地球科学进展 ›› 2002, Vol. 17 ›› Issue (6): 840 -847. doi: 10.11867/j.issn.1001-8166.2002.06.0840

综述与评述 上一篇    下一篇

煤中有害物质及其对环境的影响研究进展
刘大锰,刘志华,李运勇   
  1. 中国地质大学能源系,北京 100083
  • 收稿日期:2002-03-21 修回日期:2002-07-10 出版日期:2002-12-20
  • 通讯作者: 刘大锰(1965-),男,湖南桃源人,教授,主要从事煤层气地质、煤地球化学及环境有机污染研究与教学工作.E-mail: dmliu@cugb.edu.cn E-mail:dmliu@cugb.edu.cn
  • 基金资助:

    地质行业青年基金资助项目“煤及燃烧产物中PAHs的分布赋存特征及对环境的影响”(编号:Qh979817);教育部留学回国人员基金“燃煤环境中PAHs分布赋存规律及对环境的危害”(编号:2000-367)资助.

ADVANCES IN STUDIES OF HARMFUL SUBSTANCES IN COAL AND THEIR IMPACT ON THE ENVIRONMENT

LIU Da-meng,LIU Zhi-hua,LI Yun-yong   

  1. Department of Energy Resources, China University of Geosciences, Beijing 100083,China
  • Received:2002-03-21 Revised:2002-07-10 Online:2002-12-20 Published:2002-12-01

综述了煤中有害物质的种类、分布赋存特征及对环境的影响研究进展。探讨了煤中黄铁矿的形态、世代交替、有机硫的结构及煤中硫的地质成因。阐述了煤中微量元素的种类、地质分布、赋存状态、迁移聚集机制及其环境危害。并对煤及燃煤产物中多环芳烃的种类、赋存规律及对环境和人类健康的危害进行了详细阐述。最后指出了煤中有害物质研究中存在的问题与发展趋势。

The species, distribution and occurrence of harmful substances in coal and their influences on the environment have been systematically reviewed. The shape of pyrite in coal, formation generations, the textures of organic sulfur, and the geological genesis of sulfur in coal have been probed into as well. Three formation generations of pyrite in coal can be divided according to the δ34C values. The contents of thiophene in coal increase with coal rank. The contents of organic sulfur in coal depends on coal macerals. The sources of sulfur in coal mainly come from coal-forming plants and sedimentary environments, and the latter is more important. The δ34C value of sulfur from sea water prefers to be negative, however it prefers to be positive if the sulfur comes from fresh water. The species, distribution, occurrence and accumulation of hazardous minor and trace elements in coal and their harmful influences on the environment have been expounded. The contents and species of minor and trace elements in coal not only depend on the depositional environments and macerals, but also on the regional geological setting. The distribution and occurrence of minor and trace elements in coal can be determined with direct and indirect methods. The minor and trace elements in coals mainly originated from paleosoil, source materials, sea water, magmatic hydrothermal solution and underground water. The components of polycyclic aromatic hydrocarbons in coal, occurrence, and their impact on the environment as well on human health have been detailedly discussed too. The contents of PAHs in coal mainly depends on coal rank and sedimentary environments. However, the species and contents of PAHs in products of coal combustion are different from coal. The impact of particulate matter on the human health is related with the grain size of soot from coal combustion. The smaller is the grain size, the more hazardous is. The PAHs resulted in cancer and mutation is mainly from particulate matter of soot. The PAHs in air mainly come from coal combustion. Finally the existing problems and development trend for the study of harmful substances in coal are pointed out. The coal geology, geochemistry and environmental sciences should be systematically considered during study the harmful substances in coal. And the environmental pollution evaluation of harmful substances should be organically related with environmental pollution remediation as well.

中图分类号: 

[1] Yang Qi. Coal resources of China[J]. Bulletin of the Chinese Academy of Sciences, 1998, 12(4): 156-162.
[2] Mastral A M, Callen M, Murillo R. PAH atmospheric contamination from coal combustion[J]. Polycyclic Aromatic Compounds, 1996, 9(1~4): 37-44.
[3] Oavis C S, Fellin P, Otson R. A review of sampling methods for polyaromatic hydrocarbons in air[J]. Journal of Air Pollution Control Association, 1987, 37(12): 13-97.
[4] Zhang Lizhu, Liu Yongqing, Chen Wenlin. Distribution and occurrence of PAHs extracted from coal in China[J]. Journal of China University of Mining & Technology, 1997, 26(3): 32-35. [张丽珠,刘永庆,陈文琳. 中国煤炭苯提取液中多环芳烃赋存规律研究[J].中国矿业大学学报, 1997,26(3): 32-35.]
[5] Yao Weixi, Cui Wenheng, Xu Xiaobai. Relation of grain size of soot from coal cumbustion with distribution of PAHs and mutation[J]. Envionmental Sciences, 1991, 12(2): 9-13. [姚渭溪,崔文恒,徐晓白. 电厂燃煤锅炉排放烟尘粒径和多环芳烃的分布及致突变特性[J]. 环境科学,1991, 12(2): 9-13.]
[6] Kiss G, Varga Puchony Z, Rohrbacher G. Distribution of polycyclic aromatic hydrocarbons on atmospheric aerosol particles of different sizes[J]. Atmospheric Resources, 1998, 46(3~4): 253-261.
[7] Kalf D F, Crommentuiji T, Van de Plassche E. Environmental quality objectives for 10 polycyclic aromatic hydrocarbons (PAHs)[J]. Ecotoxicology and Environmental Safety, 1997, 36: 89-97.
[8] Cohen A D, Spackman W, Dolsen P. Occurrence and distribution of sulfur in peat-forming environments of southern Florida[J]. International Journal of Coal Geology, 1984, 4:73-96.
[9] Sinninghe Damste J S, Leeuw J W. Analysis structure and geochemical significance of organically bound sulfur in the geosphere: State of the art and future research[J]. Organic Geochemistry, 1990, 16(4~6):1 077-1 101.
[10] Querol X, Alastuey A, Chinchon J S, et al. Determination of pyritic sulfur and organic matter contents in Spanish subbituminous coals by X-ray powder diffraction[J]. International Journal of Coal Geology, 1993, 22: 279-293.
[11] Kortenski J. The occurrence and shape of pyrites in Bulgarian coal[J]. International Journal of Coal Geology, 1996, 29(4): 273-290.
[12] Prosser D J, Daws J A, Fallick A E, et al. The occurrence and δ34S of authigenic pyrite in Middle Jurassic Brent Group sediments[J]. Journal of Petrology, 1994, 17(4): 407-428.
[13] Tang Y, Ren D. Research on different pyrites in Late Permian coal of Sichuan province, southwestern China[A]. In: Parek V B K, Groppo J G, eds. Processing and Utilization of High-Sulfur Coals[C]. Netherlands: Elsevier Science Publishers B V, 1993. 37-45.
[14] Attar A. Sulfur groups in coal and their determination[A]. In: Karr C, ed. Analytical Meyhods for Coal and Coal Products Ⅲ[C]. New York: Academic Press, 1979. 585-624.
[15] Chou C L. Geologic factors affecting the abundance, distribution, and speciation of sulfur in coal[A]. In: Yang Qi, ed. Fossil Fuel Geology-Coal, Proceedings of the 30th International Geological Congress, Vol.18, Part B[C].Netherlands: VSP, 1997. 47-58.
[16] Lei J, Ren D. The petrological and geochemical characteristics of Permian high organosulfur coal from Guiding, China[A]. In: Parek B K, Proppo J G, eds. Processing and Utilization of High-Sulfur Coals[C]. Netherlands: Elsevier Science Publishers B V, 1993. 27-35.
[17] Ren Deyi. Micro-beam analysis of organic sulfur in coal macerals and their distribution[J]. Coal Geology & Exploration, 1993, 21(1): 27-29. [任德贻. 煤显微组分中有机硫的微区分析和分布特征[J]. 煤田地质与勘探,1993,21(1):27-29.]
[18] Spiker E C, Pierce B S, Bates A L, et al. Isotopic evidence for the source of sulfur in the upper freeport coal bed (west-central Pennsylvania, USA)[J].Chemical Geology,1994,114: 115-130.
[19] Price F T, Shieh Y N. Correlation between the δ34S of pyrite and organic sulfur in coal and oil-shale[J]. Chemical Geology, 1986, 58: 333-337.
[20] Liu Dameng, Yang Qi, Tang Dazhen. Occurrence and geological genesis of pyrites in Late Paleozoic coals in North China[J]. Chinese Journal of Geochemistry, 2000, 19(4): 301-311.
[21] Lei Jiajin, Ren Deyi, Tang Yuegang, et al. Sulfur accumulation model of super high organosulfur coal in Guiding, China[J]. Chinese Science Bulletin, 1995, 40(2): 165-168. 
[22] Liu Dameng, Yan Qig, Tang Dazhen, et al. Geochemistry of sulfur and elements in coal from the Antaibao surface coal mine, Pingshuo, Shanxi Province, China[J]. Internatioanl Journal of Coal Geology, 2001, 36 (1): 51-64.
[23] Liu Guijian, Peng Zicheng, Wang Guiliang, et al. Study on trace elelments in coal[J]. Advance in Earth Sciences, 2002, 17(1): 53-62. [刘桂建,彭子成,王桂梁,等. 煤中微量元素研究进展[J]. 地球科学进展,2002,17(1):53-62.]
[24] Harris L A, Barrett H E, Kopp O C. Elemental concentrations and their distribution in two bituminous coals of different paleoenvironments[J]. International Journal of Coal Geology, 1981, 1(1): 175-193.
[25] Mukherjee K N, Dutta N R, Chandra D, et al. Geochemistry of trace elements of Tertiary coals of India[J]. International Journal of Coal Geology, 1991, 17: 117-148.
[26] Van der Flier E, Fyfe W S. Uraniumthorium systematics of two Canadian coals[J]. International Journal of Coal Geology, 1985, 4: 335-353.
[27] Zhou Yiping. Distribution and Occurrence of arsenic from coal in Laochang mining district, Yunnan[J]. Coal Geology & Exploration, 1998, 26(4): 8-13. [周义平. 云南老厂矿区无烟煤中砷的分布类型及赋存状态[J]. 煤田地质与勘探,1998,26(4):8-13.]
[28] Zhuang Xinguo, Zeng Rongshu, Xu Wendong. Trace elements from No.9 coal seam in the Antaibao surface coal mine, Pingshuo Shanxi[J]. Earth Science, 1998, 23(6): 583-588. [庄新国,曾荣树,徐文东. 山西平朔安太堡露天矿9号煤层中的微量元素[J]. 地球科学,1998,23(6): 583-588.]
[29] Ren Deyi, Zhao Fenghua, Wang Yunquan. Distributions of minor and trace elements in Chinese coals[J]. International Journal of Coal Geology, 1999, 40(2~3): 175-183.
[30] Wang Yunquan. Advances in minor and trace elements in coal[J]. Coal Geology & Exploration, 1996, 24(1): 13-18. [王运泉. 煤中微量元素研究进展[J]. 煤田地质与勘探,1996,24(1):13-18.]
[31] McIntyre N S. Studies of elemental distributions within discrete coal macerals. Use of secondary ion mass spectrometry and X-ray photoelectron spectroscopy[J]. Fuel, 1985, 64: 1 705-1 712.
[32] Finkelman R B. What we don't know about the occurrence and distribution of the trace elements in coal[J]. International Journal of Coal Geology, 1989, 8: 63-66.
[33] Zhao Fenghua, Ren Deyi, Zheng Baoshan, et al. Study on the occurrence of arsenic in high-arsenic coal using XANES[J]. Chinese Science Bulletin, 1998, 43(14): 1 019-1 021.
[34] Zubovic P, Sheffey N B, Stadnichenko T. Distribution of minor elements in some coals of the Western and Southwestern Regions of the Interior coal province[J]. Geological Survey Bulletin, 1967, (1117-D):33.
[35] Zhang Shulin, Yin Jinshuang. Occurrence of Ge in coal in Bangmai basin Yunnan[J]. Acta Sedimentologica Sinica, 1988, 6: 29-39. [张淑苓,尹金双. 云南帮卖盆地煤中锗的存在形式研究[J]. 沉积学报,1988,6:29-39.]
[36]Wang Yunquan, Ren Deyi, Zhao Fenghua. Study on the leaching experiment of minor elements in coal[J]. International Journal of Coal Geology, 1999, 40(2~3): 184-190.
[37] Zhang Junying, Ren Deyi, Wang Yunquan. The relationship between organic trace elements in coal and coal rank[J]. Coal Geology & Exploration, 2000, 28(6): 11-13. [张军营,任德贻,王运泉. 煤中有机态微量元素与煤级的关系[J]. 煤田地质与勘探,2000,28(6):11-13.]
[38] Swaine D J. Trace Elements in Coal[M]. Sydney: Butterworths, 1990.35-40.
[39] Bouska V. Geochemistry of Coal[M]. Prague: Academia Press, 1981.65-75.
[40] Gluskoter H J, Ruch R R, Miller W G, et al. Trace elements in coal: Occurrence and distribution[J]. Illinois State Geological Survey Circular, 1977, 499:154.
[41] Ren Deyi, Zhao Fenghua, Zhang Junying, et al. A preliminary study on genetic types of enrichment for hazardous minor and trace elements in coal[J]. Earth Science Fontiers, 1999, 6(supp): 17-22. [任德贻,赵峰华,张军营,等. 煤中有害微量元素富集的成因类型初探[J]. 地学前缘,1999,6(增刊): 17-22.]
[42] Yang Shaojin, Dong Jinquan, Chen Bingru. Characterization of air particulate matter and their sources in urban and rural area of Beijing, China[J]. Journal of Environmental Sciences, 2000, 12(4): 402-409.
[43] Zheng B, Ding Z, Huang R, et al. Issues of health and disease relating to coal use in southwestern China[J]. Internatioanl Journal of Coal Geology, 1999, 40(2~3): 119-132.
[44] Pu Guixin, Shan Zhongjian. Preliminary study on distribution of PAHs in coals[J]. Environmental Chemistry, 1986, 5(5): 17-23. [濮贵新,单忠健. 不同煤中多环芳烃分布的初步研究[J]. 环境化学, 1986,5(5): 17-23.]
[45] Han Shuokui, Wang Liansheng, Yang Zhiwei. Separation and determination of PAHs in raw coal[J]. Journal of Environmental Sciences, 1986, 6(1):96-106. [韩朔睽,王连生,杨志伟. 原煤中多环芳烃的分离与测定[J].环境科学学报,1986,6(1): 96-106.]
[46] Liu Ruilian. Source identification of organic polluted matter in atmospheric particulate matter in Datong city[J]. Environmental Sciences, 1994, 16(1): 65-67. [刘瑞莲. 大同市大气颗粒物及有机污染物的分析研究[J].环境科学,1994, 16(1): 65-67.]
[47] Zhong Jinxian, Li Honghai, Zhang Fengzhu. Study on the sources of PAHs from air in Beijing city[J]. Environmental Chemistry, 1983, 2(4): 22-27. [钟晋贤,李洪海,张风珠. 北京地区大气中PAHs相关性研究[J]. 环境化学,1983,2(4):22-27.]
[48] Cui Wenheng, Yao Weixi, Xu Xiaobai. Emission regualrity and distribution of PAHs from coal combustion[J]. Journal of Environmental Sciences, 1993, 13(3): 317-324. [崔文恒,姚渭溪,徐晓白. 燃煤污染源多环芳烃的排放规律及分布特征[J]. 环境科学学报,1993,13(3):317-324.]
[49] Cao Xueli. Determination of reference material of environmental pollution standard for PAHs in fly ash[J]. Journal of Environmental Sciences, 1996, 16(4): 386-393. [曹学丽. 煤飞灰多环芳烃环境标准参考物的研制与定值[J]. 环境科学学报,1996,16(4):386-393.]
[50] Wang Wenxing, Su Yonghui, Li Jinhua. Dynamics of photochemical degradation of PAHs in soot[J]. Environmental Chemistry, 1997, 17(2): 97-102. [王文兴,束勇辉,李金花.煤烟粒子中PAHs光化学降解的动力学[J]. 环境化学, 1997, 17(2): 97-102.]
[51] Hong Weixiong, Quan Wenyi, Tian Dehai. Distribution and occurrence of PAHs from atmospheric particulate matter in Beijing city[J]. Environmental Chemistry, 1986, 7(1): 51-58. [洪伟雄,全文熠,田德海. 北京市城区大气可吸入颗粒物中多环芳烃的分布规律[J]. 环境化学,1986,7(1):51-58.]
[52] Mumford J L, Li X, Hu F, et al. Human exposure and dosimetry of polycyclic aromatic hydrocarbons in urine from Xuan Wei, China with lung cancer mortality associated with exposure to unvented coal smoke[J]. Carcinogenesis, 1995, 16(12): 3 031-3 036.
[53] Fu Yunnan, Liu Yiwen. Leaching of PAHs in fly ash by sea water[J]. Environmental Sciences, 1996, 17(1): 72-74. [傅云娜, 刘义文. 粉煤灰的多环芳烃在海水中的溶出[J]. 环境科学,  1996, 17(1): 72-74.]
[54] Gillete J S, Luthy R G, Clemett S J, et al. Direct Observation of polycyclic aromatic hydrocarbons on geosorbents at the subparticle scale[J]. Environmental Science and Technology, 1999, 33: 1 185-1 192.
[55] Zhu Lizhong, Liu Yongjian. Survey of PAHs in arterial street air of Hangzhou[J]. Journal of Environmental Sciences, 2001, 13(1): 8-13. 
[56] Chen Shanneng. Pollution of soot from coal combustion and BaP in air[J]. Environmental Sciences, 1988, 9(4):81-85. [陈善能. 燃煤电厂排放烟气与大气中BaP的污染[J]. 环境科学, 1988, 9(4): 81-85.]

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