地球科学进展 ›› 1999, Vol. 14 ›› Issue (5): 452 -457. doi: 10.11867/j.issn.1001-8166.1999.05.0452

综述与评述 上一篇    下一篇

名义上无水的地幔矿物中结构水的研究进展
夏群科 ①②,陈道公 ,支霞臣
  
  1. ①中国科学技术大学地球及空间科学系,安徽 合肥 230026;②中国科学技术大学化学系,安徽 合肥 230026
  • 收稿日期:1998-10-06 修回日期:1999-03-26 出版日期:1999-10-01
  • 通讯作者: 夏群科,男,1972年4月出生,博士生,矿物学和地球化学专业。
  • 基金资助:

    国家自然科学基金项目“中国东部(苏皖)富集地幔的性质和成因”(编号:49773181)与“中国东部新生代火山岩区幔源单斜辉石的氢同位素组成”(编号:49803002)资助。

RESEARCH PROGRESS IN STRUCTURAL WATER IN NOMINALLY ANHYDROUS MANTLE MINERALS

XIA Qunke ①,②, CHEN Daogong , Zhi Xiachen   

  1. ①Department of Earth and Space Sciences,University of Science and Technology of China,Hefei 230026,China;②Department of Chemistry,University of Science and Technology of China,Hefei 230026,China
  • Received:1998-10-06 Revised:1999-03-26 Online:1999-10-01 Published:1999-10-01

介绍了研究名义上无水地幔矿物中的结构水的科学意义,综述了近年来该领域的一些主要研究进展。包括7个方面:①结构水赋存状态的确定;②结构水含量的测定;③氢的结合方式;④氢在结构中的位置;⑤氢的稳定性;⑥氢的溶解度;⑦氢同位素组成。指出了存在的问题以及今后的研究方向,呼吁我国学者积极加入到这一前沿领域中来。

The scientific significance of research of trace water in nominally anhydrous mantle minerals is described; the research progress in this field are reviewed, including the following seven aspects:(1)confirmation of structural water, (2)determination of the amount of water, (3)incorporation mechanism of hydrogen, (4)the structural site of hydrogen, (5)stability of hydrogen, (6)solubility of hydrogen, and (7)hydrogen isotope compositions of some nominally anhydrous minerals; some problems and difficulties are pointed out, such as (1)the investigations of natural samples are not so enough, (2)the calibrations of IR for some minerals haven' t been made, (3)we know very little about the incorporation mechanism and structural site of hydrogen, (4)there is only a little information for stability and solubility of hydrogen,and (5)hydrogen isotope compositions of nominally anhydrous minerals are scarce; the future research emphases of this field are suggested.

中图分类号: 

〔1〕Rossman G R. Vibrational spectroscopy of hydrous components〔A〕. In: Hawthorn F C ed. Spectroscopic Methods in Mineralogy and Geology〔Z〕. Rev Mineral, 1988. Vol 18:193~206.
〔2〕Bell D R, Rossman G R. Water in the earth' s mantle: the role of nominally anhydrous minerals〔J〕. Science, 1992, 255:1 391~1 397.
〔3〕Rossman G R. Studies of OHin nominally anhydrous minerals〔J〕. Phys Chem Mineral, 1996, 23: 299~304.
〔4〕Wood B J. The effect of H2O on the 410-Kilometer seismic discontinuity〔J〕. Science, 1995, 268:74~76.
〔5〕Karato S. The role of hydrogen in the electrical conductivity of the upper mantle〔J〕. Nature, 1990, 347:272~273.
〔6〕Kronenberg A K, Kirby S H, Aines R D,et al. Solubility and diffusional uptake of hydrogen in quartz at high water pressures: Implications for hydrolytic weakening〔J〕. J Geophys Res, 1986, 91: 12 723~12 744.
〔7〕Hirth G, Kohlstedt D L. Water in the oceanic upper mantle:implications for rheology, melt extraction and the evolution of the lithosphere〔J〕. Earth Planet Sci Lett, 1996, 144:93~108.
〔8〕Ephick S C, Graham C M, Dennis P F. An ion microprobe study of anhydrous oxygen diffusion in anorthite: a comparison with hydrothermal data and some geological implications〔J〕. Contrib Mineral Petro, 1988, 100: 490~495.
〔9〕Farver J R, Yund R A. The effect of hydrogen,oxygen, and water fugacity on oxygen diffusion in alkali feldspars〔J〕.Geochim Cosmochim Acta, 1990, 54:2 953~2 964.
〔10〕Shannon R D, Mariano A N, Rossman G R. Effect of H2O and CO2on dielectric properties of single crystal cordierite and comparison with polycrystalline cordierite〔J〕. J Am Ceram Soc, 1992, 75:2 395~2 399.
〔11〕Aines R D, Rossman G R. Relationships between radiation damage and trace water in zircon, quartz and topaz〔J〕. Am Mineral, 1986, 71:1 186~1 193.
〔12〕Meade C, Reffner J A, Ito E. Synchroton infrared absorbance measure-ments of hydrogen in MgSiO3perovskite〔J〕. Science, 1994, 264:1 558~1 560.
〔13〕Kohlstedt D L, Keppler H , Rubie D C. Solubility of water in theα,βandγphases of (Mg, Fe)2SiO4〔J〕. Contrib Mineral Petrol, 1996, 123:345~357.
〔14〕Pawley A, McMillian P C, Holloway. Hydrogen in stishovite, with implications for mantle water content〔J〕.Science, 1993, 261:1 024~1 026.
〔15〕Okuchi T. Hydrogen partitioning into molten iron at high pressure: implications for earth' s core〔J〕. Science, 1997,278:1 781~1 784.
〔16〕Ahrens T J. Origin of the Earth〔J〕. Phy Today, 1994, 47(9):38~45.
〔17〕Bell D R, Ihinger P D, Rossman G R. Quantitative analysis of hydroxyl in garnet and pyroxene〔J〕. Am Mineral, 1995,80:465~474.
〔18〕Hofmeister A M, Rossman G R. A spectroscopic study of irradiation coloring of amazonite: structurally hydrous, Pb-bearing feldspar〔J〕. Am Mineral, 1985, 70:794~804.
〔19〕Rossman G R. Hydrogen in“anhydrous”minerals〔J〕. Nucl Instr Meth Phys Res, 1990, B45: 41~44.
〔20〕Kurosawa J, Yurimoto H, Matsumoto K,et al. Hydrogen analysis of mantle olivine by secondary ion mass spectrometry〔A〕. In: Syono Y, Manghnani M Heds.High-Pressure Research: Application to Earth and Planetary Sciences〔C〕. Tokyo: Terra Sci Pub Co, 1992. 283~287.
〔21〕Sweeney R J, Prozesky V M, Springhorn K A. Use of elastic recoil detection analysis (ERDA) microbeam technique for the quantitative determination of hydrogen in materials and hydrogen partitioning between olivine and melt at high pressures〔J〕. Geochim Cosmochim Acta, 1997, 61(1):101~113.
〔22〕Cho H, Rossman G R. Single-crystal NMR studies of low-concentration hydrous species in minerals: Grossular garnet〔J〕. Am Mineral, 1993, 78:1 149~1 164.
〔23〕Rossman G R, Aines R D. The hydrous components in garnets: grossular-hydrogrossular〔J〕. Am Mineral, 1991,76:1 153~1 164.
〔24〕Martin R F, Donnay G. Hydroxyl in the mantle〔J〕. Am Mineral, 1972, 57:554~570.
〔25〕Vlassopoulos D, Rossman G R, Haggerty S E. Coupled substitution of H and minor elements in rutile and implications of high OH contents in Nb-Cr rutile from the upper mantle〔J〕. Am Mineral., 1993, 78:1 181~1 191.
〔26〕Sykes D, Rossman G R, Veblen D R,et al. Enhanced hydrogen and fluorine incorporation in borian olivine〔J〕.Am Mineral, 1994, 79:904~908.
〔27〕Skogby H, Rossman G R. OH in pyroxenes: An experimental study of incorporation mechanisms and stability〔J〕. Am Mineral, 1989, 74:1 059~1 069.
〔28〕Swope R J, Smyth J R, Larson A C. H in rutile-type compounds 1. Single-crystal neutron and x-ray diffraction study of H in rutile〔J〕. Am Mineral, 1995, 80:448~453.
〔29〕Smyth J R, Swope R J, McCormick T C. Crystal chemistry and the role of hydrous clinopyroxenes in the mantle〔A〕. Am Geoph Union. Abstracts of Spring Meeting, Trans〔C〕.1992. p141.
〔30〕Mackwell S J, Kohlstedt D L. Diffusion of hydrogen in olivine: implications for water in the mantle〔J〕. J Geophys Res, 1990, 95:5 079~5 088.
〔31〕Wang L P, Zhang Y X, Essene E J. Diffusion of the hydrous component in pyrope〔J〕. Am Mineral, 1996, 81:706~718.
〔32〕Ingrin J, Hercule S, Charton T. Diffusion of hydrogen in diopside: Dehydration experiments〔J〕. J Geophys Res,1995, 100:15 489~15 499.
〔33〕Bai Q, Kohlstedt D L. Substantial hydrogen solubility in olivine and implications for water storage in the mantle〔J〕.Nature, 1992, 357:672~674.
〔34〕Ginsberg S B, Kohlstedt D L. Effects of temperature and Mg:Fe ratios on water solubility in olivine crystals〔A〕. Am Geoph Union. Abstracts of Fall Meeting, Trans〔C〕. 1995.706.
〔35〕Bai Q, Wang Z C, Dresen G. Solubility and stability of hydrogen in diopside single crystals〔A〕. Am Geoph Union.Abstracts of Fall Meeting, Trans〔C〕. 1994. 652.
〔36〕Lu R, Keppler H. Water solubility in pyrope to 100 k bar〔J〕. Contri Mineral Petrol, 1997, 129:35~42.
〔37〕Withers A C, Wood B J, Carroll M R. The OH content of pyrope at high pressure〔J〕. Chem Geol, 1998, 147:161~171.
〔38〕Ihinger P D, Bell D R. The isotopic composition of hydrogen in nominally anhydrous mantle minerals〔J〕. EOS Trans. Am Geoph Union, 1991, 72:537.
〔39〕Dyar D M, Martin S V, Mackwell S J,et al. Crystal chemistry of Fe3+,H+, and D/H in mantle-derived augite from Dish Hill: Implications for alteration during transport〔A〕. In: Dyar M D, McCammon C, Schaefer M W eds.Mineral Spectroscopy: A Tribute to Rogers G Burns (The Geochemical Society, Special Publication)〔R〕, 1996,No5,:289~304.
〔40〕Xia Q K, Chen D G, Deloule E,et al. Hydrogen isotope composition of mantle-derived megacrysts from eastern China〔J〕. Chinese Science Bulletin, 1998, 43(supple):146.
〔41〕Bell D R, Rossman G R. The distribution of hydroxyl in garnets from the subcontinental mantle of Southern Africa〔J〕. Contrib Mineral Petrol, 1992, 111:161~178.
〔42〕Smyth J R, Bell D R, Rossman G R. Incorporation of hydroxyl in upper mantle clinopyroxenes〔J〕. Nature,1991, 351:732~734.
〔43〕夏群科,陈道公,郭立鹤.女山幔源单斜辉石巨晶中的结构OH〔J〕.科学通报, 1998, 43(16): 1 764~1 766.
〔44〕夏群科,陈道公,郭立鹤,等.汉诺坝幔源单斜辉石巨晶中的微量结构水:红外光谱观察〔J〕.矿物学报,1999, (待刊).
〔45〕郭立鹤,林兴源,谢漫泽,等.河北汉诺坝玄武岩中幔源捕虏体中的水〔J〕.地质学报,1998,72(2):138~143.
〔46〕Skogby H, Bell D R, Rossman G R. Hydroxide in pyroxene:variations in the natural enviornment〔J〕. Am Mineral,1990, 75:764~774.
〔47〕Chakraborty S, Ganguly J. Cation diffusion in aluminosilicate garnets: experimental determination in spessartine-almandine diffusion couples, evolution of effective binary diffusion coefficients and applications〔J〕. Contrib Mineral Petrol, 1992, 111:74~86.
〔48〕Deloule E, Albarede F, Sheppard S M F. Hydrogen isotope heterogeneities in the mantle from ion probe analysis of amphiboles from ultramafic rocks〔J〕. Earth Planet Sci Lett,1991, 105: 543~553.
〔49〕夏群科,陈道公,Deloule E,等.幔源云母巨晶氢同位素组成的微尺度不均一性:离子探针研究〔J〕.中国科学(D辑),1999, 29(1):62~67.

[1] 陈林, 唐红, 李雄耀, 欧阳自远, 王世杰. 基于1.4 μm红外光谱测量磷灰石结构水的定量方法探讨[J]. 地球科学进展, 2016, 31(4): 403-408.
[2] 许 妍, 曹 可, 李 冕, 许自舟. 海岸带生态风险评价研究进展[J]. 地球科学进展, 2016, 31(2): 137-146.
[3] 王成金. 现代港口地理学的研究进展及展望[J]. 地球科学进展, 2008, 23(3): 243-251.
[4] 肖洪浪,李锦秀,赵良菊,程国栋. 土壤水异质性研究进展与热点[J]. 地球科学进展, 2007, 22(9): 954-959.
[5] 李耀辉,张书余. 我国沙尘暴特征及其与干旱关系的研究进展[J]. 地球科学进展, 2007, 22(11): 1169-1176.
[6] 胡娅敏,丁一汇. 东亚地区区域气候模拟的研究进展[J]. 地球科学进展, 2006, 21(9): 956-964.
[7] 陈光华,黄荣辉. 西北太平洋热带气旋和台风活动若干气候问题的研究[J]. 地球科学进展, 2006, 21(6): 610-616.
[8] 杨耀民,石学法,刘季花,王立群. 海洋环境Fe同位素地球化学研究进展[J]. 地球科学进展, 2006, 21(11): 1171-1179.
[9] 杨晓志,夏群科,于慧敏,郝艳涛. 大陆下地壳高电导率的起源:矿物中的结构水[J]. 地球科学进展, 2006, 21(1): 31-38.
[10] 夏军,左其亭. 国际水文科学研究的新进展[J]. 地球科学进展, 2006, 21(03): 256-261.
[11] 宋长青;冷疏影. 当代地理学特征:发展趋势及中国地理学研究进展[J]. 地球科学进展, 2005, 20(6): 595-599.
[12] 梁海河;徐宝祥;刘黎平;葛润生. 偏振微波雷达探测大气研究进展及几个问题的考虑[J]. 地球科学进展, 2005, 20(5): 541-548.
[13] 王奖臻,李朝阳,胡瑞忠. 斑岩铜矿研究的若干进展[J]. 地球科学进展, 2001, 16(4): 514-519.
[14] 苏根利,谢鸿森,李和平,丁东业,郭 捷. 地幔矿物与水流体之间元素分配系数的研究及意义[J]. 地球科学进展, 2001, 16(2): 226-234.
[15] 杨明义,田均良.

坡面侵蚀过程定量研究进展[J]. 地球科学进展, 2000, 15(6): 649-653.

阅读次数
全文


摘要