企盈,硕士研究生,主要从事海洋沉积学研究. E-mail:zhangqiying@stu.ouc.edu.cn

网络出版日期: 2024-06-21

基金资助

国家自然科学基金项目(编号:42276060);山东省优秀青年基金项目(编号:ZR2021YQ26)资助.

Authigenic Pyrite Indicates Seafloor Methane Seepage

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  • (1. Key Laboratory of Submarine Geosciences and Prospecting Technology, College of Marine Geosciences, Ocean University of China, Qingdao 266100, China; 2.Laboratory for Marine Geology, Qingdao Marine Science and Technology Center, Qingdao 266237, China)
ZHANG Qiying, Master student, research area includes marine sedimentology. E-mail: zhangqiying@stu.ouc.edu.cn

Online published: 2024-06-21

Supported by

Project supported by the National Natural Science Foundation of China (Grant No. 42276060); The Natural Science Foundation of Shandong Province (Grant No. ZR2021YQ26).

摘要

海底甲烷渗漏是海洋环境中甲烷的重要来源,对全球碳循环和极端环境生物地球化学循 环具有重要影响,示踪和重建海底(古)甲烷渗漏活动具有重要的科学意义。在甲烷渗漏活动过程 中,硫酸盐驱动的甲烷厌氧氧化作用普遍发育,从而改变孔隙水地球化学特征,并导致自生矿物的 形成。其中,自生黄铁矿是硫酸盐驱动的甲烷厌氧氧化的典型自生矿物之一,可作为记录甲烷渗 漏活动的良好指标。综述了硫酸盐驱动的甲烷厌氧氧化衍生自生黄铁矿的地球化学特征和形貌 特征,评估了其在示踪和重建海底(古)甲烷渗漏活动的潜力。结果表明,自生黄铁矿的硫和铁同 位素及原位微量元素和同位素可以有效识别硫酸盐驱动的甲烷厌氧氧化过程,甲烷渗漏环境沉积 物中自生黄铁矿的形貌和含量与正常海洋沉积物存在明显差异,彰显了自生黄铁矿示踪和重建海 底(古)甲烷渗漏事件的巨大潜力。

本文引用格式

张企盈, 苗晓明, 常鑫, 孔凡兴, 谷玉, 刘喜停 . 自生黄铁矿指示海底甲烷渗漏[J]. 地球科学进展, 0 : 1 . DOI: 10.11867/j.issn.1001-8166.2024.043.

Abstract

Seafloor methane seepage is an important source of methane and affects the global carbon cycle and extreme environmental biogeochemical cycles. Therefore, it is of great scientific significance to identify modern and ancient seafloor methane seepage. During methane leakage activities, Sulfate-Driven Anaerobic Oxidation of Methane (SD-AOM) is commonly developed, which changes the geochemical characteristics of pore water and leads to the formation of authigenic minerals. Among them, authigenic pyrite is one of the typical authigenic minerals of SD-AOM and can be used as a good indicator for recording methane leakage activities. This paper summarizes the geochemical and morphological characteristics of SD-AOM-derived authigenic pyrite and evaluates its potential for tracing and reconstructing seabed (paleo- ) methane leakage activities. The results show that the sulfur and iron isotopes, as well as in-situ trace elements and isotopes of authigenic pyrite, can effectively identify the SD-AOM process. In addition, there are significant differences in the morphology and content of authigenic pyrite in sediments in methane leakage environments compared with normal marine sediments, highlighting the great potential of authigenic pyrite in tracing and reconstructing seabed (paleo- ) methane leakage events.
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