收稿日期: 2002-12-24
修回日期: 2003-04-16
网络出版日期: 2004-02-01
基金资助
国家自然科学基金项目“喀斯特小流域营养离子循环及酸沉降影响的锶同位素示踪”(编号: 40203008);国家攀登计划项目“地质流体作用及其成矿效应研究”(编号: 95-预-39);国家自然科学基金项目“阿尔泰3号伟晶岩脉绿柱石通道水氢同位素组成及意义”(编号: 49903002)资助.
REE BEHAVIOR AND INFLUENCE FACTORS DURING CHEMICAL WEATHERING
Received date: 2002-12-24
Revised date: 2003-04-16
Online published: 2004-02-01
马英军 , 徐志方 , 刘丛强 , 张辉 , 霍润科 . 化学风化作用中的稀土元素行为及其影响因素[J]. 地球科学进展, 2004 , 19(1) : 87 -094 . DOI: 10.11867/j.issn.1001-8166.2004.01.0087
Chemical weathering plays an important role in many aspects of geological and environmental processes and is of great significance in both theoretical study and practical application. Study on geochemical behavior of trace elements during weathering can not only provide significant insight into a lot of worldwide earth science problems, but also shed light on solving some ecological and environmental problems that are closely related to mankind's living. Consequently, more attention is being paid to research on chemical weathering of the Earth crust. The physicochemical processes leading to in situ production of the detrital soil components and the release and mobilization of rare earth elements (REE) during weathering are welldocumented. From all these studies, it becomes evident that the REE mobility is mainly controlled by two factors, the climatic weathering conditions and the stability of the primary REE carrying minerals, and both geochemical and microbial factors control the abundance, distribution and form of REE during weathering and soil formation. The study contents and latest progress of REE geochemistry during chemical weathering are summarized in this paper, including aspects of REE distribution features in weathering crusts, formation cause of Ce anomaly, modes of occurrence and migration species of REE, and factors influencing geochemical distribution and migration of REE during chemical weathering. At the same time, the main methods of studying REE behavior during chemical weathering are briefly reviewed. Finally, it is particularly emphasized that the study on the effect of organic matter and microbes on REE behavior is an important study perspective in the future.
[1]Nesbitt H W. Mobility and fractionation of rare earth elements during weathering of a granodiorite [J]. Nature, 1979, 279: 206-210.
[2]Duddy I R. Redistribution and fractionation of rare earth and other elements in a weathering profile [J]. Chemical Geology, 1980, 30: 363-381.
[3]Topp S E, Salbu B, Roaldset E, et al. Vertical distribution of trace elements in laterite soil (Suriname) [J]. Chemical Geology, 1984, 47: 159-174.
[4]Banfield J F, Eggletin R A. Apatite replacement and rare earth mobilization, fractionation and fixation during weathering [J]. Clays and Clay Minerals, 1989, 37: 113-127.
[5]Price R C, Gray C M, Wilson R E, et al. The effects of weathering on rareearth element, Y and Ba abundances in Tertiary basalts from southeastern Australia[J]. Chemical Geology, 1991, 93: 245-265.
[6]Nesbitt H W, Wilson R E. Recent chemical weathering of basalts [J]. American Journal of Science, 1992, 292: 740-777.
[7]Braun J J, Pagel M, Muller J P, et al. Cerium anomalies in lateritic profiles[J]. Geochimica et Cosmochimica Acta, 1990, 54: 781-795.
[8]Braun J J, Viers J, Dupre B, et al. Solid/liquid REE fractionation in the lateritic system of Goyoum, East Cameroon: The implication for the present dynamics of the soil covers of the humid tropical regions [J]. Geochimica et Cosmochimica Acta, 1998, 62(2): 273-299.
[9]Macfarlane A W, Danielson A, Holland H D, et al. REE chemistry and SmNd systematics of late Archean weathering profiles in the Fortescue Group, Western Australia [J]. Geochimica et Cosmochimica Acta, 1994, 58(7): 1 777-1 794.
[10]Condie K C, Dengate J, Cullers R J. Behavior of rare earth elements in a paleoweathering profile on granodiorite in the Front Range, Colorado, USA [J]. Geochimica et Cosmochimica Acta, 1995, 59(2): 279-294.
[11]Koppi A J, Edis R, Field D J, et al. Rare earth element trends and ceriumuraniummanganese association in weathered rock from Kongarra, Northern Territory, Australia [J]. Geochimica et Cosmochimica Acta, 1996, 60(10): 1 695-1 707.
[12]Nesbitt H W, Markovics G. Weathering of granodioritic crust, longterm storage of elements in weathering profiles, and petrogenesis of siliciclastic sediments[J]. [WT6BX]Geochimica et Cosmochimica Acta[WT6BZ], 1997, 61(8): 1 653-1 670.
[13]Land M, hlander B, Ingri J, et al. Solid speciation and fractionation of rare earth elements in a spodosol profile from northern Sweden as revealed by sequential extraction[J].[WT6BX]Chemical Geology, [ST6BZ][WT6BZ][HT6]1999, 160: 121-138.
[14]Taunton A E, Welch S A, Banfield J F. Microbial controls on phosphate and lanthanide distributions during granite weathering and soil formation[J]. Chemical Geology, 2000, 169: 371-382.
[15]Aubert D, Stille P, Probst A. REE fractionation during granite weathering and removal by waters and suspended loads: Sr and Nd isotopic evidence[J]. Geochimica et Cosmochimica Acta, 2001, 65(3): 387-406.
[16]Islam M R, Peuraniemi V, Aario R, et al. Geochemistry and mineralogy of saprolite in Finnish Lapland[J]. Applied Geochemistry, 2002, 17(7): 885-902.
[17]Wang Xianjue(王贤觉), Shen Lipu(沈丽璞), Song Yunhua(宋云华), et al. An experimental investigation on the REE weathering crust of granites in South China[A]. In: Scientific Papers on Geology Prepared for the 25th International Geological Congress (2)[C]. Beijing: Geological Publishing House, 1980. 139-145(in Chinese).
[18]Song Yunhua(宋云华), Shen Lipu(沈丽璞). Discussion on clay minerals occurring in the weathered crust of a certain acid volcanic rock in Jiangxi Province and their formation condition[J]. Acta Mineralogica Sinica(矿物学报), 1982, (3): 207-212(in Chinese).
[19]Song Yunhua(宋云华), Shen Lipu(沈丽璞). REE geochemistry of the weathered crust of acid volcanic rocks An experimental study[J]. Geochimica(地球化学), 1986, (3): 224-234(in Chinese).
[20]Song Yunhua(宋云华), Shen Lipu(沈丽璞), Wang Xianjue(王贤觉). Preliminary discussion on REE in weathering crusts of selected rock types[J]. Chinese Science Bulletin(科学通报), 1987, 32: 695-698(in Chinese).
[21]Yang Zhuming(杨主明). Clay minerals in the REEweathering crust, Longnan, Jiangxi[J]. Scientia Geologica Sinica(地质科学), 1987, 22(1): 70-80(in Chinese).
[22]Wu Chengyu(吴澄宇), Huang Dianhao(黄典豪), Guo Zhongxun(郭中勋). REE geochemistry of the granite weathering crusts, Longnan, Jiangxi[J]. Acta Geologica Sinica(地质学报), 1989, 63(4): 349-362(in Chinese).
[23]Bao Zhiwei(包志伟). REE geochemistry of granite weathering crust, South China[J]. Geochimica(地球化学), 1992, 21: 166-174(in Chinese).
[24]Lin Chuanxian(林传仙), Zheng Zuoping(郑作平). Experimental studies on the metallogenetic mechanism of crustleaching REE deposits in southern China[J]. Geochimica(地球化学), 1994, 23(2): 189-198(in Chinese).
[25]Chen Zhicheng(陈志澄), Zhuang Wenming(庄文明), Yu Shoujun(俞受均). Some new knowledge of REE migration and concentration mechanism in weathering crust of granites, South China[J]. Advance in Earth Sciences(地球科学进展), 1993, 8(1): 47-48(in Chinese).
[26]Chen Zhicheng(陈志澄), Hong Huahua(洪华华), Zhuang Wenming(庄文明), et al. A study on determination of rare earth species in weathering crust of granites[J]. Journal of Instrumental Analysis(分析测试学报), 1993,12:21-25(in Chinese).
[27]Chen Zhicheng(陈志澄), Chen Dahui(陈达慧), Yu Shoujun(俞受均). A Preliminary study on the role of organic matter in dissolution, migration and concentration of rare earth elements in weathering crust of granites from South China[J]. Geochimica(地球化学), 1994, 23(2): 168-178(in Chinese).
[28]Chen Zhicheng(陈志澄), Yu Shoujun(俞受均), Fu Qunce(符群策), et al. Study on the organic metallogenic mechanism of weathering crust REE deposits[J]. Journal of the Chinese Rare Earth Society(中国稀土学报), 1997, 15(3): 244-251(in Chinese).
[29]Chen Binghui(陈炳辉), Chen Zhicheng(陈志澄), Yu Shoujun(俞受均), et al. The metallogeny of weathering crust REE deposits[J]. Mineral Deposits(矿床地质), 1998, 17 (supp): 473476(in Chinese).
[30]Chen Binghui(陈柄辉), Wu Fuhai(毋福海), Huang Limei(黄丽玫), et al. A study on REE biogeochemistry of the weathering crust of acid rocks and impoverishment of REE orebodies in South China[J]. Geological Review(地质评论), 1999, 45 (supp): 805-808(in Chinese).
[31]Chen Binghui(陈柄辉), Liu Huhu(刘琥琥), Wu Fuhai(毋福海). Microbes and their effects on REE extraction in weathering crust of granite[J]. Geological Review(地质评论), 2001, 47(1): 88-94(in Chinese).
[32]Li Jingyang(李景阳), Zhu Lijun(朱立军), Chen Jun(陈筠). Distribution features of REE of weathering crust of carbonate in Guizhou[J]. Carsologica Sinica(中国岩溶), 1998, 17(1): 15-24(in Chinese).
[33]Ma Yingjun,Liu Congqiang. Trace element geochemistry during chemical weathering: as exemplified by the weathered crust of granite, Longnan, Jiangxi, China[J]. Chinese Science Bulletin, 1999, 44(24): 2 260-2 263.
[34]Ma Yingjun, Liu Congqiang. Chemical weathering crust: A longterm storage of elements and its implications for sediment provenance [J]. Chinese Science Bulletin, 1999, 44 (supp): 107-110.
[35]Ma Yingjun, Huo Runke, Liu Congqiang. Speciation and fractionation of rare earth elements in a lateritic profile from southern China: Identification of the carriers of Ce anomalies[J]. Geochimica et Cosmochimica Acta, 2002, 66(15A): 471.
[36]Ma Yingjun, Liu Congqiang. Sr isotope evolution during chemical weathering of granites—impact of relative weathering rates of minerals [J]. Science in China(D), 2001, 44(8): 726-734.
[37]Balashov Y A, Ronov A B, Migdisov A A, et al. The effect of climate and facies environment on the fractionation of the rare earth during sedimentation[J]. Geochimica International, 1964, 5: 951-969.
[38]Rankin P C, Childs C W. Rareearth elements in ironmanganese concretions from some New Zealand soils [J]. Chemical Geology, 1976, 18: 55-64.
[39]Marsh J S. REE fractionation and Ce anomalies in weathering Karoo dolerite[J]. [WT6BX]Chemical Geology, 1991, 90: 189-194.
[40]Mongelli G. REE and other trace elements in a granitic weathering profile from "Serre", southern Italy [J]. Chemical Geology, 1993, 103: 17-25.
[41]Geng Anchao(耿安朝), Zhang Shen(章申), Hoiland H. Binding capacity and stability of humic acid with rare earth elements in solution[J]. China Environmental Science(中国环境科学), 1998, 18(1): 52-56(in Chinese).
[42]Zhu Jianguo(朱建国), Xing Guangxi(邢光熹). A study on sequential extraction of REE in soil[J]. Soil(土壤), 1992, 24(4): 215-218(in Chinese).
[43]Chi Ru'an(池汝安), Xu Jingming(徐景明), He Peijiong(何培炯), et al. REE geochemistry of granitoid weathering crust and properties of ores in southern China[J]. Geochimica(地球化学), 1995, 24(3): 261-269(in Chinese).
[44]Wang Lijun(王立军), Wang Yuqi(王玉琦), Zhang Shen(章申), et al. Speciation of rare earth elements in different types of soils in China[J]. Journal of the Chinese Rare Earth Society(中国稀土学报), 1997, 15(1): 64-70(in Chinese).
[45]Henderson P. Rare Earth Element Geochemistry[M]. Amsterdam: Elsevier, 1984. 346-365, 492-494.
[46]Wang Zhonggang(王中刚), Yu Xueyuan(于学元), Zhao Zhenhua(赵振华), et al. Rare Earth Element Geochemistry[M]. Beijing: Science Press, 1989. 45-75,133-359(in Chinese).
[47]Wood S A. The aqueous geochemistry of the rareearth elements and Yttrium: 1. Review of available lowtemperature data for inorganic complexes and the inorganic REE speciation of natural waters[J]. Chemical Geology, 1990, 82: 159-186.
[48]Gosselin D C, Smith M R, Lepel E A, et al. Rare earth elements in chloriderich groundwater, Palo Duro Basin, Texas, USA[J]. Geochimica et Cosmochimica Acta, 1992, 56(4): 1 495-1 505.
[49]Hyeon J, Byrne R H. Examination of comparative rare earth element complexation behavior using linear freeenergy relationships[J]. Geochimica et Cosmochimica Acta, 1992, 56: 1 127-1 137.
[50]Johannesson K H, Stetzenbach K J. Speciation of the rare earth element neodymium in groundwaters of the Nevada Test Site and Yucca Mountain and implications for actinide solubility [J]. Applied Geochemistry, 1995, 10: 565-572.
[51]Chen Deqian(陈德潜), Wu Jingshu(吴静淑). The metallogenic mechanism of ionadsorbed REE deposits[J]. Journal of the Chinese Rare Earth Society(中国稀土科学), 1990, 8(2): 175-179(in Chinese).
[52]Chen Binghui, Chen Zhicheng, Liang Qunyou, et al. Compounding pattern of REE, clay and humic acid in the weathering crust of granites [J]. Journal of Rare Earths, 1996, 14(1): 47-53.
[53]Chen Zhicheng, Yu Shoujun, Fu Qunce, et al. Organic metallogeny of weathering crust REE deposits [J]. Journal of Rare Earth’s, 1998, 16(1): 60-67.
[54]Wood S A. The aqueous geochemistry of the rareearth elements: Critical stability constants for complexes with simple carboxylic acids at 25℃ and l bar and their application to nuclear waste management [J]. Engineering Geology, 1993, 34: 229-259.
[55]Jia Rongfen(贾蓉芬), Liu Dehan(刘德汉), Ding Zuguo(丁祖国). REE abundance distribution pattern of bitumen in China and their environmental implications[J]. Geochimica(地球化学), 1994, 23(2): 146-154(in Chinese).
[56]Ran Yong(冉勇), Liu Zheng(刘铮). Specific adsorption of rare earth elements by soil and oxides and the mechanism[J]. Chinese Science Bulletin(科学通报), 1992, 37(18): 1 705-1 710(in Chinese).
[57]Chen Binghui, Wang Zhimei, Huang Limei, et al. The microbial metallogeny of weathering crust REE deposits in South China [J]. Chinese Science Bulletin, 1999, 44 (supp): 71-73.
[58]Ehrlich H L. Geomicrobiology: its significance for geology [J]. Earth Science Review, 1998, 45: 45-60.
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